{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T13:32:04Z","timestamp":1789997524491,"version":"4.0.1"},"reference-count":112,"publisher":"AIP Publishing","issue":"17","funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE 1265737"],"award-info":[{"award-number":["CHE 1265737"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-1564663"],"award-info":[{"award-number":["CHE-1564663"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2016,11,7]]},"abstract":"<jats:p>In situ AC nanocalorimetry was used to characterize vapor-deposited glasses of six mono- and di-alcohol molecules. Benzyl alcohol glasses with high kinetic stability and decreased heat capacity were prepared. When annealed above the glass transition temperature Tg, transformation of these glasses into the supercooled liquid took 103.4 times longer than the supercooled liquid relaxation time (\u03c4\u03b1). This kinetic stability is similar to other highly stable organic glasses prepared by vapor deposition and is the first clear demonstration of an alcohol forming a stable glass. Vapor deposited glasses of five other alcohols exhibited moderate or low kinetic stability with isothermal transformation times ranging from 100.7 to 102 \u03c4\u03b1. This wide range of kinetic stabilities is useful for investigating the factors that control stable glass formation. Using our current results and literature data, we compare the kinetic stability of vapor deposited glasses prepared from 14 molecules and find a correlation with the value of \u03c4\u03b1 at 1.25 Tg. We also observe that some vapor-deposited glasses exhibit decreased heat capacity without increased kinetic stability.<\/jats:p>","DOI":"10.1063\/1.4966582","type":"journal-article","created":{"date-parts":[[2016,11,7]],"date-time":"2016-11-07T18:00:16Z","timestamp":1478541616000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":51,"title":["Vapor-deposited alcohol glasses reveal a wide range of kinetic stability"],"prefix":"10.1063","volume":"145","author":[{"given":"M.","family":"Tylinski","sequence":"first","affiliation":[{"name":"University of Wisconsin\u2013Madison 1 Department of Chemistry, , Madison, Wisconsin 53706, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Y. Z.","family":"Chua","sequence":"additional","affiliation":[{"name":"University of Rostock 2 Institute of Physics, , Albert-Einstein-Str. 23-24, 18051 Rostock, Germany and Competence Centre CALOR, Faculty of Interdisciplinary Research, , Albert-Einstein-Str. 25, 18051 Rostock, Germany"},{"name":"University of Rostock 2 Institute of Physics, , Albert-Einstein-Str. 23-24, 18051 Rostock, Germany and Competence Centre CALOR, Faculty of Interdisciplinary Research, , Albert-Einstein-Str. 25, 18051 Rostock, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. S.","family":"Beasley","sequence":"additional","affiliation":[{"name":"University of Wisconsin\u2013Madison 1 Department of Chemistry, , Madison, Wisconsin 53706, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6736-5491","authenticated-orcid":false,"given":"C.","family":"Schick","sequence":"additional","affiliation":[{"name":"University of Rostock 2 Institute of Physics, , Albert-Einstein-Str. 23-24, 18051 Rostock, Germany and Competence Centre CALOR, Faculty of Interdisciplinary Research, , Albert-Einstein-Str. 25, 18051 Rostock, Germany"},{"name":"University of Rostock 2 Institute of Physics, , Albert-Einstein-Str. 23-24, 18051 Rostock, Germany and Competence Centre CALOR, Faculty of Interdisciplinary Research, , Albert-Einstein-Str. 25, 18051 Rostock, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4715-8473","authenticated-orcid":false,"given":"M. D.","family":"Ediger","sequence":"additional","affiliation":[{"name":"University of Wisconsin\u2013Madison 1 Department of Chemistry, , Madison, Wisconsin 53706, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2016,11,7]]},"reference":[{"key":"2023062600372386200_c1","doi-asserted-by":"publisher","first-page":"353","DOI":"10.1126\/science.1135795","article-title":"Organic glasses with exceptional thermodynamic and kinetic stability","volume":"315","year":"2007","journal-title":"Science"},{"key":"2023062600372386200_c2","doi-asserted-by":"publisher","first-page":"51","DOI":"10.1016\/j.tca.2009.05.016","article-title":"Glass transition in vapor deposited thin films of toluene","volume":"492","year":"2009","journal-title":"Thermochim. Acta"},{"key":"2023062600372386200_c3","doi-asserted-by":"publisher","first-page":"14327","DOI":"10.1021\/jp203612s","article-title":"Character