{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T18:20:34Z","timestamp":1760898034271,"version":"3.41.2"},"reference-count":41,"publisher":"AIP Publishing","issue":"9","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2010,9,7]]},"abstract":"<jats:p>Double photoionization spectra of the CS2 molecule have been recorded using the TOF-PEPECO technique in combination with synchrotron radiation at the photon energies h\u03bd=220, 230, 240, 243, and 362.7 eV. The spectra were recorded in the S 2p and C 1s inner-shell ionization regions and reflect dicationic states formed out of one inner-shell vacancy and one vacancy in the valence region. MCSCF calculations were performed to model the energies of the dicationic states. The spectra associated with a S 2p vacancy are well structured and have been interpreted in some detail by comparison to conventional S 2p and valence photoelectron spectra. The lowest inner-shell-valence dicationic state is observed at the vertical double ionization energy 188.45 eV and is associated with a (2p3\/2)\u22121(2\u03c0g)\u22121 double vacancy. The spectrum connected to the C 1s vacancy shows a distinct line at 310.8 eV, accompanied by additional broad features at higher double ionization energies. This line is associated with a (C\u20021s)\u22121(2\u03c0g)\u22121 double vacancy.<\/jats:p>","DOI":"10.1063\/1.3469812","type":"journal-article","created":{"date-parts":[[2010,9,7]],"date-time":"2010-09-07T22:30:58Z","timestamp":1283898658000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":13,"title":["Core-valence double photoionization of the CS2 molecule"],"prefix":"10.1063","volume":"133","author":[{"given":"E.","family":"Andersson","sequence":"first","affiliation":[{"name":"Uppsala University 1 Department of Physics and Astronomy, , Box 516, SE-751 20 Uppsala, Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J.","family":"Niskanen","sequence":"additional","affiliation":[{"name":"University of Oulu 2 Department of Physics, , Box 3000, 90014 Oulu, Finland"},{"name":"Royal Institute of Technology 3 Department of Theoretical Chemistry, School of Biotechnology, , SE-106 91 Stockholm , Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"L.","family":"Hedin","sequence":"additional","affiliation":[{"name":"Uppsala University 1 Department of Physics and Astronomy, , Box 516, SE-751 20 Uppsala, Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J. 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