{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T11:14:58Z","timestamp":1790421298544,"version":"4.1.0"},"reference-count":40,"publisher":"AIP Publishing","issue":"18","funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR 2011 BS09 002"],"award-info":[{"award-number":["ANR 2011 BS09 002"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2015,5,14]]},"abstract":"<jats:p>Nowadays, it is well established that the physical properties of confined liquids strongly differ from those in bulk phase. While dynamical and structural properties were strongly explored, dielectric properties are poorly studied despite their importance in the understanding and the modelling of molecular mechanism in a number of nano-applications such as nanofluidics, nanofiltration, and nanomedicine. Among them, the dielectric permittivity is probably one of the most important. The lack of knowledge about it strongly limits our ability to model fluid-material interactions and more generally our understanding of the behaviour of confined fluids. Recently, the dielectric permittivity of confined water in silica, Metal Organic Frameworks, and graphene materials was found to be slightly higher than the permittivity of water in bulk phase. In this work, the permittivity of water and dichloromethane confined in carbon nanotubes was predicted by means of molecular dynamics simulations. The static dielectric constant was found to be 700, i.e., 10-fold higher than the bulk value. This superpermittivity has, for origin, the excluded volume and the presence of an unconfined direction leading to a pre-orientation of water molecules close to the pore wall and an increase in dipolar fluctuations.<\/jats:p>","DOI":"10.1063\/1.4921043","type":"journal-article","created":{"date-parts":[[2015,5,12]],"date-time":"2015-05-12T17:00:22Z","timestamp":1431450022000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":43,"title":["Superpermittivity of nanoconfined water"],"prefix":"10.1063","volume":"142","author":[{"given":"Richard","family":"Renou","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Rennes 1 1 Institut des Sciences Chimiques de Rennes, CNRS, UMR 6226, , 263 Avenue du G\u00e9n\u00e9ral Leclerc, 35042 Rennes, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anthony","family":"Szymczyk","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Rennes 1 1 Institut des Sciences Chimiques de Rennes, CNRS, UMR 6226, , 263 Avenue du G\u00e9n\u00e9ral Leclerc, 35042 Rennes, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guillaume","family":"Maurin","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Montpellier 2 2 Institut Charles Gerhardt Montpellier UMR 5253 CNRS UM2, UM1, , Place E. Bataillon, 34095 Montpellier Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrice","family":"Malfreyt","sequence":"additional","affiliation":[{"name":"Institut de Chimie de Clermont-Ferrand, ICCF 3 , UMR CNRS 6296, BP 10448, F-63000 Clermont-Ferrand, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aziz","family":"Ghoufi","sequence":"additional","affiliation":[{"name":"Institut de Physique de Rennes, IPR 4 , UMR CNRS 6251, 263 Avenue du G\u00e9n\u00e9ral Leclerc, 35042 Rennes, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2015,5,12]]},"reference":[{"key":"2023062609352523500_c1","doi-asserted-by":"publisher","first-page":"R15","DOI":"10.1088\/0953-8984\/18\/6\/R01","volume":"18","year":"2006","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023062609352523500_c2","doi-asserted-by":"publisher","first-page":"1478","DOI":"10.1021\/cr040376l","volume":"106","year":"2006","journal-title":"Chem. Rev."},{"key":"2023062609352523500_c3","doi-asserted-by":"publisher","first-page":"939","DOI":"10.1524\/zpch.2009.6064","volume":"223","year":"2009","journal-title":"Z. Phys. Chem."},{"key":"2023062609352523500_c4","doi-asserted-by":"publisher","first-page":"6646","DOI":"10.1073\/pnas.1221581110","volume":"110","year":"2013","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023062609352523500_c5","doi-asserted-by":"publisher","first-page":"247401","DOI":"10.1103\/PhysRevLett.98.247401","volume":"98","year":"2007","journal-title":"Phys. Rev. Lett."},{"key":"2023062609352523500_c6","doi-asserted-by":"publisher","first-page":"3931","DOI":"10.1021\/jp4118419","volume":"118","year":"2014","journal-title":"J. Phys. Chem. B"},{"key":"2023062609352523500_c7","doi-asserted-by":"publisher","first-page":"5084","DOI":"10.1021\/la804062e","volume":"25","year":"2009","journal-title":"Langmuir"},{"key":"2023062609352523500_c8","doi-asserted-by":"publisher","first-page":"4067","DOI":"10.1021\/nl1021046","volume":"10","year":"2010","journal-title":"Nano Lett."},{"key":"2023062609352523500_c9","doi-asserted-by":"publisher","first-page":"44","DOI":"10.1038\/438044a","volume":"438","year":"2005","journal-title":"Nature"},{"key":"2023062609352523500_c10","doi-asserted-by":"publisher","first-page":"1034","DOI":"10.1126\/science.1126298","volume":"312","year":"2006","journal-title":"Science"},{"key":"2023062609352523500_c11","doi-asserted-by":"publisher","first-page":"2632","DOI":"10.1021\/nl080705f","volume":"8","year":"2008","journal-title":"Nano Lett."},{"key":"2023062609352523500_c12","doi-asserted-by":"publisher","first-page":"6872","DOI":"10.1021\/nl502837d","volume":"14","year":"2014","journal-title":"Nano Lett."},{"key":"2023062609352523500_c13","doi-asserted-by":"publisher","first-page":"3602","DOI":"10.1021\/nl3012853","volume":"12","year":"2012","journal-title":"Nano Lett."