{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T10:45:55Z","timestamp":1753872355254,"version":"3.41.2"},"reference-count":62,"publisher":"AIP Publishing","issue":"20","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2005,11,22]]},"abstract":"<jats:p>The lifetimes of the hydroxyl stretch fundamentals of two methanol isotopomers, MeOH and MeOD, in carbon tetrachloride solvent are calculated through the use of the perturbative Landau-Teller and fluctuating Landau-Teller methods. Examination of these systems allows for insight into the nature of the vibrational couplings that lead to intramolecular vibrational energy transfer. While both systems display energy transfer to nearly degenerate modes, MeOD also displays strong coupling to an off-resonant vibration. The relaxation of MeOH and MeOD occurs through transitions involving a total change in the vibrational quanta of 4 and 3, respectively. We calculate vibrational energy relaxation lifetimes of 4\u20135 ps for MeOH and 2\u20133 ps for MeOD that agree well with the experimentally determined values.<\/jats:p>","DOI":"10.1063\/1.2131055","type":"journal-article","created":{"date-parts":[[2005,11,28]],"date-time":"2005-11-28T23:03:50Z","timestamp":1133219030000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":14,"title":["Vibrational energy relaxation of the OH(D) stretch fundamental of methanol in carbon tetrachloride"],"prefix":"10.1063","volume":"123","author":[{"given":"Tolga S.","family":"Gulmen","sequence":"first","affiliation":[{"name":"Department of Chemistry and Theoretical Chemistry Institute , , Madison, Wisconsin 53706"},{"name":"University of Wisconsin-Madison , , Madison, Wisconsin 53706"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"suffix":"III","given":"Edwin L.","family":"Sibert","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Theoretical Chemistry Institute , , Madison, Wisconsin 53706"},{"name":"University of Wisconsin-Madison , , Madison, Wisconsin 53706"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2005,11,30]]},"reference":[{"key":"2023073102225031800_c1","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1002\/jrs.1250260302","volume":"26","year":"1995","journal-title":"J. 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