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Both 2H-P and Cu-P adsorb with their center above a surface bridge site. Consistency is obtained between the experimental and DFT-predicted structural models, with a characteristic change in the corrugation of the four N atoms of the molecule\u2019s macrocycle following metalation. Interestingly, comparison with previously published data for cobalt porphine adsorbed on the same surface evidences a distinct increase in the average height of the N atoms above the surface through the series 2H-P, Cu-P, and cobalt porphine. Such an increase strikingly anti-correlates the DFT-predicted adsorption strength, with 2H-P having the smallest adsorption height despite the weakest calculated adsorption energy. In addition, our findings suggest that for these macrocyclic compounds, substrate-to-molecule charge transfer and adsorption strength may not be univocally correlated.<\/jats:p>","DOI":"10.1063\/1.5084027","type":"journal-article","created":{"date-parts":[[2019,3,1]],"date-time":"2019-03-01T08:51:44Z","timestamp":1551430304000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":16,"title":["Local adsorption structure and bonding of porphine on Cu(111) before and after self-metalation"],"prefix":"10.1063","volume":"150","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0827-2022","authenticated-orcid":false,"given":"D. 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