{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T10:46:41Z","timestamp":1753872401472,"version":"3.41.2"},"reference-count":43,"publisher":"AIP Publishing","issue":"8","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2006,2,28]]},"abstract":"<jats:p>The A\u0303\u03a0u2\u2212X\u0303\u03a0g2 electronic band system of the jet-cooled CS2+ ion has been studied by laser-induced fluorescence and wavelength-resolved emission techniques. The ions were produced in a pulsed electric discharge jet using a precursor mixture of carbon disulfide vapor in high-pressure argon. Rotational analysis of the high-resolution spectrum of the \u03a03\u221522 component of the 000 band gave linear-molecule molecular structures of r0\u2033=1.5554(10)\u00c5 and r0\u2032=1.6172(12)\u00c5. Renner-Teller analyses of the vibronic structure in the spectra showed that the ground-state spin-orbit splitting (A=\u2212447.0cm\u22121) is much larger than that of the excited state (A=\u2212177.5cm\u22121), but that the Renner-Teller parameters are of similar magnitude and that a strong \u03bd1\u22122\u03bd2 Fermi resonance occurs in both states. Previous analyses of the vibronic structure in the ground and excited states of the ion from pulsed field-ionization\u2013photoelectron data are shown to be substantially correct.<\/jats:p>","DOI":"10.1063\/1.2172612","type":"journal-article","created":{"date-parts":[[2006,2,23]],"date-time":"2006-02-23T23:03:25Z","timestamp":1140735805000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":13,"title":["The molecular structure and a Renner-Teller analysis of the ground and first excited electronic states of the jet-cooled CS2+ molecular ion"],"prefix":"10.1063","volume":"124","author":[{"given":"Sheng-Gui","family":"He","sequence":"first","affiliation":[{"name":"University of Kentucky Department of Chemistry, , Lexington, Kentucky 40506-0055"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dennis J.","family":"Clouthier","sequence":"additional","affiliation":[{"name":"University of Kentucky Department of Chemistry, , Lexington, Kentucky 40506-0055"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2006,2,27]]},"reference":[{"key":"2023070402375360900_c1","doi-asserted-by":"crossref","first-page":"220","DOI":"10.1098\/rspa.1958.0038","volume":"244","year":"1958","journal-title":"Proc. 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