{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T06:14:24Z","timestamp":1790662464937,"version":"4.1.0"},"reference-count":80,"publisher":"AIP Publishing","issue":"21","license":[{"start":{"date-parts":[[2022,12,2]],"date-time":"2022-12-02T00:00:00Z","timestamp":1669939200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2022,12,2]],"date-time":"2022-12-02T00:00:00Z","timestamp":1669939200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Corning Inc.","award":["CM00002159\/SA\/01"],"award-info":[{"award-number":["CM00002159\/SA\/01"]}]},{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"publisher","award":["RGF\/EA\/180060"],"award-info":[{"award-number":["RGF\/EA\/180060"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"publisher","award":["Dorothy Hodgkin Research Fellowship"],"award-info":[{"award-number":["Dorothy Hodgkin Research Fellowship"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/L015544\/1"],"award-info":[{"award-number":["EP\/L015544\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021200","name":"ISIS Neutron and Muon Source","doi-asserted-by":"publisher","award":["STU0173"],"award-info":[{"award-number":["STU0173"]}],"id":[{"id":"10.13039\/501100021200","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100011889","name":"Diamond Light Source","doi-asserted-by":"publisher","award":["STU0173"],"award-info":[{"award-number":["STU0173"]}],"id":[{"id":"10.13039\/100011889","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","award":["2013\/07793-6"],"award-info":[{"award-number":["2013\/07793-6"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","award":["311069\/2020-7"],"award-info":[{"award-number":["311069\/2020-7"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","award":["310870\/2020-8"],"award-info":[{"award-number":["310870\/2020-8"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-AC02-06CH11357"],"award-info":[{"award-number":["DE-AC02-06CH11357"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2022,12,7]]},"abstract":"<jats:p>Neutron diffraction with magnesium isotope substitution, high energy x-ray diffraction, and 29Si, 27Al, and 25Mg solid-state nuclear magnetic resonance (NMR) spectroscopy were used to measure the structure of glassy diopside (CaMgSi2O6), enstatite (MgSiO3), and four (MgO)x(Al2O3)y(SiO2)1\u2212x\u2212y glasses, with x = 0.375 or 0.25 along the 50 mol.\u2009% silica tie-line (1 \u2212 x \u2212 y = 0.5) or with x = 0.3 or 0.2 along the 60 mol.\u2009% silica tie-line (1 \u2212 x \u2212 y = 0.6). The bound coherent neutron scattering length of the isotope 25Mg was remeasured, and the value of 3.720(12) fm was obtained from a Rietveld refinement of the powder diffraction patterns measured for crystalline 25MgO. The diffraction results for the glasses show a broad asymmetric distribution of Mg\u2013O nearest-neighbors with a coordination number of 4.40(4) and 4.46(4) for the diopside and enstatite glasses, respectively. As magnesia is replaced by alumina along a tie-line with 50 or 60 mol.\u2009% silica, the Mg\u2013O coordination number increases with the weighted bond distance as less Mg2+ ions adopt a network-modifying role and more of these ions adopt a predominantly charge-compensating role. 25Mg magic angle spinning (MAS) NMR results could not resolve the different coordination environments of Mg2+ under the employed field strength (14.1\u00a0T) and spinning rate (20\u00a0kHz). The results emphasize the power of neutron diffraction with isotope substitution to provide unambiguous site-specific information on the coordination environment of magnesium in disordered materials.