of devitrification, viewed from enthalpic paths, of the vapor-deposited ethylbenzene glasses","volume":"115","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c4","doi-asserted-by":"publisher","first-page":"094502","DOI":"10.1063\/1.4893716","article-title":"Enthalpy and high temperature relaxation kinetics of stable vapor-deposited glasses of toluene","volume":"141","year":"2014","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c5","doi-asserted-by":"publisher","first-page":"3639","DOI":"10.1021\/acs.jpclett.5b01611","article-title":"Probing toluene and ethylbenzene stable glass formation using inert gas permeation","volume":"6","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"key":"2023062600372386200_c6","doi-asserted-by":"publisher","first-page":"084511","DOI":"10.1063\/1.4929511","article-title":"Kinetic stability and heat capacity of vapor-deposited glasses of o-terphenyl","volume":"143","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c7","doi-asserted-by":"publisher","first-page":"045901","DOI":"10.1103\/PhysRevLett.113.045901","article-title":"Role of fragility in the formation of highly stable organic glasses","volume":"113","year":"2014","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c8","doi-asserted-by":"publisher","first-page":"154502","DOI":"10.1063\/1.4758807","article-title":"Vapor-deposited \u03b1,\u03b1,\u03b2-tris-naphthylbenzene glasses with low heat capacity and high kinetic stability","volume":"137","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c9","doi-asserted-by":"publisher","first-page":"054506","DOI":"10.1063\/1.4906806","article-title":"How much time is needed to form a kinetically stable glass? AC calorimetric study of vapor-deposited glasses of ethylcyclohexane","volume":"142","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c10","doi-asserted-by":"publisher","first-page":"4934","DOI":"10.1021\/jp7113384","article-title":"Hiking down the energy landscape: Progress toward the Kauzmann temperature via vapor deposition","volume":"112","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c11","doi-asserted-by":"publisher","first-page":"13303","DOI":"10.1021\/jp404944s","article-title":"Surface self-diffusion of organic glasses","volume":"117","year":"2013","journal-title":"J. Phys. Chem. A"},{"key":"2023062600372386200_c12","doi-asserted-by":"publisher","first-page":"109","DOI":"10.1016\/j.cplett.2008.05.050","article-title":"Anomalously high-density glass of ethylbenzene prepared by vapor deposition at temperatures close to the glass-transition temperature","volume":"459","year":"2008","journal-title":"Chem. Phys. Lett."},{"key":"2023062600372386200_c13","doi-asserted-by":"publisher","first-page":"10311","DOI":"10.1021\/jp404256r","article-title":"Molar volumes of ethylcyclohexane and butyronitrile glasses resulting from vapor deposition: Dependence on deposition temperature and comparison to alkylbenzenes","volume":"117","year":"2013","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c14","doi-asserted-by":"publisher","first-page":"084506","DOI":"10.1063\/1.4928521","article-title":"The effect of chemical structure on the stability of physical vapor deposited glasses of 1,3,5-triarylbenzene","volume":"143","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c15","doi-asserted-by":"publisher","first-page":"4227","DOI":"10.1073\/pnas.1421042112","article-title":"Tunable molecular orientation and elevated thermal stability of vapor-deposited organic semiconductors","volume":"112","year":"2015","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023062600372386200_c16","doi-asserted-by":"publisher","first-page":"014702","DOI":"10.1063\/1.3442416","article-title":"Observation of low heat capacities for vapor-deposited glasses of indomethacin as determined by AC nanocalorimetry","volume":"133","year":"2010","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c17","doi-asserted-by":"publisher","first-page":"1240","DOI":"10.1246\/bcsj.82.1240","article-title":"Behavior of glass and supercooled liquid alkylbenzenes vapor-deposited on cold substrates: Toward the understanding of the curious light scattering observed in some supercooled liquid states","volume":"82","year":"2009","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"2023062600372386200_c18","doi-asserted-by":"publisher","first-page":"62","DOI":"10.1016\/j.cplett.2010.09.010","article-title":"Generality of forming stable organic glasses by vapor deposition","volume":"499","year":"2010","journal-title":"Chem. Phys. Lett."