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Activation of the benzylboronic ester is achieved by irreversible coordination of an alkyllithium Lewis base to form a nucleophilic benzylboronate. This boronate was found to react with aldehydes, imines, ketones, and alkyl bromides. A copper catalyst was employed in reactions of the boronate with epoxides and aziridines.<\/jats:p><jats:p>1 \tIntroduction<\/jats:p><jats:p>2 \t1,2-Additions<\/jats:p><jats:p>3 \tAdditions to sp3 Electrophiles<\/jats:p><jats:p>4 \tConclusion and Outlook<\/jats:p>","DOI":"10.1055\/a-2072-2754","type":"journal-article","created":{"date-parts":[[2023,4,12]],"date-time":"2023-04-12T23:08:28Z","timestamp":1681340908000},"page":"2639-2647","source":"Crossref","is-referenced-by-count":1,"title":["Reactions of Benzylboronate Nucleophiles"],"prefix":"10.1055","volume":"55","author":[{"given":"Timothy J.","family":"Barker","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrew","family":"Bogatkevich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dallas W.","family":"Crowder","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sophia G.","family":"Gierszal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jacob C.","family":"Hayes","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael R.","family":"Hollerbach","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Richard W.","family":"Russell","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"194","published-online":{"date-parts":[[2023,5,8]]},"reference":[{"key":"ref1","doi-asserted-by":"crossref","first-page":"6722","DOI":"10.1002\/anie.201101379","volume":"50","author":"A Suzuki","year":"2011","journal-title":"Angew. 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