<\/jats:p>","DOI":"10.1063\/5.0125879","type":"journal-article","created":{"date-parts":[[2022,12,2]],"date-time":"2022-12-02T06:29:59Z","timestamp":1669962599000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":32,"title":["Structure of diopside, enstatite, and magnesium aluminosilicate glasses: A joint approach using neutron and x-ray diffraction and solid-state NMR"],"prefix":"10.1063","volume":"157","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9124-3232","authenticated-orcid":false,"given":"Hesameddin","family":"Mohammadi","sequence":"first","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6455-3710","authenticated-orcid":false,"given":"Rita","family":"Mendes Da Silva","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6501-8525","authenticated-orcid":false,"given":"Anita","family":"Zeidler","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2247-7171","authenticated-orcid":false,"given":"Lawrence V. D.","family":"Gammond","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3394-2403","authenticated-orcid":false,"given":"Florian","family":"Gehlhaar","sequence":"additional","affiliation":[{"name":"Institut Laue Langevin 2 , 71 Avenue des Martyrs, 38042 Grenoble Cedex 9, France"},{"name":"Institut f\u00fcr Anorganische Chemie, Universit\u00e4t Leipzig 3 , Johannisallee 29, 04103 Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6538-2204","authenticated-orcid":false,"suffix":"Jr.","given":"Marcos","family":"de Oliveira","sequence":"additional","affiliation":[{"name":"Instituto de F\u00edsica de S\u00e3o Carlos, Universidade de S\u00e3o Paulo 4 , CP 369, S\u00e3o Carlos SP 13566-590, SP, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4291-3169","authenticated-orcid":false,"given":"Hugo","family":"Damasceno","sequence":"additional","affiliation":[{"name":"Instituto de F\u00edsica de S\u00e3o Carlos, Universidade de S\u00e3o Paulo 4 , CP 369, S\u00e3o Carlos SP 13566-590, SP, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6536-0117","authenticated-orcid":false,"given":"Hellmut","family":"Eckert","sequence":"additional","affiliation":[{"name":"Instituto de F\u00edsica de S\u00e3o Carlos, Universidade de S\u00e3o Paulo 4 , CP 369, S\u00e3o Carlos SP 13566-590, SP, Brazil"},{"name":"Institut f\u00fcr Physikalische Chemie, WWU M\u00fcnster 5 , Corrensstra\u00dfe 30, D48149 M\u00fcnster, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6647-9865","authenticated-orcid":false,"given":"Randall E.","family":"Youngman","sequence":"additional","affiliation":[{"name":"Science and Technology Division, Corning Incorporated 6 , Corning, New York 14831, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruce G.","family":"Aitken","sequence":"additional","affiliation":[{"name":"Science and Technology Division, Corning Incorporated 6 , Corning, New York 14831, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1204-0750","authenticated-orcid":false,"given":"Henry E.","family":"Fischer","sequence":"additional","affiliation":[{"name":"Institut Laue Langevin 2 , 71 Avenue des Martyrs, 38042 Grenoble Cedex 9, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8873-525X","authenticated-orcid":false,"given":"Holger","family":"Kohlmann","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, Universit\u00e4t Leipzig 3 , Johannisallee 29, 04103 Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3554-0707","authenticated-orcid":false,"given":"Laurent","family":"Cormier","sequence":"additional","affiliation":[{"name":"Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC), Sorbonne Universit\u00e9, CNRS UMR 7590 7 , Mus\u00e9um National d\u2019Histoire Naturelle, IRD UMR 206, 4 place Jussieu, 75005 Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7007-7749","authenticated-orcid":false,"given":"Chris J.","family":"Benmore","sequence":"additional","affiliation":[{"name":"X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory 8 , 9700 South Cass Avenue, Lemont, Illinois 60439, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8671-1011","authenticated-orcid":false,"given":"Philip S.","family":"Salmon","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2022,12,2]]},"reference":[{"key":"2023081006553511900_c1","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1524\/zkri.1983.165.14.65","volume":"165","year":"1983","journal-title":"Z. Kristallogr."