{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T04:39:14Z","timestamp":1770352754944,"version":"3.49.0"},"reference-count":33,"publisher":"AIP Publishing","issue":"8","funder":[{"name":"Spanish Ministrerio de Industria Economia y Competitivided","award":["FIS 2016-80440"],"award-info":[{"award-number":["FIS 2016-80440"]}]},{"DOI":"10.13039\/501100001700","name":"Ministry of Education, Culture, Sports, Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001700","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2018,2,28]]},"abstract":"<jats:p>As a sequel paper to our study of the elastic scattering for electron collisions with phosphorus trifluoride, PF3 molecules, we report absolute inelastic differential and integral cross sections (DCS and ICS) of vibrational excitations for the compound fundamental vibrational modes v13 (v1 + v3), v24 (v2 + v4), and their sum in the impact energy range of 2.0\u201310 eV and over a scattering angle range of 20\u00b0\u2013130\u00b0. The measured angular distributions of scattered electron intensities for the present inelastic scattering are normalized to the elastic peak intensity corresponding to the DCSs of He. These vibrational excitation measurements demonstrate the presence of resonances around 2 eV and also around 6\u201310 eV. In addition, a generalized oscillator strength analysis is applied to derive oscillator strength f0-values and (unscaled Born) ICSs from the corresponding DCSs measured for the low-lying optically allowed 8a1\u22121 \u2192 7e (\u03c3*) excitation band, which is assigned as the Jahn-Teller splitting and 8a1\u22121 \u2192 4s Rydberg transition at impact energies of 100, 200, and 300 eV, over a scattering angle range of 1.0\u00b0\u201315\u00b0. The f0-values obtained in the present study are compared with the results of previous photoabsorption and pseudo-optical measurements. The unscaled Born ICSs are compared with the binary-encounter f-scaled Born ICSs estimated over a wide impact energy region from the excitation thresholds.<\/jats:p>","DOI":"10.1063\/1.5012844","type":"journal-article","created":{"date-parts":[[2018,2,28]],"date-time":"2018-02-28T15:06:46Z","timestamp":1519830406000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":4,"title":["Absolute cross section measurements for the scattering of low- and intermediate-energy electrons from PF3. II. Inelastic scattering of vibrational and electronic excitations"],"prefix":"10.1063","volume":"148","author":[{"given":"N.","family":"Hishiyama","sequence":"first","affiliation":[{"name":"Department of Physics, Sophia University 1 , Chiyoda-ku, Tokyo 102-8554, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8874-8790","authenticated-orcid":false,"given":"M.","family":"Hoshino","sequence":"additional","affiliation":[{"name":"Department of Physics, Sophia University 1 , Chiyoda-ku, Tokyo 102-8554, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4332-434X","authenticated-orcid":false,"given":"F.","family":"Blanco","sequence":"additional","affiliation":[{"name":"Departamento de Fisica, Atomica, Molecular y Nuclear, Facultad de Ciencias Fisicas, Universidad Complutense de Madrid 2 , E-28040 Madrid, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G.","family":"Garc\u00eda","sequence":"additional","affiliation":[{"name":"Instituto de Fisica Fundamental, Consejo Superior de Investigaciones Cient\u00edficas 3 , 28006 Madrid, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"H.","family":"Tanaka","sequence":"additional","affiliation":[{"name":"Department of Physics, Sophia University 1 , Chiyoda-ku, Tokyo 102-8554, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2018,2,28]]},"reference":[{"key":"2023062520160200300_c1","doi-asserted-by":"publisher","first-page":"224308","DOI":"10.1063\/1.5009482","volume":"147","year":"2017","journal-title":"J. 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