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We present a general recipe for constructing functionals for small-molecular liquids based only on bulk experimental properties and ab initio calculations of a single solvent molecule. This recipe combines the exact free energy of the non-interacting system with fundamental measure theory for the repulsive contribution and a weighted density functional for the short-ranged attractive interactions. We add to these ingredients a weighted polarization functional for the long-range correlations in both the rotational and molecular-polarizability contributions to the dielectric response. We also perform molecular dynamics calculations for the free energy of cavity formation and the high-field dielectric response, and show that our free-energy functional adequately describes these properties (which are key for accurate solvation calculations) for all three solvents in our study: water, chloroform, and carbon tetrachloride.<\/jats:p>","DOI":"10.1063\/1.4870653","type":"journal-article","created":{"date-parts":[[2014,4,14]],"date-time":"2014-04-14T12:24:42Z","timestamp":1397478282000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":30,"title":["A recipe for free-energy functionals of polarizable molecular fluids"],"prefix":"10.1063","volume":"140","author":[{"given":"Ravishankar","family":"Sundararaman","sequence":"first","affiliation":[{"name":"Cornell University Department of Physics, , Ithaca, New York 14853, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kendra","family":"Letchworth-Weaver","sequence":"additional","affiliation":[{"name":"Cornell University Department of Physics, , Ithaca, New York 14853, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"T. 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