},{"key":"2023062600372386200_c19","doi-asserted-by":"publisher","first-page":"2683","DOI":"10.1021\/jz201174m","article-title":"Highly stable vapor-deposited glasses of four tris-naphthylbenzene isomers","volume":"2","year":"2011","journal-title":"J. Phys. Chem. Lett."},{"key":"2023062600372386200_c20","doi-asserted-by":"publisher","first-page":"12724","DOI":"10.1021\/jp400960g","article-title":"Highly stable glasses of cis-decalin and cis\/trans-decalin mixtures","volume":"117","year":"2013","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c21","doi-asserted-by":"publisher","first-page":"256","DOI":"10.1016\/j.jnoncrysol.2014.07.031","article-title":"Highly stable glasses of celecoxib: Influence on thermo-kinetic properties, microstructure and response towards crystal growth","volume":"407","year":"2014","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c22","doi-asserted-by":"publisher","first-page":"4076","DOI":"10.1021\/jp5109174","article-title":"Devitrification properties of vapor-deposited ethylcyclohexane glasses and interpretation of the molecular mechanism for formation of vapor-deposited glasses","volume":"119","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c23","doi-asserted-by":"publisher","first-page":"244503","DOI":"10.1063\/1.4954665","article-title":"Glass transition and stable glass formation of tetrachloromethane","volume":"144","year":"2016","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c24","doi-asserted-by":"publisher","first-page":"244502","DOI":"10.1063\/1.3511721","article-title":"Macroscopic facilitation of glassy relaxation kinetics: Ultrastable glass films with frontlike thermal response","volume":"133","year":"2010","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c25","doi-asserted-by":"publisher","first-page":"194903","DOI":"10.1063\/1.3586805","article-title":"A molecular view of vapor deposited glasses","volume":"134","year":"2011","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c26","doi-asserted-by":"publisher","first-page":"275702","DOI":"10.1103\/PhysRevLett.107.275702","article-title":"Preparation and relaxation of very stable glassy states of a simulated liquid","volume":"107","year":"2011","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c27","doi-asserted-by":"publisher","first-page":"224503","DOI":"10.1063\/1.4903200","article-title":"Equilibrium ultrastable glasses produced by random pinning","volume":"141","year":"2014","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c28","doi-asserted-by":"publisher","first-page":"5898","DOI":"10.1039\/C6SM00810K","article-title":"Inherent structure energy is a good indicator of molecular mobility in glasses","volume":"12","year":"2016","journal-title":"Soft Matter"},{"key":"2023062600372386200_c29","doi-asserted-by":"publisher","first-page":"144505","DOI":"10.1063\/1.4823769","article-title":"Model vapor-deposited glasses: Growth front and composition effects","volume":"139","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c30","doi-asserted-by":"publisher","first-page":"5904","DOI":"10.1002\/adma.201302700","article-title":"Ultrastable metallic glass","volume":"25","year":"2013","journal-title":"Adv. Mater."},{"key":"2023062600372386200_c31","doi-asserted-by":"publisher","first-page":"1233","DOI":"10.1038\/ncomms2228","article-title":"Supercooled liquids with enhanced orientational order","volume":"3","year":"2012","journal-title":"Nat. Commun."},{"key":"2023062600372386200_c32","doi-asserted-by":"publisher","first-page":"244504","DOI":"10.1063\/1.4937795","article-title":"Dielectric and specific heat relaxations in vapor deposited glycerol","volume":"143","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c33","doi-asserted-by":"publisher","first-page":"244506","DOI":"10.1063\/1.4771964","article-title":"Glass transition in ultrathin films of amorphous solid water","volume":"137","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c34","doi-asserted-by":"publisher","first-page":"024501","DOI":"10.1063\/1.4773354","article-title":"In situ investigation of vapor-deposited glasses of toluene and ethylbenzene via alternating current chip-nanocalorimetry","volume":"138","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c35","doi-asserted-by":"publisher","first-page":"15415","DOI":"10.1021\/jp405005n","article-title":"High-throughput ellipsometric characterization of