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By analyzing two nights of observations using the ESPRESSO high-resolution spectrograph, we studied the architecture and atmosphere of hot Jupiter WASP-122b (KELT-14b). By analyzing the Rossiter-McLaughlin (RM) effect, we measured the spin-orbit angle of the system to be <jats:italic>\u03bb<\/jats:italic> = 0.09<jats:sub>\u22120.90<\/jats:sub><jats:sup>+0.88<\/jats:sup> deg. This result is in line with literature obliquity measurements of planetary systems around stars with effective temperatures cooler than 6500 K. Using the transmission spectroscopy, we studied the atmosphere of the planet. Applying both the single-line analysis and the cross-correlation method, we looked for Ca <jats:sc>I<\/jats:sc>, Cr <jats:sc>I<\/jats:sc>, FeH, Fe <jats:sc>I<\/jats:sc>, Fe <jats:sc>II<\/jats:sc>, H<jats:sub>2<\/jats:sub>O, Li <jats:sc>I<\/jats:sc>, Mg <jats:sc>I<\/jats:sc>, Na <jats:sc>I<\/jats:sc>, Ti <jats:sc>I<\/jats:sc>, TiO, V <jats:sc>I<\/jats:sc>, VO, and Y <jats:sc>I<\/jats:sc>. 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