{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,3]],"date-time":"2025-09-03T10:20:33Z","timestamp":1756894833506,"version":"3.41.2"},"reference-count":74,"publisher":"AIP Publishing","issue":"23","funder":[{"DOI":"10.13039\/501100001663","name":"Volkswagen Foundation","doi-asserted-by":"publisher","award":["88366"],"award-info":[{"award-number":["88366"]}],"id":[{"id":"10.13039\/501100001663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["CU 44\/55-1"],"award-info":[{"award-number":["CU 44\/55-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Transcampus Research Award","award":["tC RA 2020-01"],"award-info":[{"award-number":["tC RA 2020-01"]}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2022,6,21]]},"abstract":"<jats:p>Dispersion interactions are one of the components of van der Waals (vdW) forces that play a key role in the understanding of intermolecular interactions in many physical, chemical, and biological processes. The theory of dispersion forces was developed by London in the early years of quantum mechanics. However, it was only in the 1960s that it was recognized that for molecules lacking an inversion center, such as chiral and helical molecules, there are chirality-sensitive corrections to the dispersion forces proportional to the rotatory power known from the theory of circular dichroism and with the same distance scaling law R\u22126 as the London energy. The discovery of the chirality-induced spin selectivity effect in recent years has led to an additional twist in the study of chiral molecular systems, showing a close relation between spin and molecular geometry. Motivated by it, we propose in this investigation to describe the mutual induction of charge and spin-density fluctuations in a pair A\u2013B of chiral molecules by a simple physical model. The model assumes that the same fluctuating electric fields responsible for vdW forces can induce a magnetic response via a Rashba-like term so that a spin\u2013orbit field acting on molecule B is generated by the electric field arising from charge density fluctuations in molecule A (and vice versa). Within a second-order perturbative approach, these contributions manifest as an effective intermolecular exchange interaction. Although expected to be weaker than the standard London forces, these interactions display the same R\u22126 distance scaling.<\/jats:p>","DOI":"10.1063\/5.0090266","type":"journal-article","created":{"date-parts":[[2022,6,3]],"date-time":"2022-06-03T17:35:10Z","timestamp":1654277710000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":14,"title":["The contribution of intermolecular spin interactions to the London dispersion forces between chiral molecules"],"prefix":"10.1063","volume":"156","author":[{"given":"M.","family":"Geyer","sequence":"first","affiliation":[{"name":"Institute for Materials Science and Max\u00a0Bergmann Center of Biomaterials, Dresden University of Technology 1 , 01062 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8121-8041","authenticated-orcid":false,"given":"R.","family":"Gutierrez","sequence":"additional","affiliation":[{"name":"Institute for Materials Science and Max\u00a0Bergmann Center of Biomaterials, Dresden University of Technology 1 , 01062 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5237-4851","authenticated-orcid":false,"given":"V.","family":"Mujica","sequence":"additional","affiliation":[{"name":"Arizona State University, School of Molecular Sciences 2 , P.O. 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