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The analysis suggests that electronic and nuclear contributions to the rate constants can be roughly separated, the former leading to a negative temperature coefficient, the latter to a positive temperature coefficient. The nuclear factor in the rate constant is found to be of Arrhenius form with an activation energy which is close to the energy of crossing of the CF3Br and CF3Br\u2212 potential curves along the CBr bond.<\/jats:p>","DOI":"10.1063\/1.4729369","type":"journal-article","created":{"date-parts":[[2012,7,11]],"date-time":"2012-07-11T22:55:47Z","timestamp":1342047347000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":12,"title":["Analysis by kinetic modeling of the temperature dependence of thermal electron attachment to CF3Br"],"prefix":"10.1063","volume":"137","author":[{"given":"J\u00fcrgen","family":"Troe","sequence":"first","affiliation":[{"name":"Universit\u00e4t G\u00f6ttingen 1 Institut f\u00fcr Physikalische Chemie, , Tammannstrasse 6, D-37077 G\u00f6ttingen, Germany"},{"name":"Max-Planck-Institut f\u00fcr Biophysikalische Chemie 2 , Am Fassberg 11, D-37077 G\u00f6ttingen, Germany"},{"name":"Laser-Laboratorium G\u00f6ttingen 3 , Hans-Adolf-Krebs-Weg 1, D-37077 G\u00f6ttingen, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thomas M.","family":"Miller","sequence":"additional","affiliation":[{"name":"Air Force Research Laboratory 4 , Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117-5776, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nicholas S.","family":"Shuman","sequence":"additional","affiliation":[{"name":"Air Force Research Laboratory 4 , Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117-5776, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Albert A.","family":"Viggiano","sequence":"additional","affiliation":[{"name":"Air Force Research Laboratory 4 , Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117-5776, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2012,7,10]]},"reference":[{"key":"2023070122513856800_c1","doi-asserted-by":"publisher","first-page":"054306","DOI":"10.1063\/1.3614471","volume":"135","year":"2011","journal-title":"J. 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