{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T12:20:07Z","timestamp":1761394807980,"version":"3.37.3"},"reference-count":37,"publisher":"Springer Science and Business Media LLC","issue":"5","license":[{"start":{"date-parts":[[2016,5,1]],"date-time":"2016-05-01T00:00:00Z","timestamp":1462060800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2016,5,1]],"date-time":"2016-05-01T00:00:00Z","timestamp":1462060800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"funder":[{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"crossref","award":["Marie Curie Intra European Fellowship within the 7"],"award-info":[{"award-number":["Marie Curie Intra European Fellowship within the 7"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100000921","name":"European Cooperation in Science and Technology","doi-asserted-by":"crossref","award":["CM1005"],"award-info":[{"award-number":["CM1005"]}],"id":[{"id":"10.13039\/501100000921","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Photochem Photobiol Sci"],"published-print":{"date-parts":[[2016,5]]},"DOI":"10.1039\/c6pp00057f","type":"journal-article","created":{"date-parts":[[2016,4,19]],"date-time":"2016-04-19T08:38:38Z","timestamp":1461055118000},"page":"635-643","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Effect of solvent polarity on the spectroscopic properties of an alkynyl gold(i) gelator. The particular case of water"],"prefix":"10.1007","volume":"15","author":[{"given":"Raquel","family":"Gavara","sequence":"first","affiliation":[]},{"given":"Jo\u00e3o Carlos","family":"Lima","sequence":"additional","affiliation":[]},{"given":"Laura","family":"Rodr\u00edguez","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2016,5,1]]},"reference":[{"key":"150505_CR1","doi-asserted-by":"publisher","first-page":"1806","DOI":"10.1039\/b708615f","volume":"37","author":"V W-W Yam","year":"2008","unstructured":"V. W.-W. Yam and E. C.-C. Cheng, Highlights on the recent advances in gold chemistry-a photophysical perspective, Chem. Soc. Rev., 2008, 37, 1806\u20131813.","journal-title":"Chem. Soc. Rev."},{"key":"150505_CR2","doi-asserted-by":"publisher","first-page":"2541","DOI":"10.1039\/c0cs00094a","volume":"40","author":"G-J Zhou","year":"2011","unstructured":"G.-J. Zhou, W.-Y. Wong, Organometallic acetylides of PtII, AuI and HgII as new generation optical power limiting materials, Chem. Soc. Rev., 2011, 40, 2541\u20132566.","journal-title":"Chem. Soc. Rev."},{"key":"150505_CR3","doi-asserted-by":"publisher","first-page":"4144","DOI":"10.1039\/C3CS60453E","volume":"43","author":"M Mauro","year":"2014","unstructured":"M. Mauro, A. Aliprandi, D. Septiadi, N. S. Kehra and L. De Cola, When self-assembly meets biology: luminescent platinum complexes for imaging applications, Chem. Soc. Rev., 2014, 43, 4144\u20134166.","journal-title":"Chem. Soc. Rev."},{"key":"150505_CR4","doi-asserted-by":"publisher","first-page":"5442","DOI":"10.1039\/c1cs15123a","volume":"40","author":"J C Lima","year":"2011","unstructured":"J. C. Lima and L. Rodr\u00edguez, Applications of gold(I) alkynyl systems: a growing field to explore, Chem. Soc. Rev., 2011, 40, 5442\u20135456.","journal-title":"Chem. Soc. Rev."},{"key":"150505_CR5","doi-asserted-by":"publisher","first-page":"1152","DOI":"10.1246\/cl.150592","volume":"44","author":"A Aliprandi","year":"2015","unstructured":"A. Aliprandi, D. Genovese, M. Mauro and L. De Cola, Recent Advances in Phosphorescent Pt(II) Complexes Featuring Metallophilic Interactions: Properties and Applications, Chem. Lett., 2015, 44, 1152\u20131169.","journal-title":"Chem. Lett."