{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T23:02:27Z","timestamp":1771455747293,"version":"3.50.1"},"reference-count":60,"publisher":"AIP Publishing","issue":"11","license":[{"start":{"date-parts":[[2022,3,15]],"date-time":"2022-03-15T00:00:00Z","timestamp":1647302400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2022,3,15]],"date-time":"2022-03-15T00:00:00Z","timestamp":1647302400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2022,3,21]]},"abstract":"<jats:p>The effect of particle size and support on the catalytic performance of supported subnanometer copper clusters was investigated in the oxidative dehydrogenation of cyclohexene. From among the investigated seven size-selected subnanometer copper particles between a single atom and clusters containing 2\u20137 atoms, the highest activity was observed for the titania-supported copper tetramer with 100% selectivity toward benzene production and being about an order of magnitude more active than not only all the other investigated cluster sizes on the same support but also the same tetramer on the other supports, Al2O3, SiO2, and SnO2. In addition to the profound effect of cluster size on activity and with Cu4 outstanding from the studied series, Cu4 clusters supported on SiO2 provide an example of tuning selectivity through support effects when this particular catalyst also produces cyclohexadiene with about 30% selectivity. Titania-supported Cu5 and Cu7 clusters supported on TiO2 produce a high fraction of cyclohexadiene in contrast to their neighbors, while Cu4 and Cu6 solely produce benzene without any combustion, thus representing odd\u2013even oscillation of selectivity with the number of atoms in the cluster.<\/jats:p>","DOI":"10.1063\/5.0065350","type":"journal-article","created":{"date-parts":[[2022,2,23]],"date-time":"2022-02-23T18:04:39Z","timestamp":1645639479000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":13,"title":["Atom by atom built subnanometer copper cluster catalyst for the highly selective oxidative dehydrogenation of cyclohexene"],"prefix":"10.1063","volume":"156","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3949-5093","authenticated-orcid":false,"given":"Stanislav","family":"Valtera","sequence":"first","affiliation":[{"name":"Department of Nanocatalysis, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 1 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1177-2837","authenticated-orcid":false,"given":"Juraj","family":"Ja\u0161\u00edk","sequence":"additional","affiliation":[{"name":"Department of Nanocatalysis, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 1 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5887-2328","authenticated-orcid":false,"given":"Mykhailo","family":"Vaidulych","sequence":"additional","affiliation":[{"name":"Department of Nanocatalysis, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 1 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9896-4497","authenticated-orcid":false,"given":"Joanna El\u017cbieta","family":"Olsz\u00f3wka","sequence":"additional","affiliation":[{"name":"Department of Nanocatalysis, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 1 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6730-9710","authenticated-orcid":false,"given":"Magda","family":"Zl\u00e1malov\u00e1","sequence":"additional","affiliation":[{"name":"Department of Electrochemical Materials, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 2 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"},{"name":"Department of Inorganic Chemistry, Faculty of Science, Charles University 3 , Hlavova 2030, CZ-128 40 Prague, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9309-8956","authenticated-orcid":false,"given":"Hana","family":"Tar\u00e1bkov\u00e1","sequence":"additional","affiliation":[{"name":"Department of Electrochemical Materials, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 2 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3342-4603","authenticated-orcid":false,"given":"Ladislav","family":"Kavan","sequence":"additional","affiliation":[{"name":"Department of Electrochemical Materials, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 2 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1879-2099","authenticated-orcid":false,"given":"\u0160tefan","family":"Vajda","sequence":"additional","affiliation":[{"name":"Department of Nanocatalysis, J. Heyrovsk\u00fd Institute of Physical Chemistry, v.v.i., Czech Academy of Sciences 1 , Dolej\u0161kova 2155\/3, CZ-182 23 Prague 8, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2022,3,15]]},"reference":[{"key":"2023081004452128300_c1","doi-asserted-by":"publisher","first-page":"1443","DOI":"10.3390\/catal10121443","article-title":"Adipic acid route: Oxidation of cyclohexene vs. cyclohexane","volume":"10","year":"2020","journal-title":"Catalysts"},{"key":"2023081004452128300_c2","doi-asserted-by":"publisher","first-page":"11844","DOI":"10.1021\/acs.jpcc.9b09603","article-title":"Mechanistic studies of the oxidation of cyclohexene to 2-cyclohexen-1-one over ALD prepared titania supported vanadia","volume":"124","year":"2020","journal-title":"J. Chem. Phys. C"},{"key":"2023081004452128300_c3","doi-asserted-by":"publisher","first-page":"469","DOI":"10.12693\/aphyspola.132.469","article-title":"Oxidation of cyclohexene with H2O2 catalyzed by vanadium based polyoxometalates doped modified clays as green catalysts","volume":"132","year":"2017","journal-title":"Acta Phys. Pol., A"},{"key":"2023081004452128300_c4","doi-asserted-by":"publisher","first-page":"1132","DOI":"10.1038\/nature04190","article-title":"Tunable gold catalysts for selective hydrocarbon oxidation under mild conditions","volume":"437","year":"2005","journal-title":"Nature"},{"key":"2023081004452128300_c5","doi-asserted-by":"publisher","first-page":"2868","DOI":"10.1039\/c2gc35677e","article-title":"A large-scale continuous-flow process for the production of adipic acid via catalytic oxidation of cyclohexene with H2O2","volume":"14","year":"2012","journal-title":"Green Chem."},{"key":"2023081004452128300_c6","doi-asserted-by":"publisher","first-page":"371","DOI":"10.1016\/0021-9517(81)90297-9","article-title":"The structure sensitivity of cyclohexane dehydrogenation and hydrogenolysis catalyzed by platinum single crystals at atmospheric pressure","volume":"67","year":"1981","journal-title":"J. Catal."},{"key":"2023081004452128300_c7","doi-asserted-by":"publisher","first-page":"1437","DOI":"10.1007\/s10562-012-0925-y","article-title":"Nickel particle size effects on cyclohexane dehydrogenation: A combined reaction kinetics and surface science study","volume":"142","year":"2012","journal-title":"Catal. Lett."},{"key":"2023081004452128300_c8","doi-asserted-by":"publisher","first-page":"1307","DOI":"10.1002\/cctc.201901795","article-title":"Oxidative dehydrogenation of cyclohexane by Cu vs Pd clusters: Selectivity control by specific cluster dynamics","volume":"12","year":"2020","journal-title":"ChemCatChem"},{"key":"2023081004452128300_c9","doi-asserted-by":"publisher","first-page":"610","DOI":"10.1002\/cctc.202001380","article-title":"COX-resistant oxidative dehydrogenation of cyclohexane catalyzed by sp3@sp2 nanodiamonds towards highly selective cyclohexene production","volume":"13","year":"2021","journal-title":"ChemCatChem"},{"key":"2023081004452128300_c10","doi-asserted-by":"publisher","first-page":"421","DOI":"10.1016\/j.jcat.2009.11.026","article-title":"Oxidative dehydrogenation of cyclohexane over alumina-supported vanadium oxide nanoliths","volume":"269","year":"2010","journal-title":"J. Catal."},{"key":"2023081004452128300_c11","doi-asserted-by":"publisher","first-page":"305","DOI":"10.1016\/0021-9517(75)90040-8","article-title":"Low-energy electron diffraction, work function charge and mass spectrometric studies of chemisorption and dehydrogenation of cyclohexane, cyclohexene and 1,3-cyclohexadiene on the Pt(111) surface","volume":"36","year":"1975","journal-title":"J. Catal."},{"key":"2023081004452128300_c12","doi-asserted-by":"publisher","first-page":"39","DOI":"10.1016\/s1381-1169(97)00255-0","article-title":"Thermochemistry of the selective dehydrogenation of cyclohexane to benzene on Pt surfaces","volume":"131","year":"1998","journal-title":"J. Mol. Catal. A: Chem."},{"key":"2023081004452128300_c13","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1007\/s10562-008-9637-8","article-title":"Influence of particle size on reaction selectivity in cyclohexene hydrogenation and dehydrogenation over silica-supported monodisperse Pt particles","volume":"126","year":"2008","journal-title":"Catal. Lett."},{"key":"2023081004452128300_c14","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/0039-6028(80)90072-2","article-title":"The effect of surface oxygen on hydrocarbon reactions catalyzed by platinum crystal surfaces with variable kink concentrations","volume":"91","year":"1980","journal-title":"Surf. Sci."},{"key":"2023081004452128300_c15","doi-asserted-by":"publisher","first-page":"353","DOI":"10.1098\/rspa.1987.0043","article-title":"Evidence of surface-reaction segregation in cyclohexene hydrogenation and dehydrogenation over supported platinum","volume":"410","year":"1987","journal-title":"Proc. Math. Phys. Eng. Sci."