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Ternary Hg\u2013In\u2013S (HIS) NCs are reported for the first time and found to have the same tetragonal chalcopyrite motif as Cu\u2013In\u2013S and Ag\u2013In\u2013S NCs, corroborated by phonon spectra, while X-ray photoelectron spectroscopic data indicate mercury to be present as Hg+ in the Hg\u2013In\u2013S NCs. Colloidal HIS and Hg\u2013In\u2013S\/ZnS NCs showed little or no variations of the spectral width of the photoluminescence band upon NC size selection, temperature variation in a broad range of 10\u2013350 K, deposition of a ZnS shell, or postsynthesis annealing. All these observations are similar to those reported earlier for Ag\u2013In\u2013S and Ag\u2013In\u2013S\/ZnS NCs and allowed us to assume a general photoluminescence mechanism for all three ternary compounds, based on the model of radiative self-trapped exciton recombination.<\/jats:p>","DOI":"10.1063\/1.5119991","type":"journal-article","created":{"date-parts":[[2019,10,8]],"date-time":"2019-10-08T14:44:31Z","timestamp":1570545871000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":14,"title":["Mercury-indium-sulfide nanocrystals: A new member of the family of ternary in based chalcogenides"],"prefix":"10.1063","volume":"151","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5054-2746","authenticated-orcid":false,"given":"Oleksandr","family":"Stroyuk","sequence":"first","affiliation":[{"name":"Forschungszentrum J\u00fclich GmbH, Helmholtz-Institut Erlangen N\u00fcrnberg f\u00fcr Erneuerbare Energien (HI ERN) 1 , Immerwahrstr. 2, 91058 Erlangen, Germany"},{"name":"L.V. 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