},{"key":"2023081006553511900_c2","doi-asserted-by":"publisher","first-page":"43","DOI":"10.2183\/pjab.55.43","volume":"55","year":"1979","journal-title":"Proc. Jpn. Acad., Ser. B"},{"key":"2023081006553511900_c3","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1524\/zkri.1969.129.1-4.65","volume":"129","year":"1969","journal-title":"Z. Kristallogr."},{"key":"2023081006553511900_c4","doi-asserted-by":"publisher","first-page":"166","DOI":"10.1016\/0031-9201(70)90050-6","volume":"3","year":"1970","journal-title":"Phys. Earth Planet. Inter."},{"key":"2023081006553511900_c5","doi-asserted-by":"publisher","first-page":"2191","DOI":"10.2138\/am-2015-5303","volume":"100","year":"2015","journal-title":"Am. Mineral."},{"key":"2023081006553511900_c6","first-page":"218","volume":"60","year":"1975","journal-title":"Am. Mineral."},{"key":"2023081006553511900_c7","doi-asserted-by":"publisher","first-page":"517","DOI":"10.1016\/j.jnoncrysol.2009.04.074","volume":"356","year":"2010","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c8","doi-asserted-by":"publisher","first-page":"100067","DOI":"10.1016\/j.jmro.2022.100067","volume":"12\u201313","year":"2022","journal-title":"J. Magn. Reson. Open"},{"key":"2023081006553511900_c9","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1016\/b978-0-12-397018-3.00002-8","volume":"75","year":"2012","journal-title":"Annu. Rep. NMR Spectrosc."},{"key":"2023081006553511900_c10","doi-asserted-by":"crossref","first-page":"1519","DOI":"10.1007\/978-3-319-93728-1","volume-title":"Springer Handbook of Glass","author":"Musgraves","year":"2019"},{"key":"2023081006553511900_c11","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1007\/978-3-319-93728-1","volume-title":"Springer Handbook of Glass","author":"Musgraves","year":"2019"},{"key":"2023081006553511900_c12","doi-asserted-by":"publisher","first-page":"129","DOI":"10.1016\/j.pepi.2007.04.002","volume":"162","year":"2007","journal-title":"Phys. Earth Planet. Inter."},{"key":"2023081006553511900_c13","volume-title":"Magmas under Pressure","author":"Kono","year":"2018"},{"key":"2023081006553511900_c14","doi-asserted-by":"publisher","first-page":"100024","DOI":"10.1016\/j.nocx.2019.100024","volume":"3","year":"2019","journal-title":"J. Non-Cryst. Solids: X"},{"key":"2023081006553511900_c15","doi-asserted-by":"publisher","first-page":"21938","DOI":"10.1073\/pnas.2014519117","volume":"117","year":"2020","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2023081006553511900_c16","doi-asserted-by":"publisher","first-page":"224204","DOI":"10.1103\/physrevb.83.224204","volume":"83","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023081006553511900_c17","doi-asserted-by":"publisher","first-page":"233","DOI":"10.1088\/0034-4885\/69\/1\/r05","volume":"69","year":"2006","journal-title":"Rep. Prog. Phys."},{"key":"2023081006553511900_c18","doi-asserted-by":"publisher","first-page":"473","DOI":"10.1107\/s0567739472001251","volume":"28","year":"1972","journal-title":"Acta Crystallogr., Sect. A: Found. Adv."},{"key":"2023081006553511900_c19","volume-title":"Solid-State Physics","year":"2009","edition":"4th ed."},{"key":"2023081006553511900_c20","doi-asserted-by":"publisher","first-page":"416","DOI":"10.1107\/s0108767394013292","volume":"51","year":"1995","journal-title":"Acta Crystallogr., Sect. A: Found. Adv."},{"key":"2023081006553511900_c21","doi-asserted-by":"publisher","first-page":"6115","DOI":"10.1103\/physrevb.58.6115","volume":"58","year":"1998","journal-title":"Phys. Rev. B"},{"key":"2023081006553511900_c22","doi-asserted-by":"publisher","first-page":"074501","DOI":"10.1063\/5.0049399","volume":"155","year":"2021","journal-title":"J. Chem. Phys."