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The values of the first- and second-order properties of the aromatic molecules are calculated using the response theory with the asymptotically corrected LPBE0 functional. The second-order properties of the closed-shell alkaline-earth-metal atoms are obtained using the expectation-value coupled cluster theory and of the open-shell alkali-metal atoms using analytical wavefunctions. These properties are used for the calculation of the dispersion Cn,displ,m and induction Cn,indl,m coefficients (Cnl,m=Cn,displ,m+Cn,indl,m) with n up to 12 using the available implemented analytical formulas. It is shown that the inclusion of the coefficients with n &amp;gt; 6 is important for reproducing the interaction energy in the van der Waals region at R \u2248 6 \u00c5. The reported long-range potentials should be useful for constructing the analytical potentials valid for the whole intermolecular interaction range, which are needed for spectroscopic and scattering studies.<\/jats:p>","DOI":"10.1063\/5.0135929","type":"journal-article","created":{"date-parts":[[2023,2,16]],"date-time":"2023-02-16T18:01:00Z","timestamp":1676570460000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["Long-range interactions of aromatic molecules with alkali-metal and alkaline-earth-metal atoms"],"prefix":"10.1063","volume":"158","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4351-5066","authenticated-orcid":false,"given":"Leonid","family":"Shirkov","sequence":"first","affiliation":[{"name":"Institute of Physics, Polish Academy of Sciences 1 , Al. 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