},{"key":"150505_CR6","doi-asserted-by":"publisher","first-page":"10343","DOI":"10.1039\/C4CC03259D","volume":"50","author":"E E Langdon-Jones","year":"2014","unstructured":"E. E. Langdon-Jones and S. J. A. Pope, Recent developments in gold(I) coordination chemistry: luminescence properties and bioimaging opportunities, Chem. Commun., 2014, 50, 10343\u201310354.","journal-title":"Chem. Commun."},{"key":"150505_CR7","doi-asserted-by":"publisher","first-page":"1373","DOI":"10.1016\/j.ccr.2013.01.005","volume":"257","author":"J Zhang","year":"2013","unstructured":"J. Zhang, C.-Y. Su, Metal-organic gels: From discrete metallogelators to coordination polymers, Coord. Chem. Rev., 2013, 257, 1373\u20131408.","journal-title":"Coord. Chem. Rev."},{"key":"150505_CR8","doi-asserted-by":"publisher","first-page":"370","DOI":"10.1039\/C1CS15182G","volume":"41","author":"H Schmidbaur","year":"2012","unstructured":"H. Schmidbaur and A. Schier, Aurophilic interactions as a subject of current research: an up-date, Chem. Soc. Rev., 2012, 41, 370\u2013412.","journal-title":"Chem. Soc. Rev."},{"key":"150505_CR9","doi-asserted-by":"publisher","first-page":"2111","DOI":"10.1016\/j.ccr.2011.02.003","volume":"255","author":"X M He","year":"2011","unstructured":"X. M. He and V. W.-W. Yam, Luminescent Gold(I) Complexes for Chemosensing, Coord. Chem. Rev., 2011, 255, 2111\u20132123.","journal-title":"Coord. Chem. Rev."},{"key":"150505_CR10","doi-asserted-by":"publisher","first-page":"11579","DOI":"10.1039\/c1cc13767k","volume":"47","author":"V W W Yam","year":"2011","unstructured":"V. W. W. Yam and K. M. C. Wong, Luminescent metal complexes of d6, d8 and d10 transition metal centres, Chem. Commun., 2011, 47, 11579\u201311592.","journal-title":"Chem. Commun."},{"key":"150505_CR11","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1021\/cr940396v","volume":"97","author":"P Pyykk\u00f6","year":"1997","unstructured":"P. Pyykk\u00f6, Strong Closed-Shell Interactions in Inorganic Chemistry, Chem. Rev., 1997, 97, 597\u2013636.","journal-title":"Chem. Rev."},{"key":"150505_CR12","doi-asserted-by":"publisher","first-page":"417","DOI":"10.1002\/anie.198804171","volume":"27","author":"H Schmidbaur","year":"1988","unstructured":"H. Schmidbaur, W. Graf and G. M\u00fcller, Weak Intramolecular Bonding Relationships: The Conformation-Determining Attractive Interaction between Gold(I) Centers, Angew. Chem., Int. Ed. Engl., 1988, 27, 417\u2013419.","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"150505_CR13","first-page":"49","volume":"41","author":"T Steiner","year":"2002","unstructured":"T. Steiner, The hydrogen bond in the solid state, Angew. Chem., Int. Ed., 2002, 41, 49\u201376.","journal-title":"Angew. Chem., Int. Ed."},{"key":"150505_CR14","doi-asserted-by":"publisher","first-page":"1","DOI":"10.3390\/inorganics3010001","volume":"3","author":"J C Lima","year":"2015","unstructured":"J. C. Lima and L. Rodr\u00edguez, Supramolecular Gold Metallogelators: The Key Role of Metallophilic Interactions, Inorganics, 2015, 3, 1\u201318.","journal-title":"Inorganics"},{"key":"150505_CR15","doi-asserted-by":"publisher","first-page":"10371","DOI":"10.1021\/ja001545w","volume":"122","author":"M A Rawashdeh-Omary","year":"2000","unstructured":"M. A. Rawashdeh-Omary, M. A. Omary and H. H. Patterson, Oligomerization of Au(CN)2\u2212 and Ag(CN)2\u2212 Ions in Solution via Ground-State Aurophilic and Argentophilic Bonding, J. Am. Chem. Soc., 2000, 122, 10371\u201310380.