},{"key":"2023081004452128300_c16","doi-asserted-by":"publisher","first-page":"300","DOI":"10.1039\/c4gc01353k","article-title":"Renewable polycarbonates and polyesters from 1,4-cyclohexadiene","volume":"17","year":"2015","journal-title":"Green Chem."},{"key":"2023081004452128300_c17","doi-asserted-by":"publisher","first-page":"1973","DOI":"10.3390\/ma12121973","article-title":"Hydrogen storage for mobility: A review","volume":"12","year":"2019","journal-title":"Materials"},{"key":"2023081004452128300_c18","doi-asserted-by":"publisher","first-page":"2778","DOI":"10.1021\/acs.energyfuels.9b00296","article-title":"The prospect of hydrogen storage using liquid organic hydrogen carriers","volume":"33","year":"2019","journal-title":"Energy Fuels"},{"key":"2023081004452128300_c19","doi-asserted-by":"publisher","first-page":"1181","DOI":"10.1039\/tf9635901181","article-title":"Some reactions of cyclohexene with hydrogen and deuterium on evaporated gold films","volume":"59","year":"1963","journal-title":"Trans. Faraday Soc."},{"key":"2023081004452128300_c20","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1016\/j.susc.2005.09.051","article-title":"Hydrogenation and dehydrogenation of cyclohexene on Pt(100): A sum frequency generation vibrational spectroscopic and kinetic study","volume":"599","year":"2005","journal-title":"Surf. Sci."},{"key":"2023081004452128300_c21","doi-asserted-by":"publisher","first-page":"50","DOI":"10.1016\/j.cattod.2010.12.014","article-title":"Reprint of: Oxidative dehydrogenation of cyclohexane and cyclohexene over supported gold, \u2013palladium catalysts","volume":"160","year":"2011","journal-title":"Catal. Today"},{"key":"2023081004452128300_c22","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1006\/jcat.1996.0359","article-title":"The oxidative dehydrogenation of cyclohexane and cyclohexene over unsupported and supported molybdena catalysts prepared by metal oxide vapor deposition","volume":"164","year":"1996","journal-title":"J. Catal."},{"key":"2023081004452128300_c23","doi-asserted-by":"publisher","first-page":"577","DOI":"10.1038\/nnano.2015.140","article-title":"Catalysis by clusters with precise numbers of atoms","volume":"10","year":"2015","journal-title":"Nat. Nanotechnol."},{"key":"2023081004452128300_c24","doi-asserted-by":"publisher","first-page":"7152","DOI":"10.1021\/acscatal.5b01816","article-title":"Catalysis applications of size-selected cluster deposition","volume":"5","year":"2015","journal-title":"ACS Catal."},{"key":"2023081004452128300_c25","doi-asserted-by":"publisher","first-page":"9336","DOI":"10.1039\/c2cp40162b","article-title":"Oxidative dehydrogenation of cyclohexene on size selected subnanometer cobalt clusters: Improved catalytic performance via evolution of cluster-assembled nanostructures","volume":"14","year":"2012","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023081004452128300_c26","doi-asserted-by":"publisher","first-page":"1632","DOI":"10.1002\/cctc.201200294","article-title":"Support-dependent performance of size-selected subnanometer cobalt cluster-based catalysts in the dehydrogenation of cyclohexene","volume":"4","year":"2012","journal-title":"ChemCatChem"},{"key":"2023081004452128300_c27","doi-asserted-by":"publisher","first-page":"110901","DOI":"10.1063\/1.5020301","article-title":"Perspective: Size selected clusters for catalysis and electrochemistry","volume":"148","year":"2018","journal-title":"J. Chem. Phys."},{"key":"2023081004452128300_c28","doi-asserted-by":"publisher","first-page":"213","DOI":"10.1038\/nmat2384","article-title":"Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane","volume":"8","year":"2009","journal-title":"Nat. Mater."},{"key":"2023081004452128300_c29","doi-asserted-by":"publisher","first-page":"954","DOI":"10.1038\/s41467-019-08819-5","article-title":"Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts","volume":"10","year":"2019","journal-title":"Nat. Commun."