{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,26]],"date-time":"2025-12-26T22:33:43Z","timestamp":1766788423760,"version":"3.41.2"},"reference-count":65,"publisher":"AIP Publishing","issue":"13","funder":[{"name":"king saud university","award":["RGP-VPP-333"],"award-info":[{"award-number":["RGP-VPP-333"]}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["COST ACTION CM 1405","PIRSES-GA-2012-317544"],"award-info":[{"award-number":["COST ACTION CM 1405","PIRSES-GA-2012-317544"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2015,10,7]]},"abstract":"<jats:p>Results are presented that suggest that thiazyl hydride (HSN)\/thionitrosyl hydride (sulfimide, HNS) can be used as light-sensitive compounds for NO-delivery in biological media, as well as markers for the possible detection of intermediates in nitrites + H2S reactions at the cellular level. They are expected to be more efficient than the HNO\/HON isovalent species and hence they should be considered instead. A set of characteristic spectroscopic features are identified that could aid in the possible detection of these species in the gas phase or in biological environments. The possibility of intramolecular dynamical processes involving excited states that are capable of interconverting HNS and its isomeric form HSN is examined.<\/jats:p>","DOI":"10.1063\/1.4932084","type":"journal-article","created":{"date-parts":[[2015,10,1]],"date-time":"2015-10-01T17:00:27Z","timestamp":1443718827000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":9,"title":["On the role of HNS and HSN as light-sensitive NO-donors for delivery in biological media"],"prefix":"10.1063","volume":"143","author":[{"given":"Tarek","family":"Trabelsi","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Tunis El Manar 1 Laboratoire de Spectroscopie Atomique, Mol\u00e9culaire et Applications\u2013LSAMA, , Tunis, Tunisia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roberto","family":"Linguerri","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Paris-Est 2 Laboratoire Mod\u00e9lisation et Simulation Multi Echelle, MSME UMR 8208 CNRS, , 5 bd Descartes, 77454 Marne-la-Vall\u00e9e, France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Saida","family":"Ben Yaghlane","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Tunis El Manar 1 Laboratoire de Spectroscopie Atomique, Mol\u00e9culaire et Applications\u2013LSAMA, , Tunis, Tunisia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nejm-Eddine","family":"Jaidane","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Tunis El Manar 1 Laboratoire de Spectroscopie Atomique, Mol\u00e9culaire et Applications\u2013LSAMA, , Tunis, Tunisia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Muneerah","family":"Mogren Al-Mogren","sequence":"additional","affiliation":[{"name":"King Saud University 3 Chemistry Department, Faculty of Science, , P.O. 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