vapor-deposited indomethacin glasses","volume":"117","year":"2013","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c36","doi-asserted-by":"publisher","first-page":"244509","DOI":"10.1063\/1.4938420","article-title":"Vapor-deposited glasses of methyl-m-toluate: How uniform is stable glass transformation?","volume":"143","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c37","doi-asserted-by":"publisher","first-page":"124515","DOI":"10.1063\/1.3643332","article-title":"Dynamics of glass-forming liquids. XV. Dynamical features of molecular liquids that form ultra-stable glasses by vapor deposition","volume":"135","year":"2011","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c38","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1016\/j.jnoncrysol.2014.08.044","article-title":"On the uncertain distinction between fast landscape exploration and second amorphous phase (ideal glass) interpretations of the ultrastable glass phenomenon","volume":"407","year":"2014","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c39","doi-asserted-by":"publisher","first-page":"11127","DOI":"10.1021\/jp104523h","article-title":"Structural relaxation of vapor-deposited water, methanol, ethanol, and 1-propanol films studied using low-energy ion scattering","volume":"114","year":"2010","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c40","doi-asserted-by":"publisher","first-page":"8007","DOI":"10.1021\/acs.jpcb.6b05658","article-title":"Hydrogen bonding slows down surface diffusion of molecular glasses","volume":"120","year":"2016","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c41","doi-asserted-by":"publisher","first-page":"204508","DOI":"10.1063\/1.4768168","article-title":"Stable glasses of indomethacin and \u03b1,\u03b1,\u03b2-tris-naphthylbenzene transform into ordinary supercooled liquids","volume":"137","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c42","doi-asserted-by":"publisher","first-page":"134504","DOI":"10.1063\/1.4916649","article-title":"Thermal stability of vapor-deposited stable glasses of an organic semiconductor","volume":"142","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c43","doi-asserted-by":"publisher","first-page":"104503","DOI":"10.1063\/1.2539105","article-title":"Comparing calorimetric and dielectric polarization modes in viscous 2-ethyl-1-hexanol","volume":"126","year":"2007","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c44","doi-asserted-by":"publisher","first-page":"8878","DOI":"10.1103\/PhysRevB.62.8878","article-title":"Excess wing in the dielectric loss of glass-forming ethanol: A relaxation process","volume":"62","year":"2000","journal-title":"Phys. Rev. B"},{"key":"2023062600372386200_c45","doi-asserted-by":"publisher","first-page":"1086","DOI":"10.1063\/1.474456","article-title":"Dynamics of glass-forming liquids. III. Comparing the dielectric \u03b1- and \u03b2-relaxation of 1-propanol and o-terphenyl","volume":"107","year":"1997","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c46","doi-asserted-by":"publisher","first-page":"11585","DOI":"10.1063\/1.478006","article-title":"Relationship between the primary and secondary dielectric relaxation processes in propylene glycol and its oligomers","volume":"110","year":"1999","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c47","doi-asserted-by":"publisher","first-page":"2338","DOI":"10.1103\/PhysRevLett.82.2338","article-title":"Molecular dynamics in confining space: From the single molecule to the liquid state","volume":"82","year":"1999","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c48","doi-asserted-by":"publisher","first-page":"221","DOI":"10.1016\/0022-3093(91)90305-P","article-title":"The glass transition of organic liquids confined to small pores","volume":"131-133","year":"1991","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c49","doi-asserted-by":"publisher","first-page":"2128","DOI":"10.1021\/cm9601188","article-title":"Vitrification and crystallization of organic liquids confined to nanoscale pores","volume":"8","year":"1996","journal-title":"Chem. Mater."},{"key":"2023062600372386200_c50","doi-asserted-by":"publisher","first-page":"033902","DOI":"10.1063\/1.3692742","article-title":"Differential alternating current chip calorimeter for in situ investigation of vapor-deposited thin films","volume":"83","year":"2012","journal-title":"Rev. Sci. Instrum."