{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,20]],"date-time":"2025-09-20T19:14:34Z","timestamp":1758395674598},"reference-count":103,"publisher":"AIP Publishing","issue":"2","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2004,1,8]]},"abstract":"<jats:p>An experimental technique based on a scheme of vibrationally mediated photodissociation has been developed and applied to the spectroscopic study of highly excited vibrational states in HCN, with energies between 29\u200a000 and 30\u200a000 cm\u22121. The technique consists of four sequential steps: in the first one, a high power laser is used to vibrationally excite the sample to an intermediate state, typically (0,0,4), the \u03bd3 mode being approximately equivalent to the C\u2013H stretching vibration. Then a second laser is used to search for transitions between this intermediate state and highly vibrationally excited states. When one of these transitions is found, HCN molecules are transferred to a highly excited vibrational state. Third, a ultraviolet laser photodissociates the highly excited molecules to produce H and CN radicals in its A\u200a2\u03a0 electronic state. Finally, a fourth laser (probe) detects the presence of the CN(A) photofragments by means of an A\u2192B\u2192X laser induced fluorescence scheme. The spectra obtained with this technique, consisting of several rotationally resolved vibrational bands, have been analyzed. The positions and rotational parameters of the states observed are presented and compared with the results of a state-of-the-art variational calculation.<\/jats:p>","DOI":"10.1063\/1.1631253","type":"journal-article","created":{"date-parts":[[2003,12,24]],"date-time":"2003-12-24T23:00:45Z","timestamp":1072306845000},"page":"691-703","update-policy":"http:\/\/dx.doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":11,"title":["Spectroscopy of highly excited vibrational states of HCN in its ground electronic state"],"prefix":"10.1063","volume":"120","author":[{"given":"R. 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