{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T17:41:08Z","timestamp":1792518068631,"version":"4.5.0"},"reference-count":53,"publisher":"AIP Publishing","issue":"19","funder":[{"name":"NSF EXCEDE","award":["TG-MCA08X040"],"award-info":[{"award-number":["TG-MCA08X040"]}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-1531590"],"award-info":[{"award-number":["CHE-1531590"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000774","name":"Defense Threat Reduction Agency","doi-asserted-by":"publisher","award":["HDTRA1-12-1-0023"],"award-info":[{"award-number":["HDTRA1-12-1-0023"]}],"id":[{"id":"10.13039\/100000774","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006231","name":"Brookhaven National Laboratory","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006231","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006754","name":"Army Research Laboratory","doi-asserted-by":"publisher","award":["W911NF-16-2-0022"],"award-info":[{"award-number":["W911NF-16-2-0022"]}],"id":[{"id":"10.13039\/100006754","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2018,5,21]]},"abstract":"<jats:p>Tin sulfides, SnxSy, are an important class of materials that are actively investigated as novel photovoltaic and water splitting materials. A first-principles evolutionary crystal structure search is performed with the goal of constructing the complete phase diagram of SnxSy and discovering new phases as well as new compounds of varying stoichiometry at ambient conditions and pressures up to 100 GPa. The ambient phase of SnS2 with P3\u00afm1 symmetry remains stable up to 28 GPa. Another ambient phase, SnS, experiences a series of phase transformations including \u03b1-SnS to \u03b2-SnS at 9 GPa, followed by \u03b2-SnS to \u03b3-SnS at 40 GPa. \u03b3-SnS is a new high-pressure metallic phase with Pm3\u00afm space group symmetry stable up to 100 GPa, which becomes a superconductor with a maximum Tc = 9.74 K at 40 GPa. Another new metallic compound, Sn3S4 with I4\u00af3d space group symmetry, is predicted to be stable at pressures above 15 GPa, which also becomes a superconductor with relatively high Tc = 21.9 K at 30 GPa.<\/jats:p>","DOI":"10.1063\/1.5018434","type":"journal-article","created":{"date-parts":[[2018,5,15]],"date-time":"2018-05-15T11:29:21Z","timestamp":1526383761000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":33,"title":["Novel phases and superconductivity of tin sulfide compounds"],"prefix":"10.1063","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7038-9726","authenticated-orcid":false,"given":"Joseph M.","family":"Gonzalez","sequence":"first","affiliation":[{"name":"Department of Physics, University of South Florida , Tampa, Florida 33620, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kien","family":"Nguyen-Cong","sequence":"additional","affiliation":[{"name":"Department of Physics, University of South Florida , Tampa, Florida 33620, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brad A.","family":"Steele","sequence":"additional","affiliation":[{"name":"Department of Physics, University of South Florida , Tampa, Florida 33620, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5348-6484","authenticated-orcid":false,"given":"Ivan I.","family":"Oleynik","sequence":"additional","affiliation":[{"name":"Department of Physics, University of South Florida , Tampa, Florida 33620, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2018,5,15]]},"reference":[{"key":"2023062601342747200_c1","doi-asserted-by":"publisher","first-page":"536","DOI":"10.1103\/physrev.143.536","volume":"143","year":"1966","journal-title":"Phys. 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