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR16","doi-asserted-by":"publisher","first-page":"13472","DOI":"10.1002\/anie.201308135","volume":"52","author":"W-X Ni","year":"2013","unstructured":"W.-X. Ni, M. Li, J. Zheng, S. Z. Zhan, Y.-M. Qiu, S. W. Ng and D. Li, Approaching White-Light Emission from a Phosphorescent Trinuclear Gold(I) Cluster by Modulating Its Aggregation Behavior, Angew. Chem., Int. Ed., 2013, 52, 13472\u201313476.","journal-title":"Angew. Chem., Int. Ed."},{"key":"150505_CR17","doi-asserted-by":"publisher","first-page":"2327","DOI":"10.1021\/ja012397s","volume":"124","author":"R L White-Morris","year":"2002","unstructured":"R. L. White-Morris, M. M. Olmstead, F. Jiang, D. S. Tinti and A. L. Balch, Remarkable Variations in the Luminescence of Frozen Solutions of [AuC(NHMe)22](PF6)\u00b70.5(Acetone). Structural and Spectroscopic Studies of the Effects of Anions and Solvents on Gold(I) Carbene Complexes, J. Am. Chem. Soc., 2002, 124, 2327\u20132336.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR18","doi-asserted-by":"publisher","first-page":"2596","DOI":"10.1021\/om100300a","volume":"29","author":"E Vergara","year":"2010","unstructured":"E. Vergara, E. Cerrada, A. Casini, O. Zava, M. Laguna and P. J. Dyson, Antiproliferative Activity of Gold(I) Alkyne Complexes Containing Water-Soluble Phosphane Ligands, Organometallics, 2010, 29, 2596\u20132603.","journal-title":"Organometallics"},{"key":"150505_CR19","doi-asserted-by":"publisher","first-page":"6564","DOI":"10.1021\/ja3018994","volume":"134","author":"I O Koshevoy","year":"2012","unstructured":"I. O. Koshevoy, Y.-C. Chang, A. J. Karttunen, M. Haukka, T. Pakkanen, P.-T. Chou, Modulation of Metallophilic Bonds: Solvent-Induced Isomerization and Luminescence Vapochromism of a Polymorphic Au\u2013Cu Cluster, J. Am. Chem. Soc., 2012, 134, 6564\u20136567.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR20","doi-asserted-by":"publisher","first-page":"5104","DOI":"10.1002\/chem.201204611","volume":"19","author":"I O Koshevoy","year":"2013","unstructured":"I. O. Koshevoy, Y.-C. Chang, A. J. Karttunen, J. R. Shakirova, J. J\u00e4nis, M. Haukka, T. Pakkanen, P.-T. Chou, Solid-State Luminescence of Au-Cu-Alkynyl Complexes Induced by Metallophilicity-Driven Aggregation, Chem.\u2013Eur. J., 2013, 19, 5104\u20135112.","journal-title":"Chem.\u2013Eur. J."},{"key":"150505_CR21","doi-asserted-by":"publisher","first-page":"12307","DOI":"10.1021\/ja103400e","volume":"132","author":"G F Manbeck","year":"2010","unstructured":"G. F. Manbeck, W. W. Brennessel, R. A. Stockland Jr. and R. Eisenberg, Luminescent Au(I)\/Cu(I) Alkynyl Clusters with an Ethynyl Steroid and Related Aliphatic Ligands: An Octanuclear Au4Cu4 Cluster and Luminescence Polymorphism in Au3Cu2 Clusters, J. Am. Chem. Soc., 2010, 132, 12307\u201312318.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR22","first-page":"2860","volume-title":"Chem. Commun.","author":"I O Koshevoy","year":"2009","unstructured":"I. O. Koshevoy, Y.-C. Lin, A. J. Karttunen, M. Haukka, P.-T. Chou, S. P. Tunik and T. A. Pakkanen, An intensely and oxygen independent phosphorescent gold(I)\u2013silver(I) complex: \u201ctrapping\u201d an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules, Chem. Commun., 2009, 2860\u20132862."},{"key":"150505_CR23","doi-asserted-by":"publisher","first-page":"1440","DOI":"10.1039\/b920001k","volume":"46","author":"I O Koshevoy","year":"2010","unstructured":"I. O. Koshevoy, Y.