{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,28]],"date-time":"2025-09-28T12:45:26Z","timestamp":1759063526766,"version":"3.41.2"},"reference-count":74,"publisher":"AIP Publishing","issue":"2","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2005,1,8]]},"abstract":"<jats:p>Binary complexes containing hydrogen cyanide and hydrogen fluoride are formed in helium nanodroplets, and studied using high-resolution infrared laser spectroscopy. Rotationally resolved spectra are reported for the H\u2013F and C\u2013H stretches of the linear HCN\u2013HF complex, a system that has been thoroughly studied in the gas phase. We report the high-resolution spectra of the higher energy, bent HF\u2013HCN isomer, which is also formed in helium. Stark spectra are reported for both isomers, providing dipole moments of these complexes. The experimental results are compared with ab initio calculations, also reported here. Spectra are reported for several ternary complexes, including (HCN)2\u2013HF,\u2008HCN\u2013(HF)2,\u2008HF\u2013(HCN)2, and HF\u2013HCN\u2013HF.<\/jats:p>","DOI":"10.1063\/1.1828047","type":"journal-article","created":{"date-parts":[[2004,12,27]],"date-time":"2004-12-27T00:01:28Z","timestamp":1104105688000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":34,"title":["The isomers of HF\u2013HCN formed in helium nanodroplets: Infrared spectroscopy and <i>ab initio<\/i> calculations"],"prefix":"10.1063","volume":"122","author":[{"given":"G. E.","family":"Douberly","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina\u200927599"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"R. E.","family":"Miller","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina\u200927599"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2004,12,21]]},"reference":[{"key":"2023070200164123300_r1","doi-asserted-by":"crossref","first-page":"440","DOI":"10.1063\/1.471897","volume":"105","year":"1996","journal-title":"J. Chem. Phys."},{"key":"2023070200164123300_r2","doi-asserted-by":"crossref","first-page":"6007","DOI":"10.1063\/1.464841","volume":"98","year":"1993","journal-title":"J. Chem. Phys."},{"key":"2023070200164123300_r3","doi-asserted-by":"crossref","first-page":"9130","DOI":"10.1063\/1.472747","volume":"105","year":"1996","journal-title":"J. Chem. Phys."},{"key":"2023070200164123300_r4","doi-asserted-by":"crossref","first-page":"8527","DOI":"10.1063\/1.473908","volume":"106","year":"1997","journal-title":"J. Chem. 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