},{"key":"2023081006553511900_c23","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1016\/0022-3093(90)90240-m","volume":"119","year":"1990","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c24","doi-asserted-by":"publisher","first-page":"498","DOI":"10.1016\/j.gca.2013.04.026","volume":"122","year":"2013","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2023081006553511900_c25","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1016\/0092-640x(91)90012-s","volume":"49","year":"1991","journal-title":"At. Data Nucl. Data Tables"},{"key":"2023081006553511900_c26","doi-asserted-by":"publisher","first-page":"26","DOI":"10.1080\/10448639208218770","volume":"3","year":"1992","journal-title":"Neutron News"},{"key":"2023081006553511900_c27","doi-asserted-by":"publisher","first-page":"453","DOI":"10.6028\/jres.070a.037","volume":"70A","year":"1966","journal-title":"J. Res. Natl. Bur. Stand., Sect. A"},{"key":"2023081006553511900_c28","doi-asserted-by":"publisher","first-page":"s160","DOI":"10.1007\/s003390101087","volume":"74","year":"2002","journal-title":"Appl. Phys. A"},{"key":"2023081006553511900_c29","doi-asserted-by":"publisher","first-page":"284126","DOI":"10.1088\/0953-8984\/24\/28\/284126","volume":"24","year":"2012","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023081006553511900_c30","doi-asserted-by":"publisher","first-page":"55","DOI":"10.1016\/0921-4526(93)90108-i","volume":"192","year":"1993","journal-title":"Physica B"},{"key":"2023081006553511900_c31","year":"2022"},{"key":"2023081006553511900_c32","doi-asserted-by":"publisher","first-page":"544","DOI":"10.1107\/s0021889813003531","volume":"46","year":"2013","journal-title":"J. Appl. Cryst."},{"key":"2023081006553511900_c33","doi-asserted-by":"publisher","first-page":"505105","DOI":"10.1088\/0953-8984\/24\/50\/505105","volume":"24","year":"2012","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023081006553511900_c34","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1016\/0369-643x(58)90029-x","volume":"3","year":"1958","journal-title":"Nucl. Instrum."},{"key":"2023081006553511900_c35","doi-asserted-by":"publisher","first-page":"361","DOI":"10.1016\/s0029-554x(75)80006-1","volume":"127","year":"1975","journal-title":"Nucl. Instrum. Methods"},{"key":"2023081006553511900_c36","doi-asserted-by":"publisher","first-page":"495","DOI":"10.1016\/0029-554x(78)90009-5","volume":"157","year":"1978","journal-title":"Nucl. Instrum. Methods"},{"key":"2023081006553511900_c37","doi-asserted-by":"publisher","first-page":"12779","DOI":"10.1021\/ja00156a015","volume":"117","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"2023081006553511900_c38","doi-asserted-by":"publisher","first-page":"497","DOI":"10.1016\/s0009-2614(02)00398-6","volume":"356","year":"2002","journal-title":"Chem. Phys. Lett."},{"key":"2023081006553511900_c39","doi-asserted-by":"publisher","first-page":"70","DOI":"10.1002\/mrc.984","volume":"40","year":"2002","journal-title":"Magn. Reson. Chem."},{"key":"2023081006553511900_c40","first-page":"1","volume-title":"Special Applications. NMR Basic Principles and Progress","author":"Pfeifer","year":"1993"},{"key":"2023081006553511900_c41","doi-asserted-by":"publisher","first-page":"244","DOI":"10.1016\/j.jmr.2008.03.001","volume":"192","year":"2008","journal-title":"J. Magn. Reson."},{"key":"2023081006553511900_c42","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1016\/j.ssnmr.2013.10.003","volume":"55\u201356","year":"2013","journal-title":"Solid State Nucl. Magn. Reson."},{"key":"2023081006553511900_c43","doi-asserted-by":"publisher","first-page":"630","DOI":"10.1103\/physrev.94.630","volume":"94","year":"1954","journal-title":"Phys. Rev."},{"key":"2023081006553511900_c44","doi-asserted-by":"publisher","first-page":"688","DOI":"10.1063\/1.1716296","volume":"29","year":"1958","journal-title":"Rev. Sci. Instrum."},{"key":"2023081006553511900_c45","doi-asserted-by":"publisher","first-page":"56","DOI":"10.1016\/j.jmr.2019.02.006","volume":"301","year":"2019","journal-title":"J. Magn. Reson."