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This straightforward transformation proceeds by reaction of primary amides, carbamates, sulfonamides, sulfinamides, and ureas with stable N-thiosuccinimides or N-thiophthalimides, which in turn are prepared in a single step from commercial thiols. The use of stable N-thiosuccinimide and N-thiophthalimide reactants is desirable because it obviates the use of highly reactive sulfenyl chlorides.<\/jats:p>","DOI":"10.1055\/s-0041-1738430","type":"journal-article","created":{"date-parts":[[2022,12,21]],"date-time":"2022-12-21T00:19:51Z","timestamp":1671581991000},"page":"2353-2360","source":"Crossref","is-referenced-by-count":22,"title":["Synthesis of N-Acylsulfenamides from Amides and N-Thiosuccinimides"],"prefix":"10.1055","volume":"55","author":[{"given":"Jessica T.","family":"Liu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2962-3175","authenticated-orcid":false,"given":"Daniel S.","family":"Brandes","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9320-5512","authenticated-orcid":false,"given":"Jonathan A.","family":"Ellman","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nathaniel S.","family":"Greenwood","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"194","published-online":{"date-parts":[[2022,12,20]]},"reference":[{"key":"ref1","doi-asserted-by":"crossref","first-page":"689","DOI":"10.1021\/cr00094a001","volume":"89","author":"L Craine","year":"1989","journal-title":"Chem. 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