{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T16:21:25Z","timestamp":1787502085743,"version":"build-2736575974"},"reference-count":67,"publisher":"AIP Publishing","issue":"18","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2013,5,14]]},"abstract":"<jats:p>Anions populate fluid interfaces specifically. Here, we report experiments showing that on hydrogen-bonded interfaces anions interact specifically over unexpectedly long distances. The composition of binary electrolyte (Na+, X\u2212\/Y\u2212) films was investigated as a function of solvent, film thickness, and third ion additions in free-standing films produced by blowing up drops with a high-speed gas. These films soon fragment into charged sub-micrometer droplets carrying excess anions detectable in situ by online electrospray ionization mass spectrometry. We found that (1) the larger anions are enriched in the thinner (nanoscopic air-liquid-air) films produced at higher gas velocities in all (water, methanol, 2-propanol, and acetonitrile) tested solvents, (2) third ions (beginning at sub-\u03bcM levels) specifically perturb X\u2212\/Y\u2212 ratios in water and methanol but have no effect in acetonitrile or 2-propanol. Thus, among these polar organic liquids (of similar viscosities but much smaller surface tensions and dielectric permittivities than water) only on methanol do anions interact specifically over long, viz.: \u27e8ri \u2212 rj\u27e9\/nm = 150 (c\/\u03bcM)\u22121\/3, distances. Our findings point to the extended hydrogen-bond networks of water and methanol as likely conduits for such interactions.<\/jats:p>","DOI":"10.1063\/1.4803652","type":"journal-article","created":{"date-parts":[[2013,5,9]],"date-time":"2013-05-09T18:13:24Z","timestamp":1368123204000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":45,"title":["Long-range specific ion-ion interactions in hydrogen-bonded liquid films"],"prefix":"10.1063","volume":"138","author":[{"given":"Shinichi","family":"Enami","sequence":"first","affiliation":[{"name":"Kyoto University 1 The Hakubi Center for Advanced Research, , Kyoto 606-8302, Japan ; Research Institute for Sustainable Humanosphere, , Uji 611-0011, Japan ; and PRESTO, , Kawaguchi 332-0012, Japan"},{"name":"Kyoto University 1 The Hakubi Center for Advanced Research, , Kyoto 606-8302, Japan ; Research Institute for Sustainable Humanosphere, , Uji 611-0011, Japan ; and PRESTO, , Kawaguchi 332-0012, Japan"},{"name":"Japan Science and Technology Agency 1 The Hakubi Center for Advanced Research, , Kyoto 606-8302, Japan ; Research Institute for Sustainable Humanosphere, , Uji 611-0011, Japan ; and PRESTO, , Kawaguchi 332-0012, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agust\u00edn J.","family":"Colussi","sequence":"additional","affiliation":[{"name":"California Institute of Technology 2 Ronald and Maxine Linde Center for Global Environmental Science, , California 91125, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2013,5,9]]},"reference":[{"key":"2023080404091948500_c1","doi-asserted-by":"publisher","first-page":"14398","DOI":"10.1021\/jp309157x","volume":"116","year":"2012","journal-title":"J. Phys. Chem. B"},{"key":"2023080404091948500_c2","doi-asserted-by":"publisher","first-page":"7716","DOI":"10.1073\/pnas.0913376107","volume":"107","year":"2010","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c3","doi-asserted-by":"publisher","first-page":"424108","DOI":"10.1088\/0953-8984\/21\/42\/424108","volume":"21","year":"2009","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023080404091948500_c4","doi-asserted-by":"publisher","first-page":"144","DOI":"10.1038\/191144a0","volume":"191","year":"1961","journal-title":"Nature (London)"},{"key":"2023080404091948500_c5","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1557\/mrs.2011.71","volume":"36","year":"2011","journal-title":"MRS Bull."},{"key":"2023080404091948500_c6","doi-asserted-by":"publisher","first-page":"2936","DOI":"10.1039\/c0sm01162b","volume":"7","year":"2011","journal-title":"Soft Matter"},{"key":"2023080404091948500_c7","doi-asserted-by":"publisher","first-page":"8710","DOI":"10.1021\/la2006277","volume":"27","year":"2011","journal-title":"Langmuir"},{"key":"2023080404091948500_c8","doi-asserted-by":"publisher","first-page":"34","DOI":"10.1016\/j.cocis.2009.11.008","volume":"15","year":"2010","journal-title":"Curr. Opin. Colloid Interface Sci."},{"key":"2023080404091948500_c9","doi-asserted-by":"publisher","first-page":"12352","DOI":"10.1039\/c1cp20538b","volume":"13","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023080404091948500_c10","doi-asserted-by":"publisher","first-page":"401","DOI":"10.1146\/annurev-physchem-032511-143813","volume":"63","year":"2012","journal-title":"Annu. Rev. Phys. Chem."