},{"key":"2023081006553511900_c46","doi-asserted-by":"publisher","first-page":"296","DOI":"10.1006\/jmre.2000.2179","volume":"147","year":"2000","journal-title":"J. Magn. Reson."},{"key":"2023081006553511900_c47","doi-asserted-by":"publisher","first-page":"2249","DOI":"10.1107\/s160057671601493x","volume":"49","year":"2016","journal-title":"J. Appl. Cryst."},{"key":"2023081006553511900_c48","doi-asserted-by":"publisher","first-page":"646","DOI":"10.1107\/s1600576716000455","volume":"49","year":"2016","journal-title":"J. Appl. Cryst."},{"key":"2023081006553511900_c49","doi-asserted-by":"publisher","first-page":"678","DOI":"10.1107\/s0021889804011744","volume":"37","year":"2004","journal-title":"J. Appl. Cryst."},{"key":"2023081006553511900_c50","doi-asserted-by":"publisher","first-page":"064503","DOI":"10.1063\/5.0079607","volume":"156","year":"2022","journal-title":"J. Chem. Phys."},{"key":"2023081006553511900_c51","doi-asserted-by":"publisher","first-page":"159","DOI":"10.1016\/0079-6565(92)80001-V","volume":"24","year":"1992","journal-title":"Prog. Nucl. Magn. Reson. Spectrosc."},{"key":"2023081006553511900_c52","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1007\/978-3-642-79127-7","volume-title":"Solid-State NMR IV Methods and Applications of Solid-State NMR","author":"Bl\u00fcmich","year":"1994"},{"key":"2023081006553511900_c53","doi-asserted-by":"publisher","first-page":"237","DOI":"10.1016\/bs.arnmr.2015.04.004","volume":"86","year":"2015","journal-title":"Annu. Rep. NMR Spectrosc."},{"key":"2023081006553511900_c54","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1016\/j.gca.2013.10.025","volume":"125","year":"2014","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2023081006553511900_c55","doi-asserted-by":"publisher","first-page":"4471","DOI":"10.1021\/cm1011795","volume":"22","year":"2010","journal-title":"Chem. Mater."},{"key":"2023081006553511900_c56","doi-asserted-by":"publisher","first-page":"120383","DOI":"10.1016\/j.jnoncrysol.2020.120383","volume":"550","year":"2020","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c57","doi-asserted-by":"publisher","first-page":"209","DOI":"10.1016\/0022-3093(92)90069-v","volume":"149","year":"1992","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c58","doi-asserted-by":"publisher","first-page":"14941","DOI":"10.1021\/acs.jpcc.9b03600","volume":"123","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"2023081006553511900_c59","doi-asserted-by":"publisher","first-page":"229","DOI":"10.1088\/0022-3719\/2\/2\/305","volume":"2","year":"1969","journal-title":"J. Phys. C: Solid State Phys."},{"key":"2023081006553511900_c60","doi-asserted-by":"publisher","first-page":"11443","DOI":"10.1088\/0953-8984\/18\/50\/004","volume":"18","year":"2006","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023081006553511900_c61","doi-asserted-by":"publisher","first-page":"15243","DOI":"10.1021\/jp9079603","volume":"113","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"2023081006553511900_c62","doi-asserted-by":"publisher","first-page":"2787","DOI":"10.1016\/j.jnoncrysol.2011.02.045","volume":"357","year":"2011","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c63","doi-asserted-by":"publisher","first-page":"8","DOI":"10.1016\/s0022-3093(00)00139-3","volume":"273","year":"2000","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c64","first-page":"31","volume-title":"Mineralogical Society of America Special Paper Number Two: Pyroxenes and Amphiboles: Crystal Chemistry and Phase Petrology","author":"Papike","year":"1969"},{"key":"2023081006553511900_c65","doi-asserted-by":"publisher","first-page":"1459","DOI":"10.2138\/am-2000-1015","volume":"85","year":"2000","journal-title":"Am. Mineral."},{"key":"2023081006553511900_c66","doi-asserted-by":"publisher","first-page":"440","DOI":"10.1016\/s0022-3093(01)00693-7","volume":"293\u2013295","year":"2001","journal-title":"J. Non-Cryst. Solids"},{"key":"2023081006553511900_c67","doi-asserted-by":"publisher","first-page":"4518","DOI":"10.1111\/jace.17876","volume":"104","year":"2021","journal-title":"J. Am. Ceram. Soc."