{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:11:13Z","timestamp":1791727873030,"version":"4.3.4"},"reference-count":61,"publisher":"AIP Publishing","issue":"23","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2021,12,21]]},"abstract":"<jats:p>It is well known that structure determines property, but obtaining a pair of silver nanoclusters with comparable structures to understand the structure\u2013property relationship is a very challenging task. A new 60-nuclei silver nanocluster (SD\/Ag60a) protected by a mixed-ligand shell of tBuS\u2212 and o-CH3OPhCOO\u2212 was obtained and characterized. Single crystal x-ray diffraction reveals that SD\/Ag60a has an identical metal nuclearity and core\u2013shell structural type to SD\/Ag1 previously reported by our group, whereas the compositions of the core and shell have undergone a rearrangement from an Ag12 cuboctahedron core and an Ag48 rhombicuboctahedron shell in SD\/Ag1 to an Ag14 rhombic dodecahedron core and an oval Ag46 shell in SD\/Ag60a. The core enlargement from Ag12 to Ag14 originates from the replacement of two S2\u2212 in Ag12S15 by two Ag+, which gives a new Ag14S13 core. This result indicates that the metal frameworks of silver nanoclusters have some extent flexibility despite the same nuclearity, which can be influenced by ligands, solvents, anion templates, and others in the embryonic stage of the assembly. Interestingly, different core\u2013shell architectures of Ag60 nanoclusters also significantly endow the different optical absorption bands, photocurrent-generating properties, and luminesecent behaviors. This work not only realizes the regulation of the core\u2013shell structure of silver nanoclusters with the same nuclearity but also provides a comparable model for investigating the relationship of structure\u2013photoelectric properties.<\/jats:p>","DOI":"10.1063\/5.0070138","type":"journal-article","created":{"date-parts":[[2021,12,15]],"date-time":"2021-12-15T11:10:35Z","timestamp":1639566635000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":9,"title":["Structural rearrangement of Ag60 nanocluster endowing different luminescence performances"],"prefix":"10.1063","volume":"155","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7432-6108","authenticated-orcid":false,"given":"Yan-Min","family":"Su","sequence":"first","affiliation":[{"name":"Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University 1 , Jinan 250100, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Yu","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Qingdao University 2 , Qingdao 266071, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8315-3501","authenticated-orcid":false,"given":"Zhi","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University 1 , Jinan 250100, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2181-7402","authenticated-orcid":false,"given":"Zhi-Yong","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University 3 , Xinxiang 453007, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5063-8825","authenticated-orcid":false,"given":"Xian-Qiang","family":"Huang","sequence":"additional","affiliation":[{"name":"Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University 4 , Liaocheng 252000, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9999-9755","authenticated-orcid":false,"given":"Chen-Ho","family":"Tung","sequence":"additional","affiliation":[{"name":"Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University 1 , Jinan 250100, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5966-1207","authenticated-orcid":false,"given":"Di","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University 1 , Jinan 250100, People\u2019s Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2021,12,15]]},"reference":[{"key":"2023062617124993600_c1","doi-asserted-by":"publisher","first-page":"3084","DOI":"10.1021\/acs.accounts.8b00371","volume":"51","year":"2018","journal-title":"Acc. Chem. Res."},{"key":"2023062617124993600_c2","doi-asserted-by":"publisher","first-page":"4832","DOI":"10.1002\/anie.201411944","volume":"54","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c3","doi-asserted-by":"publisher","first-page":"54","DOI":"10.1016\/j.ccr.2016.10.007","volume":"331","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"2023062617124993600_c4","doi-asserted-by":"publisher","first-page":"2422","DOI":"10.1039\/c8cs00800k","volume":"48","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"2023062617124993600_c5","doi-asserted-by":"publisher","first-page":"1871","DOI":"10.1039\/c2cs35252d","volume":"42","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"2023062617124993600_c6","doi-asserted-by":"publisher","first-page":"19550","DOI":"10.1021\/jacs.9b10569","volume":"141","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c7","doi-asserted-by":"publisher","first-page":"14673","DOI":"10.1002\/anie.201906425","volume":"58","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c8","doi-asserted-by":"publisher","first-page":"2297","DOI":"10.1039\/d0cs01393e","volume":"50","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"2023062617124993600_c9","doi-asserted-by":"publisher","first-page":"14727","DOI":"10.1021\/jacs.6b09007","volume":"138","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c10","doi-asserted-by":"publisher","first-page":"10346","DOI":"10.1021\/acs.chemrev.5b00703","volume":"116","year":"2016","journal-title":"Chem. Rev."