{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T12:07:01Z","timestamp":1761394021499,"version":"3.41.2"},"reference-count":34,"publisher":"AIP Publishing","issue":"9","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2011,3,7]]},"abstract":"<jats:p>Electron attachment to POCl3 was studied in the bath gas He over the pressure range 0.4\u20133.1 Torr and the temperature range 300\u20131210 K. Branching fractions of POCl3\u2212, POCl2\u2212, Cl\u2212, and Cl2\u2212 were measured. The results are analyzed by kinetic modeling, using electron attachment theory for the characterization of the nonthermal energy distribution of the excited POCl3\u2212* anions formed and chemical activation-type unimolecular rate theory for the subsequent competition between collisional stabilization of POCl3\u2212* and its dissociation to various dissociation products. Primary and secondary dissociations and\/or thermal dissociations of the anions are identified. The measured branching fractions are found to be consistent with the modeling results based on molecular parameters obtained from quantum-chemical calculations.<\/jats:p>","DOI":"10.1063\/1.3549139","type":"journal-article","created":{"date-parts":[[2011,3,4]],"date-time":"2011-03-04T16:37:27Z","timestamp":1299256647000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":20,"title":["Electron attachment to POCl3. III. 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