-C. Lin, Y.-C. Chen, A. J. Karttunen, M. Haukka, P.-T. Chou, S. P. Tunik and T. A. Pakkanen, Rational reductive fusion of two heterometallic clusters: formation of a highly stable, intensely phosphorescent Au\u2013Ag aggregate and application in two-photon imaging in human mesenchymal stem cells, Chem. Commun., 2010, 46, 1440\u20131442.","journal-title":"Chem. Commun."},{"key":"150505_CR24","doi-asserted-by":"publisher","first-page":"9703","DOI":"10.1039\/c1dt10197h","volume":"40","author":"X He","year":"2011","unstructured":"X. He, N. Zhu and V. W.-W. Yam, Design and synthesis of luminescence chemosensors based on alkynyl phosphine gold(I)\u2013copper(I) aggregates, Dalton Trans., 2011, 40, 9703\u20139710.","journal-title":"Dalton Trans."},{"key":"150505_CR25","doi-asserted-by":"publisher","first-page":"9022","DOI":"10.1039\/c0dt00587h","volume":"39","author":"I O Koshevoy","year":"2010","unstructured":"I. O. Koshevoy, P. V. Ostrova, A. J. Karttunen, A. S. Melnikov and M. A. Khodorkovskiy, Assembly of the heterometallic Au(I)\u2013M(I) (M = Cu, Ag) clusters containing the dialkyne-derived diphosphines: synthesis, luminescence and theoretical studies, Dalton Trans., 2010, 39, 9022\u20139031.","journal-title":"Dalton Trans."},{"key":"150505_CR26","doi-asserted-by":"publisher","first-page":"72","DOI":"10.1039\/C2CC37262B","volume":"49","author":"R Gavara","year":"2013","unstructured":"R. Gavara, J. Llorca, J. C. Lima and L. Rodr\u00edguez, A luminescent hydrogel based on a new Au(I) complex, Chem. Commun., 2013, 49, 72\u201374.","journal-title":"Chem. Commun."},{"key":"150505_CR27","doi-asserted-by":"publisher","first-page":"5195","DOI":"10.1021\/acs.inorgchem.5b00025","volume":"54","author":"R Gavara","year":"2015","unstructured":"R. Gavara, E. Aguil\u00f3, C. Fonseca Guerra, L. Rodr\u00edguez and J. C. Lima, Thermodynamic Aspects of Aurophilic Hydrogelators, Inorg. Chem., 2015, 54, 5195\u20135203.","journal-title":"Inorg. Chem."},{"key":"150505_CR28","doi-asserted-by":"publisher","first-page":"7636","DOI":"10.1021\/ic300609f","volume":"51","author":"L Rodr\u00edguez","year":"2012","unstructured":"L. Rodr\u00edguez, M. Ferrer, R. Crehuet, J. Anglada and J. C. Lima, Correlation between Photophysical Parameters and Gold\u2212Gold Distances in Gold(I) (4-Pyridyl)ethynyl Complexes, Inorg. Chem., 2012, 51, 7636\u20137641.","journal-title":"Inorg. Chem."},{"key":"150505_CR29","first-page":"2899","volume-title":"Eur. J. Inorg. Chem.","author":"M Ferrer","year":"2008","unstructured":"M. Ferrer, A. Guti\u00e9rrez, L. Rodr\u00edguez, O. Rossell, J. C. Lima, M. Font-Bard\u00eda and X. Solans, Study of the Effect of the Phosphane Bridging Chain Nature on the Structural and Photophysical Properties of a Series of Gold(I) Ethynylpyridine Complexes, Eur. J. Inorg. Chem., 2008, 2899\u20132909."},{"key":"150505_CR30","doi-asserted-by":"publisher","first-page":"1061","DOI":"10.1021\/ja01210a043","volume":"68","author":"P S Albright","year":"1946","unstructured":"P. S. Albright and L. J. Gosting, Dielectric Constants of the Methanol-Water System from 5 to 55\u00b0, J. Am. Chem. Soc., 1946, 68, 1061\u20131063.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR31","doi-asserted-by":"publisher","first-page":"721","DOI":"10.1063\/1.1744225","volume":"28","author":"E G McRae","year":"1958","unstructured":"E. G. McRae and M. Kasha, Enhancement of Phosphorescence Ability upon Aggregation of Dye Molecules, J. Chem. Phys., 1958, 28, 721\u2013722.","journal-title":"J. Chem. Phys."