},{"key":"2023062617124993600_c11","doi-asserted-by":"publisher","first-page":"14418","DOI":"10.1002\/anie.202006454","volume":"59","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c12","doi-asserted-by":"publisher","first-page":"917","DOI":"10.1007\/s11434-016-1091-1","volume":"61","year":"2016","journal-title":"Sci. Bull."},{"key":"2023062617124993600_c13","doi-asserted-by":"publisher","first-page":"12346","DOI":"10.1021\/jacs.7b05243","volume":"139","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c14","doi-asserted-by":"publisher","first-page":"2619","DOI":"10.1021\/acs.jpcc.0c08693","volume":"125","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"2023062617124993600_c15","doi-asserted-by":"publisher","first-page":"10695","DOI":"10.1039\/c4dt00762j","volume":"43","year":"2014","journal-title":"Dalton Trans."},{"key":"2023062617124993600_c16","doi-asserted-by":"publisher","first-page":"12416","DOI":"10.1002\/chem.201404049","volume":"20","year":"2014","journal-title":"Chem. Eur. J."},{"key":"2023062617124993600_c17","doi-asserted-by":"publisher","first-page":"6771","DOI":"10.1039\/c9cc03533h","volume":"55","year":"2019","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c18","doi-asserted-by":"publisher","first-page":"17678","DOI":"10.1021\/ja108684m","volume":"132","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c19","doi-asserted-by":"publisher","first-page":"9318","DOI":"10.1021\/acsnano.8b04233","volume":"12","year":"2018","journal-title":"ACS Nano"},{"key":"2023062617124993600_c20","doi-asserted-by":"publisher","first-page":"8930","DOI":"10.1039\/c7nr00931c","volume":"9","year":"2017","journal-title":"Nanoscale"},{"key":"2023062617124993600_c21","doi-asserted-by":"publisher","first-page":"3601","DOI":"10.1039\/c6nr09632h","volume":"9","year":"2017","journal-title":"Nanoscale"},{"key":"2023062617124993600_c22","doi-asserted-by":"publisher","first-page":"1600","DOI":"10.1021\/jacs.7b12777","volume":"140","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c23","doi-asserted-by":"publisher","first-page":"564","DOI":"10.1039\/c8sc03396j","volume":"10","year":"2019","journal-title":"Chem. Sci."},{"key":"2023062617124993600_c24","doi-asserted-by":"publisher","first-page":"4461","DOI":"10.1039\/c8cc01767k","volume":"54","year":"2018","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c25","doi-asserted-by":"publisher","first-page":"12132","DOI":"10.1073\/pnas.1711972114","volume":"114","year":"2017","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023062617124993600_c26","doi-asserted-by":"publisher","first-page":"480","DOI":"10.1021\/acs.organomet.6b00866","volume":"36","year":"2017","journal-title":"Organometallics"},{"key":"2023062617124993600_c27","doi-asserted-by":"publisher","first-page":"8668","DOI":"10.1002\/anie.202016692","volume":"60","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c28","doi-asserted-by":"publisher","first-page":"4789","DOI":"10.1039\/c9cc09818f","volume":"56","year":"2020","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c29","doi-asserted-by":"publisher","first-page":"20033","DOI":"10.1039\/c8nr05989f","volume":"10","year":"2018","journal-title":"Nanoscale"},{"key":"2023062617124993600_c30","doi-asserted-by":"publisher","first-page":"11898","DOI":"10.1002\/anie.202004268","volume":"59","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c31","doi-asserted-by":"publisher","first-page":"8022","DOI":"10.1039\/c6cc02873j","volume":"52","year":"2016","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c32","doi-asserted-by":"publisher","first-page":"8691","DOI":"10.1039\/c2cc33446a","volume":"48","year":"2012","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c33","doi-asserted-by":"publisher","first-page":"1640","DOI":"10.1002\/chem.201704298","volume":"24","year":"2018","journal-title":"Chem. Eur. J."},{"key":"2023062617124993600_c34","doi-asserted-by":"publisher","first-page":"4407","DOI":"10.1038\/s41467-018-06755-4","volume":"9","year":"2018","journal-title":"Nat. Commun."},{"key":"2023062617124993600_c35","doi-asserted-by":"publisher","first-page":"195","DOI":"10.1002\/anie.201810772","volume":"58","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c36","doi-asserted-by":"publisher","first-page":"17884","DOI":"10.1021\/jacs.9b09460","volume":"141","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c37","doi-asserted-by":"publisher","first-page":"4231","DOI":"10.1002\/anie.202013681","volume":"60","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c38","doi-asserted-by":"publisher","first-page":"3316","DOI":"10.1038\/s41467-020-17198-1","volume":"11","year":"2020","journal-title":"Nat. Commun."