{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T15:50:52Z","timestamp":1760889052095},"reference-count":0,"publisher":"Portland Press Ltd.","issue":"5","content-domain":{"domain":["portlandpress.com"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[1971,10,1]]},"abstract":"<jats:p>The biosynthesis of the cyanogenic glucosides, linamarin and prunasin, was investigated in linen-flax, peach and cherry-laurel shoots. It was shown that related 2-oximino acids, aldoximes, nitriles and 2-hydroxynitriles were generally good precursors of the aglycone moiety. Studies with double-labelled compounds confirmed the retention of the oximino nitrogen atom from 2-oximinoisovaleric acid and isobutyraldoxime in the biosynthesis of linamarin. A general pathway from amino acids to cyanogenic glucosides involving N-hydroxyamino acids, aldoximes, nitriles and 2-hydroxynitriles is proposed.<\/jats:p>","DOI":"10.1042\/bj1240935","type":"journal-article","created":{"date-parts":[[2015,8,13]],"date-time":"2015-08-13T21:37:43Z","timestamp":1439501863000},"page":"935-941","update-policy":"http:\/\/dx.doi.org\/10.1042\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Oximes, nitriles and 2-hydroxynitriles as precursors in the biosynthesis of cyanogenic glucosides"],"prefix":"10.1042","volume":"124","author":[{"given":"B. A.","family":"Tapper","sequence":"first","affiliation":[{"name":"Applied Biochemistry Division, Department of Scientific and Industrial Research, Palmerston North, New Zealand"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G. W.","family":"Butler","sequence":"additional","affiliation":[{"name":"Applied Biochemistry Division, Department of Scientific and Industrial Research, Palmerston North, New Zealand"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"288","container-title":["Biochemical Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/portlandpress.com\/biochemj\/article-pdf\/124\/5\/935\/773756\/bj1240935.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/portlandpress.com\/biochemj\/article-pdf\/124\/5\/935\/773756\/bj1240935.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,11,26]],"date-time":"2021-11-26T15:35:03Z","timestamp":1637940903000},"score":1,"resource":{"primary":{"URL":"https:\/\/portlandpress.com\/biochemj\/article\/124\/5\/935\/8334\/Oximes-nitriles-and-2-hydroxynitriles-as"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1971,10,1]]},"references-count":0,"journal-issue":{"issue":"5","published-print":{"date-parts":[[1971,10,1]]}},"URL":"https:\/\/doi.org\/10.1042\/bj1240935","relation":{},"ISSN":["0306-3283"],"issn-type":[{"value":"0306-3283","type":"print"}],"subject":[],"published":{"date-parts":[[1971,10,1]]}}}