},{"key":"2023062600372386200_c51","doi-asserted-by":"publisher","first-page":"12A517","DOI":"10.1063\/1.4772594","article-title":"Manipulating the properties of stable organic glasses using kinetic facilitation","volume":"138","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c52","doi-asserted-by":"publisher","first-page":"065503","DOI":"10.1103\/PhysRevLett.102.065503","article-title":"Stable glass transformation to supercooled liquid via surface-initiated growth front","volume":"102","year":"2009","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c53","doi-asserted-by":"publisher","first-page":"1353","DOI":"10.1073\/pnas.0909421106","article-title":"Spatiotemporal structures in aging and rejuvenating glasses","volume":"106","year":"2009","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023062600372386200_c54","doi-asserted-by":"publisher","first-page":"10795","DOI":"10.1021\/jp506782d","article-title":"Evaluation of growth front velocity in ultrastable glasses of indomethacin over a wide temperature interval","volume":"118","year":"2014","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c55","doi-asserted-by":"publisher","first-page":"3875","DOI":"10.1021\/jp512905a","article-title":"Influence of substrate temperature on the transformation front velocities that determine thermal stability of vapor-deposited glasses","volume":"119","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c56","doi-asserted-by":"publisher","first-page":"124505","DOI":"10.1063\/1.2844797","article-title":"Dynamics of glass-forming liquids. XII. Dielectric study of primary and secondary relaxations in ethylcyclohexane","volume":"128","year":"2008","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c57","doi-asserted-by":"publisher","first-page":"532","DOI":"10.1515\/zna-1953-0903","article-title":"Molekulare theorie der Mikroreibung","volume":"8","year":"1953","journal-title":"Z. Naturforsch., A"},{"key":"2023062600372386200_c58","first-page":"1","article-title":"Theoretical treatment of permitivity and loss","volume-title":"Dielectric Property Molecular Behavior","year":"1969"},{"key":"2023062600372386200_c59","doi-asserted-by":"publisher","first-page":"6251","DOI":"10.1063\/1.469071","article-title":"Dynamics of glass-forming liquids. I. Temperature-derivative analysis of dielectric relaxation data","volume":"102","year":"1995","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c60","doi-asserted-by":"publisher","first-page":"2043","DOI":"10.1063\/1.470961","article-title":"Dynamics of glass-forming liquids. II. Detailed comparison of dielectric relaxation, dc-conductivity, and viscosity data","volume":"104","year":"1996","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c61","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1111\/j.1151-2916.1925.tb16731.x","article-title":"Analysis of recent measurements of the viscosity of glasses","volume":"8","year":"1925","journal-title":"J. Am. Ceram. Soc."},{"key":"2023062600372386200_c62","doi-asserted-by":"publisher","first-page":"5176","DOI":"10.1021\/ja0291437","article-title":"Nanometer-resolved interfacial fluidity","volume":"125","year":"2003","journal-title":"J. Am. Ceram. Soc."},{"key":"2023062600372386200_c63","doi-asserted-by":"publisher","first-page":"256103","DOI":"10.1103\/PhysRevLett.106.256103","article-title":"Surface self-diffusion of an organic glass","volume":"106","year":"2011","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c64","doi-asserted-by":"publisher","first-page":"5071","DOI":"10.1021\/jp5127464","article-title":"Fast surface diffusion of amorphous o-terphenyl and its competition with viscous flow in surface evolution","volume":"119","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c65","doi-asserted-by":"publisher","first-page":"4466","DOI":"10.1063\/1.461769","article-title":"Glassy relaxation at surfaces: The correlation length of cooperative motion in the facilitated kinetic Ising model","volume":"95","year":"1991","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c66","doi-asserted-by":"publisher","first-page":"194704","DOI":"10.1063\/1.3573903","article-title":"Evolution of glassy gratings with variable aspect ratios under surface diffusion","volume":"134","year":"2011","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c67","doi-asserted-by":"publisher","first-page":"114524","DOI":"10.1063\/1.3565480","article-title":"Properties of model atomic free-standing thin films","volume":"134","year":"2011","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c68","doi-asserted-by":"publisher","first-page":"174204","DOI":"10.1103\/PhysRevB.84.174204","article-title":"Free