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This allows for the efficient simulation of Franck\u2013Condon dark vibronic spectra. In addition, vibrational angular momentum terms have been implemented into this formalism, as they are important for an accurate description of vibrational wavefunctions spanning double-well potentials. This approach has been used to compute the FC-forbidden vibronic spectrum of the n \u2192 \u03c0* transition of formaldehyde based on a potential energy and transition dipole moment surfaces obtained from explicitly correlated multi-reference configuration interaction calculations. An extensive analysis of the resulting vibronic structure is provided, which allows for a detailed assignment and interpretation of the experimental spectrum.<\/jats:p>","DOI":"10.1063\/5.0003272","type":"journal-article","created":{"date-parts":[[2020,3,18]],"date-time":"2020-03-18T13:43:18Z","timestamp":1584538998000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Account of non-Condon effects in time-independent Raman wavefunction theory: Calculation of the S1\u2008\u2190 S vibronic absorption spectrum of formaldehyde"],"prefix":"10.1063","volume":"152","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0049-4835","authenticated-orcid":false,"given":"Taras","family":"Petrenko","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Theoretische Chemie, Universit\u00e4t Stuttgart , Pfaffenwaldring 55, 70569 Stuttgart, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0623-3254","authenticated-orcid":false,"given":"Guntram","family":"Rauhut","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Theoretische Chemie, Universit\u00e4t Stuttgart , Pfaffenwaldring 55, 70569 Stuttgart, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2020,3,18]]},"reference":[{"key":"2023062609255216500_c1","doi-asserted-by":"publisher","first-page":"041103","DOI":"10.1063\/1.3074100","volume":"130","year":"2009","journal-title":"J. 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