},{"key":"2023081004452128300_c30","doi-asserted-by":"publisher","first-page":"10342","DOI":"10.1021\/jp912220w","article-title":"Oxidative decomposition of methanol on subnanometer palladium clusters: The effect of catalyst size and support composition","volume":"114","year":"2010","journal-title":"J. Chem. Phys. C"},{"key":"2023081004452128300_c31","doi-asserted-by":"publisher","first-page":"10754","DOI":"10.1021\/acs.jpcb.8b09910","article-title":"Disentangling coupling effects in the infrared spectra of liquid water","volume":"122","year":"2018","journal-title":"J. Phys. Chem. B"},{"key":"2023081004452128300_c32","doi-asserted-by":"publisher","first-page":"7422","DOI":"10.1021\/jp0701035","article-title":"Structure and morphology of hydroxylated amorphous alumina surfaces","volume":"111","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"2023081004452128300_c33","first-page":"39","article-title":"Nature and estimation of functional groups on solid surfaces","volume-title":"Catalysis: Science and Technology","author":"Anderson","year":"1983"},{"key":"2023081004452128300_c34","doi-asserted-by":"publisher","first-page":"341","DOI":"10.1021\/la026208a","article-title":"FT-IR study of water adsorption on aluminum oxide surfaces","volume":"19","year":"2003","journal-title":"Langmuir"},{"key":"2023081004452128300_c35","doi-asserted-by":"publisher","first-page":"19530","DOI":"10.1021\/jp804296a","article-title":"Al2O3 atomic layer deposition with trimethylaluminum and ozone studied by in situ transmission FTIR spectroscopy and quadrupole mass spectrometry","volume":"112","year":"2008","journal-title":"J. Chem. Phys. C"},{"key":"2023081004452128300_c36","doi-asserted-by":"publisher","first-page":"135","DOI":"10.1016\/s0040-6090(96)08934-1","article-title":"Al3O3 thin film growth on Si(100) using binary reaction sequence chemistry","volume":"292","year":"1997","journal-title":"Thin Solid Films"},{"key":"2023081004452128300_c37","doi-asserted-by":"publisher","first-page":"2179","DOI":"10.1016\/j.apsusc.2007.09.027","article-title":"Nanostructural and surface morphological evolution of chemically sprayed SnO2 thin films","volume":"254","year":"2008","journal-title":"Appl. Surf. Sci."},{"key":"2023081004452128300_c38","doi-asserted-by":"publisher","first-page":"2252","DOI":"10.1016\/j.apsusc.2009.10.047","article-title":"Characteristics of electron beam evaporated nanocrystalline SnO2 thin films annealed in air","volume":"256","year":"2010","journal-title":"Appl. Surf. Sci."},{"key":"2023081004452128300_c39","doi-asserted-by":"publisher","first-page":"209","DOI":"10.1016\/j.jnoncrysol.2005.11.031","article-title":"Electrical, structural and optical properties of SnO2 thin films prepared by spray pyrolysis","volume":"352","year":"2006","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081004452128300_c40","doi-asserted-by":"publisher","first-page":"1706","DOI":"10.1021\/cm400164a","article-title":"In situ infrared spectroscopic study of atomic layer-deposited TiO2 thin films by nonaqueous routes","volume":"25","year":"2013","journal-title":"Chem. Mater."},{"key":"2023081004452128300_c41","doi-asserted-by":"publisher","first-page":"47","DOI":"10.1016\/s0040-6090(97)00340-4","article-title":"The effect of thermal annealing on aerosol-gel deposited SiO2 films: A FTIR deconvolution study","volume":"310","year":"1997","journal-title":"Thin Solid Films"},{"key":"2023081004452128300_c42","doi-asserted-by":"publisher","first-page":"174201","DOI":"10.1063\/1.4871799","article-title":"Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument","volume":"140","year":"2014","journal-title":"J. Chem. Phys."},{"key":"2023081004452128300_c43","volume-title":"NIST Chemistry WebBook, NIST Standard Reference Database Number 69","year":"2021"},{"key":"2023081004452128300_c44","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1088\/0957-4484\/12\/2\/307","article-title":"Topographic characterization of AFM-grown SiO2 on Si","volume":"12","year":"2001","journal-title":"Nanotechnology"},{"key":"2023081004452128300_c45","doi-asserted-by":"publisher","first-page":"826","DOI":"10.1126\/science.1180297","article-title":"Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces","volume":"326","year":"2009","journal-title":"Science"},{"key":"2023081004452128300_c46","doi-asserted-by":"publisher","first-page":"6735","DOI":"10.1039\/c4cp00160e","article-title":"Very small \u2018window of opportunity\u2019 for generating CO oxidation-active Aun on TiO2","volume":"16","year":"2014","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023081004452128300_c47","doi-asserted-by":"publisher","first-page":"9573","DOI":"10.1021\/jp9935992","article-title":"When gold is not noble: Nanoscale gold catalysts","volume":"103","year":"1999","journal-title":"J. Phys. Chem. A"},{"key":"2023081004452128300_c48","doi-asserted-by":"publisher","first-page":"4981","DOI":"10.1021\/acs.chemrev.7b00776","article-title":"Metal catalysts for heterogeneous catalysis: From single atoms to nanoclusters and nanoparticles","volume":"118","year":"2018","journal-title":"Chem. Rev."