surface effects on thermodynamics and glass formation in simple monatomic supercooled liquids","volume":"84","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023062600372386200_c69","doi-asserted-by":"publisher","first-page":"234514","DOI":"10.1063\/1.3041651","article-title":"On the surface of glasses","volume":"129","year":"2008","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c70","doi-asserted-by":"publisher","first-page":"244705","DOI":"10.1063\/1.4937953","article-title":"Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films","volume":"143","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c71","doi-asserted-by":"publisher","first-page":"154702","DOI":"10.1063\/1.2789438","article-title":"Influence of substrate temperature on the stability of glasses prepared by vapor deposition","volume":"127","year":"2007","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c72","doi-asserted-by":"publisher","first-page":"064503","DOI":"10.1063\/1.4960301","article-title":"Surface diffusion and surface crystal growth of tris-napthyl benzene glasses","volume":"145","year":"2016","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c73","doi-asserted-by":"publisher","first-page":"094514","DOI":"10.1063\/1.3690137","article-title":"A statistical model of hydrogen bond networks in liquid alcohols","volume":"136","year":"2012","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c74","doi-asserted-by":"publisher","first-page":"5073","DOI":"10.1063\/1.1453400","article-title":"Dynamics of propylene glycol and its 7-mer by neutron scattering","volume":"116","year":"2002","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c75","doi-asserted-by":"publisher","first-page":"225","DOI":"10.1016\/S0022-3093(98)00638-3","article-title":"Relaxational and vibrational dynamics of poly(propylene glycol)","volume":"235","year":"1998","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c76","doi-asserted-by":"publisher","first-page":"3187","DOI":"10.1063\/1.1340605","article-title":"Structure of liquid ethylene glycol: A molecular dynamics simulation study with different force fields","volume":"114","year":"2001","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c77","doi-asserted-by":"publisher","first-page":"20","DOI":"10.1016\/j.molliq.2013.05.033","article-title":"Ethylene glycol revisited: Molecular dynamics simulations and visualization of the liquid and its hydrogen-bond network","volume":"189","year":"2014","journal-title":"J. Mol. Liq."},{"key":"2023062600372386200_c78","doi-asserted-by":"publisher","first-page":"94","DOI":"10.1134\/S0036024414010063","article-title":"Investigating hydrogen bonds in liquid ethylene glycol structure by means of molecular dynamics","volume":"88","year":"2014","journal-title":"Russ. J. Phys. Chem. A"},{"key":"2023062600372386200_c79","doi-asserted-by":"publisher","first-page":"125","DOI":"10.1016\/j.physrep.2014.07.005","article-title":"Structure and dynamics of monohydroxy alcohols\u2014Milestones towards their microscopic understanding, 100 years after Debye","volume":"545","year":"2014","journal-title":"Phys. Rep."},{"key":"2023062600372386200_c80","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1107\/S0021889894010149","article-title":"Determination of liquid structures of the primary alcohols methanol, ethanol, 1-propanol, 1-butanol and 1-octanol by X-ray scattering","volume":"28","year":"1995","journal-title":"J. Appl. Crystallogr."},{"key":"2023062600372386200_c81","doi-asserted-by":"publisher","first-page":"144505","DOI":"10.1063\/1.3374820","article-title":"Insights on the origin of the Debye process in monoalcohols from dielectric spectroscopy under extreme pressure conditions","volume":"132","year":"2010","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c82","doi-asserted-by":"publisher","first-page":"014501","DOI":"10.1063\/1.4904908","article-title":"Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study","volume":"142","year":"2015","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c83","doi-asserted-by":"publisher","first-page":"13473","DOI":"10.1021\/jp206665w","article-title":"Hydrogen bonding and molecular aggregates in liquid methanol, ethanol, and 1-propanol","volume":"115","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c84","doi-asserted-by":"publisher","first-page":"154302","DOI":"10.1063\/1.4945809","article-title":"Revisiting the formation of cyclic clusters in liquid ethanol","volume":"144","year":"2016","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c85","doi-asserted-by":"publisher","first-page":"363","DOI":"10.1016\/0301-0104(78)85129-5","article-title":"Light scattering evidence for fast relaxation of hydrogen-bonded structures in liquid benzyl alcohol","volume":"31","year":"1978","journal-title":"Chem. Phys."