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By comparison with 1H spin-lattice relaxation results for pure glycerol, it has been demonstrated that the inter-molecular electron spin\u2013proton spin dipole-dipole interactions are affected not only by relative translational motion of the solvent and solute molecules, but also by their rotational dynamics as the interacting spins are displaced from the molecular centers; the eccentricity effects are usually not taken into account. The 1H relaxation data have been decomposed into translational and rotational contributions and their relative importance as a function of frequency and temperature discussed in detail. It has been demonstrated that neglecting the rotational effects on the inter-molecular interactions leads to non-realistic conclusions regarding the translational dynamics of the paramagnetic molecules.<\/jats:p>","DOI":"10.1063\/1.3692603","type":"journal-article","created":{"date-parts":[[2012,3,15]],"date-time":"2012-03-15T15:13:30Z","timestamp":1331824410000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":15,"title":["1H NMR relaxation in glycerol solutions of nitroxide radicals: Effects of translational and rotational dynamics"],"prefix":"10.1063","volume":"136","author":[{"given":"D.","family":"Kruk","sequence":"first","affiliation":[{"name":"University of Warmia and Mazury in Olsztyn 1 Faculty of Mathematics and Computer Science, , Sloneczna 54, PL-10710 Olsztyn, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A.","family":"Korpala","sequence":"additional","affiliation":[{"name":"Jagiellonian University 2 Institute of Physics, , Reymonta 4, 30-059 Krakow, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"E.","family":"R\u00f6ssler","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Bayreuth 3 Experimentalphysik II, , 95440 Bayreuth, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K. 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