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Contrary to non-relativistic density functional theory (DFT), spin\u2013orbit coupling, however, leads to a non-vanishing paramagnetic current density. Density functionals depending on the kinetic energy density, such as meta-generalized gradient approximations, should therefore be constructed in the framework of current DFT (CDFT). The latter has previously exclusively been used in the regime of strong magnetic fields. Herein, we present a consistent CDFT approach for relativistic DFT, including spin\u2013orbit coupling. Furthermore, we assess the importance of the current density terms for ground-state energies, excitation energies, nuclear magnetic resonance shielding, and spin\u2013spin coupling constants, as well as hyperfine coupling constants, \u0394g-shifts, and the nuclear quadrupole interaction tensor in electron paramagnetic resonance (EPR) spectroscopy. The most notable changes are found for EPR properties. The impact of the current-dependent terms rises with the number of unpaired electrons, and consequently, the EPR properties are more sensitive toward CDFT. Considerable changes are observed for the strongly constrained and appropriately normed functionals, as well as the B97M family and TASK. The current density terms are less important when exact exchange is incorporated. At the same time, the current-dependent kernel ensures the stability of response calculations in all cases. We, therefore, strongly recommend to use the framework of CDFT for self-consistent spin\u2013orbit calculations.<\/jats:p>","DOI":"10.1063\/5.0122394","type":"journal-article","created":{"date-parts":[[2022,11,7]],"date-time":"2022-11-07T09:33:31Z","timestamp":1667813611000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":39,"title":["Current density functional framework for spin\u2013orbit coupling"],"prefix":"10.1063","volume":"157","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8234-260X","authenticated-orcid":false,"given":"Christof","family":"Holzer","sequence":"first","affiliation":[{"name":"Institute of Theoretical Solid State Physics, Karlsruhe Institute of Technology (KIT) 1 , Wolfgang-Gaede-Stra\u00dfe 1, 76131 Karlsruhe, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8344-113X","authenticated-orcid":false,"given":"Yannick J.","family":"Franzke","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie, Philipps-Universit\u00e4t Marburg 2 , Hans-Meerwein-Stra\u00dfe 4, 35032 Marburg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1895-2037","authenticated-orcid":false,"given":"Ansgar","family":"Pausch","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT) 3 , Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2022,11,22]]},"reference":[{"key":"2024011915040370900_c1","doi-asserted-by":"publisher","first-page":"403","DOI":"10.1021\/cr2001383","volume":"112","year":"2012","journal-title":"Chem. 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