},{"key":"2023062600372386200_c86","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1016\/S0167-7322(99)00168-3","article-title":"Temperature dependence of hydrogen bonding in alcohols","volume":"85","year":"2000","journal-title":"J. Mol. Liq."},{"key":"2023062600372386200_c87","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1107\/S0108768191010972","article-title":"Structure of liquid benzyl alcohol at 293 K","volume":"48","year":"1992","journal-title":"Acta Crystallogr., Sect. B: Struct. Sci."},{"key":"2023062600372386200_c88","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1002\/jrs.1250250206","article-title":"Raman and infrared study of solid benzyl alcohol","volume":"25","year":"1994","journal-title":"J. Raman Spectrosc."},{"key":"2023062600372386200_c89","doi-asserted-by":"publisher","first-page":"470","DOI":"10.1021\/je00042a031","article-title":"Viscosities and activation energies of viscous flow of the ternary mixtures of toluene, chlorobenzene, 1-hexanol, and benzyl alcohol","volume":"30","year":"1985","journal-title":"J. Chem. Eng. Data"},{"key":"2023062600372386200_c90","doi-asserted-by":"publisher","first-page":"1291","DOI":"10.1021\/je030163d","article-title":"Densities and viscosities of binary mixtures of N,N-dimethylformamide with benzyl alcohol and acetophenone at (298.15, 303.15, 308.15, and 313.15) K","volume":"48","year":"2003","journal-title":"J. Chem. Eng. Data"},{"key":"2023062600372386200_c91","doi-asserted-by":"publisher","first-page":"628","DOI":"10.1021\/je0201828","article-title":"Density, viscosity, refractive index, and speed of sound in the binary mixtures of ethyl chloroacetate + cyclohexanone, + chlorobenzene, + bromobenzene, or + benzyl alcohol at (298.15, 303.15, and 308.15) K","volume":"48","year":"2003","journal-title":"J. Chem. Eng. Data"},{"key":"2023062600372386200_c92","doi-asserted-by":"publisher","first-page":"204515","DOI":"10.1063\/1.3142142","article-title":"Enthalpy and dielectric relaxations in supercooled methyl m-toluate","volume":"130","year":"2009","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c93","doi-asserted-by":"publisher","first-page":"3961","DOI":"10.1080\/14786430802537753","article-title":"On the features of the dielectric response of supercooled ethylcyclohexane","volume":"88","year":"2008","journal-title":"Philos. Mag."},{"key":"2023062600372386200_c94","doi-asserted-by":"publisher","first-page":"2451","DOI":"10.1063\/1.1841068","article-title":"Measurement of the glass-transition temperature of simple liquids","volume":"46","year":"1967","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c95","doi-asserted-by":"publisher","first-page":"154502","DOI":"10.1063\/1.2064667","article-title":"On the dielectric susceptibility spectra of supercooledo-terphenyl","volume":"123","year":"2005","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c96","doi-asserted-by":"publisher","first-page":"9016","DOI":"10.1063\/1.476348","article-title":"Dynamics of glass-forming liquids. V. On the link between molecular dynamics and configurational entropy","volume":"108","year":"1998","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c97","doi-asserted-by":"publisher","first-page":"12536","DOI":"10.1021\/jp905162r","article-title":"Broadband dielectric relaxation study at ambient and elevated pressure of molecular dynamics of pharmaceutical: Indomethacin","volume":"113","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c98","doi-asserted-by":"publisher","first-page":"271","DOI":"10.1007\/s11095-011-0540-4","article-title":"Role of viscosity in influencing the glass-forming ability of organic molecules from the undercooled melt state","volume":"29","year":"2012","journal-title":"Pharm. Res."