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A high resolution photoelectron spectrum using synchrotron radiation is presented. Fragmentation of the molecule is studied subsequent to ionization to the atomic-mercury-like d orbitals. State dependent fragmentation behaviour is presented and specific reactions for dissociation pathways are given. The fragmentation is found to differ distinctly in similar orbitals of different mercury compounds.<\/jats:p>","DOI":"10.1063\/1.4928651","type":"journal-article","created":{"date-parts":[[2015,8,19]],"date-time":"2015-08-19T17:00:20Z","timestamp":1440003620000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["Fragmentation of mercury compounds under ultraviolet light irradiation"],"prefix":"10.1063","volume":"143","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3674-7486","authenticated-orcid":false,"given":"E.","family":"Kokkonen","sequence":"first","affiliation":[{"name":"University of Oulu 1 Centre for Molecular Materials Research, , P.O. Box 3000, 90014 Oulu, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"T.","family":"L\u00f6ytynoja","sequence":"additional","affiliation":[{"name":"University of Oulu 1 Centre for Molecular Materials Research, , P.O. 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