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Only data expressed as Rosenfeld reduced properties could be scaled successfully. Two different methods were used to obtain the scaling parameter \u03b3, one based on polynomial fits to the group (TV\u03b3) and the other based on the Avramov equation. The two methods agree well, except for \u03bb of CCl4. \u03b3 for the thermal conductivity is similar to those for the viscosity and self-diffusion coefficient for the smaller molecules. It is significantly larger for the Lennard-Jones fluid, possibly due to a different dependence on packing fraction, and much larger for polyatomic molecules where heat transfer through internal modes may have an additional effect. Methanol and ammonia, where energy can be transmitted through intermolecular hydrogen bonding, could not be scaled. This work is intended as a practical attempt to examine thermodynamic scaling of the thermal conductivity of real fluids. The divergence of the scaling parameters for different properties is unexpected, suggesting that refinement of theory is required to rationalize this result. For the Lennard-Jones fluid, the Ohtori\u2013Iishi version of the Stokes\u2013Einstein\u2013Sutherland relation applies at high densities in the liquid and supercritical region.<\/jats:p>","DOI":"10.1063\/5.0016389","type":"journal-article","created":{"date-parts":[[2020,9,8]],"date-time":"2020-09-08T15:31:12Z","timestamp":1599579072000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":11,"title":["Thermodynamic or density scaling of the thermal conductivity of liquids"],"prefix":"10.1063","volume":"153","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6732-0488","authenticated-orcid":false,"given":"Kenneth R.","family":"Harris","sequence":"first","affiliation":[{"name":"School of Science, The University of New South Wales , P.O. 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