},{"key":"2023062617124993600_c39","doi-asserted-by":"publisher","first-page":"15096","DOI":"10.1002\/chem.201803203","volume":"24","year":"2018","journal-title":"Chem. Eur. J."},{"key":"2023062617124993600_c40","doi-asserted-by":"publisher","first-page":"8284","DOI":"10.1039\/c5nr01222h","volume":"7","year":"2015","journal-title":"Nanoscale"},{"key":"2023062617124993600_c41","doi-asserted-by":"publisher","first-page":"9994","DOI":"10.1021\/jacs.7b04678","volume":"139","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c42","doi-asserted-by":"publisher","first-page":"297","DOI":"10.1021\/acsmaterialslett.9b00122","volume":"1","year":"2019","journal-title":"ACS Mater. Lett."},{"key":"2023062617124993600_c43","doi-asserted-by":"publisher","first-page":"5000","DOI":"10.1021\/ja412141j","volume":"136","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c44","doi-asserted-by":"publisher","first-page":"6694","DOI":"10.1002\/anie.201601947","volume":"55","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"2023062617124993600_c45","doi-asserted-by":"publisher","first-page":"1983","DOI":"10.1039\/B419474H","year":"2005","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c46","doi-asserted-by":"publisher","first-page":"5586","DOI":"10.1039\/b812451e","year":"2008","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c47","doi-asserted-by":"publisher","first-page":"5305","DOI":"10.1039\/c7nr00732a","volume":"9","year":"2017","journal-title":"Nanoscale"},{"key":"2023062617124993600_c48","doi-asserted-by":"publisher","first-page":"5397","DOI":"10.1021\/acs.inorgchem.9b00264","volume":"58","year":"2019","journal-title":"Inorg. Chem."},{"key":"2023062617124993600_c49","doi-asserted-by":"publisher","first-page":"10745","DOI":"10.1039\/d0dt01648a","volume":"49","year":"2020","journal-title":"Dalton Trans."},{"key":"2023062617124993600_c50","doi-asserted-by":"publisher","first-page":"14845","DOI":"10.1021\/ja509019k","volume":"136","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c51","doi-asserted-by":"publisher","first-page":"11656","DOI":"10.1039\/c2cc34620f","volume":"48","year":"2012","journal-title":"Chem. Commun."},{"key":"2023062617124993600_c52","doi-asserted-by":"publisher","first-page":"13649","DOI":"10.1039\/c3dt51479j","volume":"42","year":"2013","journal-title":"Dalton Trans."},{"key":"2023062617124993600_c53","doi-asserted-by":"publisher","first-page":"1330","DOI":"10.1039\/b802352m","volume":"38","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"2023062617124993600_c54","doi-asserted-by":"publisher","first-page":"10921","DOI":"10.1021\/ja502295c","volume":"136","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c55","doi-asserted-by":"publisher","first-page":"39","DOI":"10.1016\/s0010-8545(03)00032-8","volume":"245","year":"2003","journal-title":"Coord. Chem. Rev."},{"key":"2023062617124993600_c56","doi-asserted-by":"publisher","first-page":"2558","DOI":"10.1021\/jacs.0c11891","volume":"143","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c57","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.ccr.2007.11.015","volume":"253","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"2023062617124993600_c58","doi-asserted-by":"publisher","first-page":"7589","DOI":"10.1021\/acs.chemrev.5b00074","volume":"115","year":"2015","journal-title":"Chem. Rev."},{"key":"2023062617124993600_c59","doi-asserted-by":"publisher","first-page":"7211","DOI":"10.1021\/ja00283a012","volume":"108","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"2023062617124993600_c60","doi-asserted-by":"publisher","first-page":"3625","DOI":"10.1021\/cr960109i","volume":"99","year":"1999","journal-title":"Chem. Rev."},{"key":"2023062617124993600_c61","doi-asserted-by":"publisher","first-page":"2118","DOI":"10.1007\/s11426-021-1060-3","volume":"64","year":"2021","journal-title":"Sci. China Chem."}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0070138\/13623747\/234303_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0070138\/13623747\/234303_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,6,26]],"date-time":"2023-06-26T19:44:05Z","timestamp":1687808645000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/155\/23\/234303\/200569\/Structural-rearrangement-of-Ag60-nanocluster"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,12,15]]},"references-count":61,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2021,12,21]]}},"URL":"https:\/\/doi.org\/10.1063\/5.0070138","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2021,12,21]]},"published":{"date-parts":[[2021,12,15]]},"article-number":"234303"}}