{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T22:28:53Z","timestamp":1790807333069,"version":"4.1.0"},"reference-count":42,"publisher":"AIP Publishing","issue":"14","funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CBET-0756144"],"award-info":[{"award-number":["CBET-0756144"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-0741936"],"award-info":[{"award-number":["CHE-0741936"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2011,10,14]]},"abstract":"<jats:p>The pulsed laser photolysis\/resonance fluorescence technique was used to study the reaction of S(3PJ) with CS2 in an Ar bath gas. Over 290\u2013770 K pressure-dependent kinetics were observed and low- and high-pressure limiting rate constants were derived as k0 = (11.5\u20130.0133 T\/K) \u00d7 10\u221231 cm6 molecule\u22122 s\u22121 (error limits \u00b1 20%) and k\u221e = (2.2 \u00b1 0.6) \u00d7 10\u221212 cm3 molecule\u22121 s\u22121. Equilibration observed at 690\u2013770 K yields a CS2\u2013S bond dissociation enthalpy of 131.7 \u00b1 4.0 kJ mol\u22121 at 298 K. This agrees with computed thermochemistry for a spin-forbidden C2V adduct, estimated at the coupled-cluster single double triple level extrapolated to the infinite basis set limit. A pressure-independent pathway, assigned to abstraction, was observed from 690 to 1040 K and can be summarized as 1.14 \u00d7 10\u221210 exp(\u221237.0 kJ mol\u22121\/RT) cm3 molecule\u22121 s\u22121 with error limits of \u00b1 40%. 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