},{"key":"150505_CR32","doi-asserted-by":"publisher","first-page":"371","DOI":"10.1351\/pac196511030371","volume":"11","author":"M Kasha","year":"1965","unstructured":"M. Kasha, H. R. Rawls and M. A. El-Bayoumi, The exciton model in molecular spectroscopy, Pure Appl. Chem., 1965, 11, 371\u2013392.","journal-title":"Pure Appl. Chem."},{"key":"150505_CR33","doi-asserted-by":"publisher","first-page":"11384","DOI":"10.1021\/ja0703933","volume":"129","author":"O Elbjeirami","year":"2007","unstructured":"O. Elbjeirami and M. A. Omary, Photochemistry of Neutral Isonitrile Gold(I) Complexes: Modulation of Photoreactivity by Aurophilicity and \u03c0-Acceptance Ability, J. Am. Chem. Soc., 2007, 129, 11384\u201311393.","journal-title":"J. Am. Chem. Soc."},{"key":"150505_CR34","doi-asserted-by":"publisher","first-page":"424","DOI":"10.1021\/ar100130j","volume":"44","author":"K M-C Wong","year":"2011","unstructured":"K. M.-C. Wong and V. W.-W. Yam, Self-Assembly of Luminescent Alkynylplatinum(II) Terpyridyl Complexes: Modulation of Photophysical Properties through Aggregation Behavior, Acc. Chem. Res., 2011, 44, 424\u2013434.","journal-title":"Acc. Chem. Res."},{"key":"150505_CR35","doi-asserted-by":"publisher","first-page":"4535","DOI":"10.1002\/chem.200500106","volume":"11","author":"V W-W Yam","year":"2005","unstructured":"V. W.-W. Yam, K. H.-Y. Chan, K. M.-C. Wong and N. Zhu, Luminescent Platinum(II) Terpyridyl Complexes: Effect of Counter Ions on Solvent-Induced Aggregation and Color Changes, Chem.\u2013Eur. J., 2005, 11, 4535\u20134543.","journal-title":"Chem.\u2013Eur. J."},{"key":"150505_CR36","doi-asserted-by":"publisher","first-page":"4577","DOI":"10.1002\/chem.200800276","volume":"14","author":"C Yu","year":"2008","unstructured":"C. Yu, K. H.-Y. Chan, K. M.-C. Wong and V. W.-W. Yam, Polyelectrolyte-Induced Self-Assembly of Positively Charged Alkynylplatinum(II)\u2013Terpyridyl Complexes in Aqueous Media, Chem.\u2013Eur. J., 2008, 14, 4577\u20134584.","journal-title":"Chem.\u2013Eur. J."},{"key":"150505_CR37","doi-asserted-by":"publisher","first-page":"4480","DOI":"10.1021\/j100720a004","volume":"74","author":"E P Kirby","year":"1970","unstructured":"E. P. Kirby and R. F. Steiner, Influence of solvent and temperature upon the fluorescence of indole derivatives, J. Phys. Chem., 1970, 74, 4480\u20134490.","journal-title":"J. Phys. Chem."}],"container-title":["Photochemical & Photobiological Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1039\/c6pp00057f.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1039\/c6pp00057f\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2016\/PP\/C6PP00057F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1039\/c6pp00057f.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T15:04:21Z","timestamp":1667401461000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1039\/c6pp00057f"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,5]]},"references-count":37,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2016,5]]}},"alternative-id":["150505"],"URL":"https:\/\/doi.org\/10.1039\/c6pp00057f","relation":{},"ISSN":["1474-905X","1474-9092"],"issn-type":[{"type":"print","value":"1474-905X"},{"type":"electronic","value":"1474-9092"}],"subject":[],"published":{"date-parts":[[2016,5]]},"assertion":[{"value":"26 February 2016","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"2 April 2016","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"1 May 2016","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}}]}}