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The H2S\u22efMI complexes (where M is the metal atom) are generated through laser vaporisation of a metal rod in the presence of a low concentration of H2S and CF3I in a buffer gas of argon undergoing supersonic expansion. The microwave spectra of six isotopologues of each of H2S\u22efCuI, H2S\u22efAgI and three isotopologues of H2S\u22efAuI have been measured by chirped-pulse Fourier transform microwave spectroscopy. The spectra are interpreted to determine geometries for the complexes and to establish the values of structural parameters. The complexes have Cs symmetry at equilibrium and have a pyramidal configuration about the sulfur atom. The local C2 axis of the hydrogen sulfide molecule intersects the linear axis defined by the three heavy atoms at an angle, \u03d5 = 75.00(47)\u00b0 for M = Cu, \u03d5 = 78.43(76)\u00b0 for M = Ag, and \u03d5 = 71.587(13)\u00b0 for M = Au. The trend in the molecular geometries is consistent with significant relativistic effects in the gold-containing complex. The force constant describing the interaction between the H2S and MI sub-units is determined from the measured centrifugal distortion constant, \u0394J, of each complex. Nuclear quadrupole coupling constants, \u03c7aa(M) and \u03c7aa(I) (where M denotes the metal atom), are determined for H2S\u22efCuI and H2S\u22efAuI for the first time.<\/jats:p>","DOI":"10.1063\/1.4967477","type":"journal-article","created":{"date-parts":[[2016,11,18]],"date-time":"2016-11-18T18:00:21Z","timestamp":1479492021000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":13,"title":["Geometries of H2S\u22efMI (M = Cu, Ag, Au) complexes studied by rotational spectroscopy: The effect of the metal atom"],"prefix":"10.1063","volume":"145","author":[{"given":"Chris","family":"Medcraft","sequence":"first","affiliation":[{"name":"Newcastle University 1 School of Chemistry, , Bedson Building, Newcastle upon Tyne, Tyne and Wear NE1 7RU, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dror M.","family":"Bittner","sequence":"additional","affiliation":[{"name":"Newcastle University 1 School of Chemistry, , Bedson Building, Newcastle upon Tyne, Tyne and Wear NE1 7RU, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3220-4177","authenticated-orcid":false,"given":"David P.","family":"Tew","sequence":"additional","affiliation":[{"name":"University of Bristol 2 School of Chemistry, , Bristol BS8 1TS, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9450-305X","authenticated-orcid":false,"given":"Nicholas R.","family":"Walker","sequence":"additional","affiliation":[{"name":"Newcastle University 1 School of Chemistry, , Bedson Building, Newcastle upon Tyne, Tyne and Wear NE1 7RU, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3468-9865","authenticated-orcid":false,"given":"Anthony C.","family":"Legon","sequence":"additional","affiliation":[{"name":"University of Bristol 2 School of Chemistry, , Bristol BS8 1TS, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2016,11,18]]},"reference":[{"key":"2023080201464448500_c1","doi-asserted-by":"publisher","first-page":"419","DOI":"10.1098\/rspa.1982.0081","volume":"381","year":"1982","journal-title":"Proc. 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