},{"key":"2023081006553511900_c68","doi-asserted-by":"publisher","first-page":"695","DOI":"10.2138\/am.2007.2535","volume":"92","year":"2007","journal-title":"Am. Mineral."},{"key":"2023081006553511900_c69","doi-asserted-by":"publisher","first-page":"6747","DOI":"10.1021\/jp711417t","volume":"112","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"2023081006553511900_c70","doi-asserted-by":"publisher","first-page":"111","DOI":"10.1016\/j.chemgeo.2008.06.008","volume":"256","year":"2008","journal-title":"Chem. Geol."},{"key":"2023081006553511900_c71","doi-asserted-by":"publisher","first-page":"4004","DOI":"10.1021\/jp9700342","volume":"101","year":"1997","journal-title":"J. Phys. Chem. B"},{"key":"2023081006553511900_c72","doi-asserted-by":"publisher","first-page":"8440","DOI":"10.1021\/acs.jpcb.5b02469","volume":"119","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"2023081006553511900_c73","doi-asserted-by":"publisher","first-page":"1011","DOI":"10.1016\/0016-7037(91)90159-3","volume":"55","year":"1991","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2023081006553511900_c74","doi-asserted-by":"publisher","first-page":"105","DOI":"10.2138\/rmg.2022.87.03","volume":"87","year":"2022","journal-title":"Rev. Mineral. Geochem."},{"key":"2023081006553511900_c75","unstructured":"P. S.\u2008Salmon and A.\u2008Zeidler, Structure of diopside, enstatite and magnesium aluminosilicate glasses: A joint approach using neutron and x-ray diffraction and solid-state NMR, University of Bath Research Data Archive, 2022, 10.15125\/BATH-01192."},{"key":"2023081006553511900_c76","unstructured":"F.\u2008Gehlhaar, H. E.\u2008Fischer, T.\u2008Hansen, and H.\u2008Kohlmann, Accurate neutron scattering lengths of Sm- and Nd-isotopes, Institut Laue-Langevin, Grenoble, France, 2021, https:\/\/doi.ill.fr\/10.5291\/ILL-DATA.1-10-50."},{"key":"2023081006553511900_c77","unstructured":"P. S.\u2008Salmon, H.\u2008Eckert, H. E.\u2008Fischer, L. V. D.\u2008Gammond, R.\u2008Mendes Da Silva, H.\u2008Mohammadi, and A.\u2008Zeidler, Structural change in phosphate-based glassy precursors to superionic conducting glass-ceramic electrolytes, Institut Laue-Langevin, Grenoble, France 2019, 10.5291\/ILL-DATA.6-05-1009."},{"key":"2023081006553511900_c78","unstructured":"P. S.\u2008Salmon, B. G.\u2008Aitken, H. E.\u2008Fischer, L. V. D.\u2008Gammond, R.\u2008Mendes Da Silva, H.\u2008Mohammadi, and A.\u2008Zeidler, Structure of magnesium aluminosilicate glass by neutron diffraction with isotope substitution, Institut Laue-Langevin, Grenoble, France, 2019, 10.5291\/ILL-DATA.6-05-1002."},{"key":"2023081006553511900_c79","unstructured":"E.\u2008Gir\u00f3n Lange, F. H.\u2008Cova, G. J.\u2008Cuello, H.\u2008Mohammadi, P. S.\u2008Salmon, G.\u2008Vaughan, and A.\u2008Zeidler, Structure of aluminosilicate glasses by NDIS, Institut Laue-Langevin, Grenoble, France, 2021, 10.5291\/ILL-DATA.INTER-562."},{"key":"2023081006553511900_c80"}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0125879\/16743031\/214503_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0125879\/16743031\/214503_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/5.0125879\/16743031\/214503_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T16:20:40Z","timestamp":1748362840000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/157\/21\/214503\/2842301\/Structure-of-diopside-enstatite-and-magnesium"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,12,2]]},"references-count":80,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2022,12,7]]}},"URL":"https:\/\/doi.org\/10.1063\/5.0125879","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"value":"0021-9606","type":"print"},{"value":"1089-7690","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2022,12,7]]},"published":{"date-parts":[[2022,12,2]]},"article-number":"214503"}}