},{"key":"2023080404091948500_c11","doi-asserted-by":"publisher","first-page":"154707","DOI":"10.1063\/1.4704752","volume":"136","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c12","doi-asserted-by":"publisher","first-page":"701","DOI":"10.1073\/pnas.1116169109","volume":"109","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c13","doi-asserted-by":"publisher","first-page":"15125","DOI":"10.1073\/pnas.0905168106","volume":"106","year":"2009","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c14","doi-asserted-by":"publisher","first-page":"847","DOI":"10.1126\/science.1097116","volume":"304","year":"2004","journal-title":"Science"},{"key":"2023080404091948500_c15","doi-asserted-by":"publisher","first-page":"17678","DOI":"10.1073\/pnas.1110703108","volume":"108","year":"2011","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c16","doi-asserted-by":"publisher","first-page":"333","DOI":"10.1146\/annurev.physchem.57.032905.104609","volume":"57","year":"2006","journal-title":"Annu. Rev. Phys. Chem."},{"key":"2023080404091948500_c17","doi-asserted-by":"publisher","first-page":"9","DOI":"10.1039\/b816684f","volume":"141","year":"2009","journal-title":"Faraday Discuss."},{"key":"2023080404091948500_c18","volume-title":"Molecular Theory of Capillarity","year":"1989"},{"key":"2023080404091948500_c19","doi-asserted-by":"publisher","first-page":"214711","DOI":"10.1063\/1.3148890","volume":"130","year":"2009","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c20","doi-asserted-by":"publisher","first-page":"10228","DOI":"10.1073\/pnas.1200949109","volume":"109","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c21","doi-asserted-by":"publisher","first-page":"18679","DOI":"10.1073\/pnas.1209307109","volume":"109","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c22","doi-asserted-by":"publisher","first-page":"1599","DOI":"10.1021\/jz100322w","volume":"1","year":"2010","journal-title":"J. Phys. Chem. Lett."},{"key":"2023080404091948500_c23","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1017\/S0022112003006529","volume":"498","year":"2004","journal-title":"J. Fluid Mech."},{"key":"2023080404091948500_c24","doi-asserted-by":"publisher","first-page":"022104","DOI":"10.1063\/1.3680867","volume":"24","year":"2012","journal-title":"Phys. Fluids"},{"key":"2023080404091948500_c25","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1016\/0301-9322(80)90013-0","volume":"6","year":"1980","journal-title":"Int. J. Multiphase Flow"},{"key":"2023080404091948500_c26","doi-asserted-by":"publisher","first-page":"371","DOI":"10.1007\/s00348-008-0593-2","volume":"46","year":"2009","journal-title":"Exp. Fluids"},{"key":"2023080404091948500_c27","doi-asserted-by":"publisher","first-page":"1234","DOI":"10.1007\/s13361-011-0124-x","volume":"22","year":"2011","journal-title":"J. Am. Soc. Mass Spectrom."},{"key":"2023080404091948500_c28","doi-asserted-by":"publisher","first-page":"016318","DOI":"10.1103\/PhysRevE.84.016318","volume":"84","year":"2011","journal-title":"Phys. Rev. E"},{"key":"2023080404091948500_c29","volume-title":"Hydrodynamics","year":"1932","edition":"6th ed."},{"key":"2023080404091948500_c30","doi-asserted-by":"publisher","first-page":"741","DOI":"10.1016\/0301-9322(87)90063-2","volume":"13","year":"1987","journal-title":"Int. J. Multiphase Flow"},{"key":"2023080404091948500_c31","doi-asserted-by":"publisher","first-page":"13352","DOI":"10.1021\/jp806995h","volume":"112","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"2023080404091948500_c32","doi-asserted-by":"publisher","first-page":"5723","DOI":"10.1021\/jp102719s","volume":"115","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"2023080404091948500_c33","doi-asserted-by":"publisher","first-page":"5817","DOI":"10.1021\/jp1019729","volume":"114","year":"2010","journal-title":"J. Phys. Chem. A"},{"key":"2023080404091948500_c34","doi-asserted-by":"publisher","first-page":"2287","DOI":"10.1063\/1.432536","volume":"64","year":"1976","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c35","doi-asserted-by":"publisher","first-page":"1111","DOI":"10.1073\/pnas.0609969104","volume":"104","year":"2007","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c36","doi-asserted-by":"publisher","first-page":"1946","DOI":"10.1021\/jz200791c","volume":"2","year":"2011","journal-title":"J. Phys. Chem. Lett."},{"key":"2023080404091948500_c37","doi-asserted-by":"publisher","first-page":"15446","DOI":"10.1021\/ja053224w","volume":"127","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"2023080404091948500_c38","doi-asserted-by":"publisher","first-page":"114709","DOI":"10.1063\/1.4794688","volume":"138","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c39","doi-asserted-by":"publisher","first-page":"7157","DOI":"10.1021\/jp803184r","volume":"112","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"2023080404091948500_c40","doi-asserted-by":"publisher","first-page":"25598","DOI":"10.1021\/jp066197k","volume":"110","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"2023080404091948500_c41","doi-asserted-by":"publisher","first-page":"313","DOI":"10.1007\/s10955-011-0299-3","volume":"145","year":"2011","journal-title":"J. Stat. Phys."