},{"key":"2023062609352523500_c14","doi-asserted-by":"publisher","first-page":"6171","DOI":"10.1021\/nl502399y","volume":"14","year":"2014","journal-title":"Nano Lett."},{"key":"2023062609352523500_c15","doi-asserted-by":"publisher","first-page":"3910","DOI":"10.1021\/la051888d","volume":"22","year":"2006","journal-title":"Langmuir"},{"key":"2023062609352523500_c16","doi-asserted-by":"publisher","first-page":"245","DOI":"10.1016\/j.jcis.2007.02.005","volume":"309","year":"2007","journal-title":"J. Colloid Interface Sci."},{"key":"2023062609352523500_c17","doi-asserted-by":"publisher","first-page":"045419","DOI":"10.1103\/PhysRevB.80.045419","volume":"80","year":"2009","journal-title":"Phys. Rev. B"},{"key":"2023062609352523500_c18","doi-asserted-by":"publisher","first-page":"1279","DOI":"10.1021\/nn900221t","volume":"3","year":"2009","journal-title":"ACS Nano"},{"key":"2023062609352523500_c19","doi-asserted-by":"publisher","first-page":"7967","DOI":"10.1021\/jp3120435","volume":"117","year":"2013","journal-title":"J. Phys. Chem. B"},{"key":"2023062609352523500_c20","doi-asserted-by":"publisher","first-page":"2477","DOI":"10.1021\/jz401108n","volume":"4","year":"2013","journal-title":"J. Phys. Chem. Lett."},{"key":"2023062609352523500_c21","doi-asserted-by":"publisher","first-page":"166102","DOI":"10.1103\/PhysRevLett.107.166102","volume":"107","year":"2011","journal-title":"Phys. Rev. Lett."},{"key":"2023062609352523500_c22","doi-asserted-by":"publisher","first-page":"107801","DOI":"10.1103\/PhysRevLett.109.107801","volume":"109","year":"2013","journal-title":"Phys. Rev. Lett."},{"key":"2023062609352523500_c23","doi-asserted-by":"publisher","first-page":"37008","DOI":"10.1209\/0295-5075\/99\/37008","volume":"99","year":"2012","journal-title":"EPL"},{"key":"2023062609352523500_c24","doi-asserted-by":"publisher","first-page":"089802","DOI":"10.1103\/PhysRevLett.111.089802","volume":"111","year":"2013","journal-title":"Phys. Rev. Lett."},{"key":"2023062609352523500_c25","doi-asserted-by":"publisher","first-page":"11017","DOI":"10.1021\/jp403450x","volume":"117","year":"2013","journal-title":"J. Phys. Chem. C"},{"key":"2023062609352523500_c26","doi-asserted-by":"publisher","first-page":"483","DOI":"10.1080\/08927022.2014.958484","volume":"41","year":"2014","journal-title":"Mol. Simul."},{"key":"2023062609352523500_c27","doi-asserted-by":"publisher","first-page":"7679","DOI":"10.1021\/la2051564","volume":"28","year":"2012","journal-title":"Langmuir"},{"key":"2023062609352523500_c28","doi-asserted-by":"publisher","first-page":"6666","DOI":"10.1002\/ange.200501867","volume":"117","year":"2005","journal-title":"Angew. Chem."},{"key":"2023062609352523500_c29","doi-asserted-by":"publisher","first-page":"5736","DOI":"10.1021\/ja200978u","volume":"133","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"2023062609352523500_c30","doi-asserted-by":"publisher","first-page":"1345","DOI":"10.1021\/jp0268112","volume":"107","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"2023062609352523500_c31","doi-asserted-by":"publisher","first-page":"6638","DOI":"10.1021\/ja00334a030","volume":"106","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"2023062609352523500_c32","doi-asserted-by":"publisher","first-page":"141","DOI":"10.1016\/0301-0104(82)87074-2","volume":"72","year":"1982","journal-title":"Chem. Phys."},{"key":"2023062609352523500_c33","volume-title":"DLPOLY, CCP5 Program Library","year":"2014"},{"key":"2023062609352523500_c34","doi-asserted-by":"publisher","first-page":"1695","DOI":"10.1103\/PhysRevA.31.1695","volume":"31","year":"1985","journal-title":"Phys. Rev. A"},{"key":"2023062609352523500_c35","volume-title":"Computer Simulation of Liquids","year":"1987"},{"key":"2023062609352523500_c36","doi-asserted-by":"publisher","first-page":"114711","DOI":"10.1063\/1.1845431","volume":"122","year":"2005","journal-title":"J. Chem. Phys."},{"key":"2023062609352523500_c37","unstructured":"See supplementary material at http:\/\/dx.doi.org\/10.1063\/1.4921043   for radial profiles of density and axial dielectric permittivity of confined water for various thicknesses of cylindrical shell."},{"key":"2023062609352523500_c38","doi-asserted-by":"publisher","first-page":"15203","DOI":"10.1021\/jp404702j","volume":"117","year":"2013","journal-title":"J. Phys. Chem. C"},{"key":"2023062609352523500_c39","doi-asserted-by":"publisher","first-page":"1427","DOI":"10.1021\/jp709845u","volume":"112","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"2023062609352523500_c40","doi-asserted-by":"publisher","first-page":"5308","DOI":"10.1021\/nn4011494","volume":"7","year":"2013","journal-title":"ACS Nano"}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4921043\/13689720\/184706_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4921043\/13689720\/184706_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,6,26]],"date-time":"2023-06-26T12:44:13Z","timestamp":1687783453000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/142\/18\/184706\/193723\/Superpermittivity-of-nanoconfined-water"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,5,12]]},"references-count":40,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2015,5,14]]}},"URL":"https:\/\/doi.org\/10.1063\/1.4921043","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2015,5,14]]},"published":{"date-parts":[[2015,5,12]]},"article-number":"184706"}}