},{"key":"2023062600372386200_c99","doi-asserted-by":"publisher","first-page":"1828","DOI":"10.1063\/1.1531587","article-title":"Dynamics of glass-forming liquids. VII. Dielectric relaxation of supercooled tris-naphthylbenzene, squalane, and decahydroisoquinoline","volume":"118","year":"2003","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c100","doi-asserted-by":"publisher","first-page":"3038","DOI":"10.1063\/1.1728059","article-title":"Physical properties of aromatic hydrocarbons. I. Viscous and viscoelastic behavior of 1:3:5-tri-\u03b1-naphthyl benzene","volume":"45","year":"1966","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c101","doi-asserted-by":"publisher","first-page":"322","DOI":"10.1098\/rspa.1966.0138","article-title":"Viscous behaviour of supercooled liquids","volume":"292","year":"1966","journal-title":"Proc. R. Soc. A"},{"key":"2023062600372386200_c102","doi-asserted-by":"publisher","first-page":"406","DOI":"10.1016\/S0022-3093(98)00510-9","article-title":"Slow secondary relaxation in simple glass formers","volume":"235-237","year":"1998","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c103","doi-asserted-by":"publisher","first-page":"94","DOI":"10.1016\/0009-2614(84)87048-7","article-title":"2H NMR Study of supercooled toluene","volume":"112","year":"1984","journal-title":"Chem. Phys. Lett."},{"key":"2023062600372386200_c104","doi-asserted-by":"publisher","first-page":"3991","DOI":"10.1021\/jp983927i","article-title":"Fragility in liquids and polymers: New, simple quantifications and interpretations","volume":"103","year":"1999","journal-title":"J. Phys. Chem. B"},{"key":"2023062600372386200_c105","doi-asserted-by":"publisher","first-page":"235701","DOI":"10.1103\/PhysRevLett.93.235701","article-title":"Origin of the fragile-to-strong crossover in liquid silica as expressed by its potential-energy landscape","volume":"93","year":"2004","journal-title":"Phys. Rev. Lett."},{"key":"2023062600372386200_c106","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1016\/j.jnoncrysol.2014.08.012","article-title":"Accumulating evidence for non-diverging time-scales in glass-forming fluids","volume":"407","year":"2015","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c107","doi-asserted-by":"publisher","first-page":"137101","DOI":"10.1063\/1.4823797","article-title":"Comment on \u2018Temperature divergence of the dynamics of a poly(vinyl acetate) glass: Dielectric vs. mechanical behaviors\u2019 [J. Chem. Phys. 136, 154901 (2012)]","volume":"139","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c108","doi-asserted-by":"publisher","first-page":"255","DOI":"10.1016\/S0032-3861(96)00524-1","article-title":"Dielectric relaxation of the electric field in poly(vinyl acetate): A time domain study in the range 10\u22123\u2013106 s","volume":"38","year":"1997","journal-title":"Polymer"},{"key":"2023062600372386200_c109","doi-asserted-by":"publisher","first-page":"4767","DOI":"10.1063\/1.432063","article-title":"Viscous liquids and the glass transition. V. Sources of the excess specific heat of the liquid","volume":"64","year":"1976","journal-title":"J. Chem. Phys."},{"key":"2023062600372386200_c110","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1016\/0022-3093(88)90373-0","article-title":"Construction of an adiabatic calorimeter for a vapor-deposited sample and thermal characterization of amorphous butyronitrile","volume":"101","year":"1988","journal-title":"J. Non-Cryst. Solids"},{"key":"2023062600372386200_c111","doi-asserted-by":"publisher","first-page":"1602","DOI":"10.1021\/j100005a035","article-title":"Calorimetric study on structural relaxation of 1-pentene in vapor-deposited and liquid-quenched glassy states","volume":"99","year":"1995","journal-title":"J. Phys. Chem."},{"key":"2023062600372386200_c112","doi-asserted-by":"publisher","first-page":"185501","DOI":"10.1103\/physrevlett.115.185501","article-title":"Suppression of \u03b2 relaxation in vapor-deposited ultrastable glasses","volume":"115","year":"2015","journal-title":"Phys. Rev. Lett."}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4966582\/13891637\/174506_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/aip.scitation.org\/doi\/am-pdf\/10.1063\/1.4966582","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4966582\/13891637\/174506_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,6,26]],"date-time":"2023-06-26T00:37:30Z","timestamp":1687739850000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/145\/17\/174506\/195126\/Vapor-deposited-alcohol-glasses-reveal-a-wide"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,11,7]]},"references-count":112,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2016,11,7]]}},"URL":"https:\/\/doi.org\/10.1063\/1.4966582","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2016,11,7]]},"published":{"date-parts":[[2016,11,7]]},"article-number":"174506"}}