},{"key":"2023080404091948500_c42","doi-asserted-by":"publisher","first-page":"1259","DOI":"10.1021\/cr0403741","volume":"106","year":"2006","journal-title":"Chem. Rev."},{"key":"2023080404091948500_c43","doi-asserted-by":"publisher","first-page":"6838","DOI":"10.1073\/pnas.1017903108","volume":"108","year":"2011","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2023080404091948500_c44","doi-asserted-by":"publisher","first-page":"10778","DOI":"10.1021\/la100604k","volume":"26","year":"2010","journal-title":"Langmuir"},{"key":"2023080404091948500_c45","volume-title":"Intermolecular and Surface Forces","year":"2011","edition":"3rd ed."},{"key":"2023080404091948500_c46","volume-title":"Ion Properties","year":"1997"},{"key":"2023080404091948500_c47","doi-asserted-by":"publisher","first-page":"1316","DOI":"10.1039\/c0nr00698j","volume":"3","year":"2011","journal-title":"Nanoscale"},{"key":"2023080404091948500_c48","doi-asserted-by":"publisher","first-page":"1165","DOI":"10.1119\/1.3467887","volume":"78","year":"2010","journal-title":"Am. J. Phys."},{"key":"2023080404091948500_c49","doi-asserted-by":"publisher","first-page":"5004","DOI":"10.1039\/b808326f","volume":"10","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023080404091948500_c50","doi-asserted-by":"publisher","first-page":"47","DOI":"10.1103\/RevModPhys.74.47","volume":"74","year":"2002","journal-title":"Rev. Mod. Phys."},{"key":"2023080404091948500_c51","doi-asserted-by":"publisher","first-page":"6456","DOI":"10.1063\/1.1789951","volume":"121","year":"2004","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c52","doi-asserted-by":"publisher","first-page":"157401","DOI":"10.1103\/PhysRevLett.91.157401","volume":"91","year":"2003","journal-title":"Phys. Rev. Lett."},{"key":"2023080404091948500_c53","doi-asserted-by":"publisher","first-page":"829","DOI":"10.1038\/416829a","volume":"416","year":"2002","journal-title":"Nature (London)"},{"key":"2023080404091948500_c54","doi-asserted-by":"publisher","first-page":"4403","DOI":"10.1063\/1.1496457","volume":"117","year":"2002","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c55","doi-asserted-by":"publisher","first-page":"6452","DOI":"10.1039\/c0cp01802c","volume":"13","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023080404091948500_c56","doi-asserted-by":"publisher","first-page":"138","DOI":"10.1021\/jp0463464","volume":"109","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"2023080404091948500_c57","doi-asserted-by":"publisher","first-page":"12173","DOI":"10.1021\/jp206875k","volume":"115","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"2023080404091948500_c58","doi-asserted-by":"publisher","first-page":"832","DOI":"10.1126\/science.1122154","volume":"311","year":"2006","journal-title":"Science"},{"key":"2023080404091948500_c59","doi-asserted-by":"publisher","first-page":"6655","DOI":"10.1063\/1.1605093","volume":"119","year":"2003","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c60","doi-asserted-by":"publisher","first-page":"13847","DOI":"10.1021\/ja071933z","volume":"129","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2023080404091948500_c61","doi-asserted-by":"publisher","first-page":"034508","DOI":"10.1063\/1.4735267","volume":"137","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c62","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1007\/s101890170075","volume":"5","year":"2001","journal-title":"Eur. Phys. J. E"},{"key":"2023080404091948500_c63","doi-asserted-by":"publisher","first-page":"114706","DOI":"10.1063\/1.4753986","volume":"137","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023080404091948500_c64","doi-asserted-by":"publisher","first-page":"3260","DOI":"10.1039\/c0sm01057j","volume":"7","year":"2011","journal-title":"Soft Matter"},{"key":"2023080404091948500_c65","doi-asserted-by":"publisher","first-page":"373","DOI":"10.1529\/biophysj.106.087023","volume":"92","year":"2007","journal-title":"Biophys. J."},{"key":"2023080404091948500_c66","doi-asserted-by":"publisher","first-page":"019901","DOI":"10.1103\/PhysRevLett.100.019901","volume":"100","year":"2008","journal-title":"Phys. Rev. Lett."},{"key":"2023080404091948500_c67","doi-asserted-by":"crossref","unstructured":"See supplementary material at http:\/\/dx.doi.org\/10.1063\/1.4803652 for Figures S1 and S3 and Appendixes S1 and S2.","DOI":"10.1063\/1.4803652"}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4803652\/13281038\/184706_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4803652\/13281038\/184706_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,4]],"date-time":"2023-08-04T00:15:56Z","timestamp":1691108156000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/138\/18\/184706\/985749\/Long-range-specific-ion-ion-interactions-in"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,5,9]]},"references-count":67,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2013,5,14]]}},"URL":"https:\/\/doi.org\/10.1063\/1.4803652","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2013,5,14]]},"published":{"date-parts":[[2013,5,9]]},"article-number":"184706"}}