{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T14:07:40Z","timestamp":1761487660896,"version":"3.41.2"},"reference-count":47,"publisher":"AIP Publishing","issue":"5","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2006,8,7]]},"abstract":"<jats:p>The two-photon-resonant first hyperpolarizabilities associated with hyper-Rayleigh and hyper-Raman scattering are reported for 4-dimethylamino-4\u2032-nitrostilbene in 1,4-dioxane, dichloromethane, acetonitrile, and methanol, and for an ionic analog, 4-N,N-bis(6\u2033-(N,N,N-trimethylammonium)-hexyl)amino-4\u2032-nitrostilbene dibromide in methanol and water. Resonance Raman and hyper-Raman excitation profiles are also measured and modeled. The resonance Raman and hyper-Raman spectra show very similar relative intensities which do not vary much as the excitation frequency is tuned across the lowest-energy strong linear absorption band, suggesting that a single resonant electronic state dominates the one- and two-photon absorptions in this region. The absorption, resonance Raman, and hyper-Raman profiles can be simulated reasonably well with a common set of parameters. The peak resonant \u2223\u03b2\u22232, measured by hyper-Rayleigh scattering, varies by about 50% over the range of solvents examined and shows a weak correlation with the linear absorption maximum, with the redder-absorbing systems exhibiting larger peak hyperpolarizabilities. The experimental hyper-Rayleigh intensities are higher than those calculated, possibly reflecting contributions from nonresonant electronic states.<\/jats:p>","DOI":"10.1063\/1.2227028","type":"journal-article","created":{"date-parts":[[2006,8,5]],"date-time":"2006-08-05T01:35:36Z","timestamp":1154741736000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":26,"title":["Solvent effects on resonant first hyperpolarizabilities and Raman and hyper-Raman spectra of DANS and a water-soluble analog"],"prefix":"10.1063","volume":"125","author":[{"given":"Lian C. T.","family":"Shoute","sequence":"first","affiliation":[{"name":"University of California School of Natural Sciences, , Merced, Merced, California 95340"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Han Young","family":"Woo","sequence":"additional","affiliation":[{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Doojin","family":"Vak","sequence":"additional","affiliation":[{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guillermo C.","family":"Bazan","sequence":"additional","affiliation":[{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"},{"name":"University of California Department of Chemistry, , Santa Barbara, California 93106; Department of Materials, , Santa Barbara, California 93106; and Institute for Polymers and Organic Solids, , Santa Barbara, California 93106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anne","family":"Myers Kelley","sequence":"additional","affiliation":[{"name":"University of California School of Natural Sciences, , Merced, Merced, California 95340"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2006,8,2]]},"reference":[{"key":"2023073120184041200_c1","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1016\/S0301-0104(99)00079-8","volume":"245","year":"1999","journal-title":"Chem. 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