{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T11:43:15Z","timestamp":1777462995853,"version":"3.51.4"},"reference-count":38,"publisher":"AIP Publishing","issue":"8","funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["0122U000760"],"award-info":[{"award-number":["0122U000760"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100001388","name":"Wenner-Gren Foundation","doi-asserted-by":"publisher","award":["GFU 2022-0036"],"award-info":[{"award-number":["GFU 2022-0036"]}],"id":[{"id":"10.13039\/100001388","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2023,2,28]]},"abstract":"<jats:p>On the ground of multi-reference configuration interaction calculations with an account of spin\u2013orbit coupling, we have predicted the probability of two unknown spin-forbidden transitions in the spectrum of the N2\u00a0molecule: the electric dipole A\u20325\u03a3g+ \u2192 A3\u03a3u+ emission system and the magnetic dipole a\u20321\u03a3u\u2212 \u2190 A3\u03a3u+ transition. The radiative lifetime of the lowest A\u20325\u03a3g+ sublevel is less than a microsecond; the magnetic transition induced by the spin current in the triplet state is predicted with relatively low oscillator strength (f = 10\u221210), which still could be detectable.<\/jats:p>","DOI":"10.1063\/5.0136465","type":"journal-article","created":{"date-parts":[[2023,2,2]],"date-time":"2023-02-02T21:34:01Z","timestamp":1675373641000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":11,"title":["Prediction of new spin-forbidden transitions in the N2 molecule\u2014the electric dipole A\u20325\u03a3g+ \u2192 A3\u03a3u+ and magnetic dipole a\u20321\u03a3u\u2212\u2190 A3\u03a3u+ transitions"],"prefix":"10.1063","volume":"158","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9165-9649","authenticated-orcid":false,"given":"Boris","family":"Minaev","sequence":"first","affiliation":[{"name":"Department of Chemistry and Nanomaterial Sciences, The Bohdan Khmelnytsky National University 1 , Cherkasy, Ukraine"},{"name":"Department of Physics and Astronomy, Uppsala University 2 , Uppsala, Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1958-5614","authenticated-orcid":false,"given":"Ramon S.","family":"da Silva","sequence":"additional","affiliation":[{"name":"Departamento de F\u00edsica, Universidade Federal de Juiz de Fora 3 , Juiz de Fora, MG, Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7669-1424","authenticated-orcid":false,"given":"Olexander","family":"Panchenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nanomaterial Sciences, The Bohdan Khmelnytsky National University 1 , Cherkasy, Ukraine"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1763-9383","authenticated-orcid":false,"given":"Hans","family":"\u00c5gren","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, Uppsala University 2 , Uppsala, Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2023,2,23]]},"reference":[{"key":"2023081020061828300_c1","doi-asserted-by":"publisher","first-page":"113","DOI":"10.1063\/1.555546","volume":"6","year":"1977","journal-title":"J. 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