{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T17:12:06Z","timestamp":1784567526208,"version":"3.55.0"},"reference-count":13,"publisher":"AIP Publishing","issue":"5","license":[{"start":{"date-parts":[[2018,5,14]],"date-time":"2018-05-14T00:00:00Z","timestamp":1526256000000},"content-version":"vor","delay-in-days":13,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2018,5,14]],"date-time":"2018-05-14T00:00:00Z","timestamp":1526256000000},"content-version":"tdm","delay-in-days":13,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003056","name":"Ente Cassa di Risparmio di Firenze","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003056","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003407","name":"Ministero dell'Istruzione, dell'Universit\u00e0 e della Ricerca","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003407","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000879","name":"Alfred P. Sloan Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000879","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["670173"],"award-info":[{"award-number":["670173"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2018,5,1]]},"abstract":"<jats:p>An efficient loading technique has been developed for flammable, toxic, or explosive gases which can be condensed at liquid nitrogen temperature and ambient pressure in membrane diamond anvil cells (DACs). This cryogenic technique consists in a deposition of small quantities of the desired gas directly into the sample chamber. The deposition is performed using a capillary that reaches the space between the diamond anvils. The DAC is kept under inert gas overpressure during the whole process, in order to avoid contamination from atmospheric O2, CO2, and H2O. This technique provides significant advantages over standard cryo-loading and gas-loading when the condensation of dangerous samples at liquid nitrogen temperature raises safety concerns because it allows dealing with minimum quantities of condensed gases. The whole procedure is particularly fast and efficient. The \u201cspray-loading\u201d has been successfully used in our laboratory to load several samples including acetylene, ammonia, ethylene, and carbon dioxide\/water or red phosphorus\/NH3 mixtures.<\/jats:p>","DOI":"10.1063\/1.5011286","type":"journal-article","created":{"date-parts":[[2018,5,14]],"date-time":"2018-05-14T18:09:05Z","timestamp":1526321345000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":18,"title":["Spray-loading: A cryogenic deposition method for diamond anvil cell"],"prefix":"10.1063","volume":"89","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4856-0125","authenticated-orcid":false,"given":"Demetrio","family":"Scelta","sequence":"first","affiliation":[{"name":"LENS, European Laboratory for Non-Linear Spectroscopy 1 , Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy"},{"name":"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy 2 , Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0688-5167","authenticated-orcid":false,"given":"Matteo","family":"Ceppatelli","sequence":"additional","affiliation":[{"name":"LENS, European Laboratory for Non-Linear Spectroscopy 1 , Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy"},{"name":"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy 2 , Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Riccardo","family":"Ballerini","sequence":"additional","affiliation":[{"name":"LENS, European Laboratory for Non-Linear Spectroscopy 1 , Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ahmed","family":"Hajeb","sequence":"additional","affiliation":[{"name":"LENS, European Laboratory for Non-Linear Spectroscopy 1 , Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2708-3964","authenticated-orcid":false,"given":"Maurizio","family":"Peruzzini","sequence":"additional","affiliation":[{"name":"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy 2 , Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6746-696X","authenticated-orcid":false,"given":"Roberto","family":"Bini","sequence":"additional","affiliation":[{"name":"LENS, European Laboratory for Non-Linear Spectroscopy 1 , Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy"},{"name":"ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy 2 , Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Firenze, Italy"},{"name":"Dipartimento di Chimica \u201cUgo Schiff\u201d dell\u2019Universit\u00e0 degli Studi di Firenze 3 , Via della Lastruccia 3, I-50019 Sesto Fiorentino, Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2018,5,14]]},"reference":[{"key":"2023080502421835600_c1","doi-asserted-by":"publisher","first-page":"2592","DOI":"10.1063\/1.1139903","volume":"59","year":"1988","journal-title":"Rev. Sci. Instrum."},{"key":"2023080502421835600_c2","doi-asserted-by":"publisher","first-page":"1073","DOI":"10.1126\/science.206.4422.1073","volume":"206","year":"1979","journal-title":"Science"},{"key":"2023080502421835600_c3","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1080\/08957958808202482","volume":"1","year":"1988","journal-title":"High Pressure Res."},{"key":"2023080502421835600_c4","doi-asserted-by":"publisher","first-page":"871","DOI":"10.1080\/08957959008246284","volume":"5","year":"1990","journal-title":"High Pressure Res."},{"key":"2023080502421835600_c5","doi-asserted-by":"publisher","first-page":"75","DOI":"10.1080\/08957950802235640","volume":"28","year":"2008","journal-title":"High Pressure Res."},{"key":"2023080502421835600_c6","doi-asserted-by":"publisher","first-page":"5991","DOI":"10.1063\/1.1288800","volume":"113","year":"2000","journal-title":"J. Chem. Phys."},{"key":"2023080502421835600_c7","doi-asserted-by":"publisher","first-page":"11454","DOI":"10.1073\/pnas.0901836106","volume":"106","year":"2009","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023080502421835600_c8","doi-asserted-by":"publisher","first-page":"2249","DOI":"10.1021\/cm500061f","volume":"26","year":"2014","journal-title":"Chem. Mater."},{"key":"2023080502421835600_c9","doi-asserted-by":"publisher","first-page":"4065","DOI":"10.1021\/acs.chemmater.6b01639","volume":"28","year":"2016","journal-title":"Chem. Mater."},{"key":"2023080502421835600_c10","doi-asserted-by":"publisher","first-page":"5174","DOI":"10.1021\/acs.jpcc.5b12274","volume":"120","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"2023080502421835600_c11","doi-asserted-by":"publisher","first-page":"484","DOI":"10.1016\/j.carbon.2015.05.066","volume":"93","year":"2015","journal-title":"Carbon"},{"key":"2023080502421835600_c12","doi-asserted-by":"publisher","first-page":"5009","DOI":"10.1063\/1.1679088","volume":"58","year":"1973","journal-title":"J. Chem. Phys."},{"key":"2023080502421835600_c13","doi-asserted-by":"publisher","first-page":"1067","DOI":"10.1063\/1.2389013","volume":"32","year":"2006","journal-title":"Low Temp. Phys."}],"container-title":["Review of Scientific Instruments"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/rsi\/article-pdf\/doi\/10.1063\/1.5011286\/15631503\/053903_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/pubs.aip.org\/aip\/rsi\/article-pdf\/doi\/10.1063\/1.5011286\/15631503\/053903_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/rsi\/article-pdf\/doi\/10.1063\/1.5011286\/15631503\/053903_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T13:09:35Z","timestamp":1748005775000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/rsi\/article\/89\/5\/053903\/992262\/Spray-loading-A-cryogenic-deposition-method-for"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,5,1]]},"references-count":13,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2018,5,1]]}},"URL":"https:\/\/doi.org\/10.1063\/1.5011286","relation":{},"ISSN":["0034-6748","1089-7623"],"issn-type":[{"value":"0034-6748","type":"print"},{"value":"1089-7623","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2018,5]]},"published":{"date-parts":[[2018,5,1]]},"article-number":"053903"}}