},{"key":"2023081004452128300_c49","doi-asserted-by":"publisher","first-page":"124710","DOI":"10.1063\/1.2035098","article-title":"Cluster size effects on CO oxidation activity, adsorbate affinity, and temporal behavior of model Aun\/TiO2 catalysts","volume":"123","year":"2005","journal-title":"J. Phys. Chem."},{"key":"2023081004452128300_c50","doi-asserted-by":"publisher","first-page":"1888","DOI":"10.1038\/s41467-020-15850-4","article-title":"CO oxidation activity of non-reducible oxide-supported mass-selected few-atom Pt single-clusters","volume":"11","year":"2020","journal-title":"Nat. Commun."},{"key":"2023081004452128300_c51","doi-asserted-by":"publisher","first-page":"3322","DOI":"10.1021\/acscatal.7b00409","article-title":"Ethylene dehydrogenation on Pt4,7,8 clusters on Al2O3: Strong cluster size dependence linked to preferred catalyst morphologies","volume":"7","year":"2017","journal-title":"ACS Catal."},{"key":"2023081004452128300_c52","doi-asserted-by":"publisher","first-page":"108","DOI":"10.1016\/0021-9517(78)90244-0","article-title":"Determination of the mechanism of cyclohexane dehydrogenation over Pt- and Pt\u2013Pd-supported catalysts through theoretical and experimental studies","volume":"51","year":"1978","journal-title":"J. Catal."},{"key":"2023081004452128300_c53","doi-asserted-by":"publisher","first-page":"24118","DOI":"10.1021\/acs.jpcc.9b06947","article-title":"What is the best size of subnanometer copper clusters for CO2 conversion to methanol at Cu\/TiO2 interfaces? A density functional theory study","volume":"123","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"2023081004452128300_c54","doi-asserted-by":"publisher","first-page":"147793","DOI":"10.1016\/j.apsusc.2020.147793","article-title":"The growth pattern and electronic structures of Cun (n = 1\u201314) clusters on rutile TiO2(110) surface","volume":"536","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"2023081004452128300_c55","doi-asserted-by":"publisher","first-page":"10813","DOI":"10.1021\/jp508220h","article-title":"The role of charge states in the atomic structure of Cun and Ptn (n = 2\u201314 atoms) clusters: A DFT investigation","volume":"118","year":"2014","journal-title":"J. Phys. Chem. A"},{"key":"2023081004452128300_c56","doi-asserted-by":"publisher","first-page":"151772","DOI":"10.1016\/j.apsusc.2021.151772","article-title":"Evolution of atomic and electronic structures of Cun (n = 2\u201310) clusters supported on anatase TiO2(101) surface","volume":"576","year":"2022","journal-title":"Appl. Surf. Sci."},{"key":"2023081004452128300_c57","doi-asserted-by":"publisher","first-page":"1329","DOI":"10.1002\/anie.200603931","article-title":"Water gas shift reaction on Cu and Au nanoparticles supported on CeO2(111) and ZnO(000): Intrinsic activity and importance of support interactions","volume":"46","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023081004452128300_c58","doi-asserted-by":"publisher","first-page":"538","DOI":"10.1021\/ja804893b","article-title":"Control and manipulation of gold nanocatalysis: Effects of metal oxide support thickness and composition","volume":"131","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2023081004452128300_c59","doi-asserted-by":"publisher","first-page":"743","DOI":"10.1007\/s12039-011-0130-3","article-title":"A density functional study on the adsorption of hydrogen molecule onto small copper clusters","volume":"123","year":"2011","journal-title":"J. Chem. Sci."},{"key":"2023081004452128300_c60","doi-asserted-by":"publisher","first-page":"8676","DOI":"10.1021\/jacs.5b03668","article-title":"Carbon dioxide conversion to methanol over size-selected Cu4 clusters at low pressures","volume":"137","year":"2015","journal-title":"J. Am. Chem. Soc."}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0065350\/16539864\/114302_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0065350\/16539864\/114302_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0065350\/16539864\/114302_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T20:20:35Z","timestamp":1748377235000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/156\/11\/114302\/2840981\/Atom-by-atom-built-subnanometer-copper-cluster"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,15]]},"references-count":60,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2022,3,21]]}},"URL":"https:\/\/doi.org\/10.1063\/5.0065350","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2022,3,21]]},"published":{"date-parts":[[2022,3,15]]},"article-number":"114302"}}