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In general, the recombination process is selective only for spin-coherence between singlet and triplet states, and it is not, in general, selective for spin polarization. We find that spin polarization selectivity only arises in hopping-mediated electron transfer. We describe how this effective spin-polarization selectivity is a consequence of spin-polarization generated transiently in the intermediate state. The recombination process also augments the coherent spin dynamics of the charge separated state, which is found to have a significant effect on the recombination dynamics and to destroy any long-lived spin polarization. Although we only consider a simple donor\u2013bridge\u2013acceptor system, the framework we present here can be straightforwardly extended to describe spin-selective recombination processes in more complex systems.<\/jats:p>","DOI":"10.1063\/5.0150269","type":"journal-article","created":{"date-parts":[[2023,5,15]],"date-time":"2023-05-15T10:32:59Z","timestamp":1684146779000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":16,"title":["Spin selective charge recombination in chiral donor\u2013bridge\u2013acceptor triads"],"prefix":"10.1063","volume":"158","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0625-731X","authenticated-orcid":false,"given":"Thomas P.","family":"Fay","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of California 1 , Berkeley, California 94720, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2766-0688","authenticated-orcid":false,"given":"David T.","family":"Limmer","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California 1 , Berkeley, California 94720, USA"},{"name":"Kavli Energy Nanoscience Institute at Berkeley 2 , Berkeley, California 94720, USA"},{"name":"Chemical Sciences Division, Lawrence Berkeley National Laboratory 3 , Berkeley, California 94720, USA"},{"name":"Materials Science Division, Lawrence Berkeley National Laboratory 4 , Berkeley, California 94720, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2023,5,15]]},"reference":[{"key":"2024051500005083000_c1","doi-asserted-by":"publisher","first-page":"4989","DOI":"10.1021\/acsnano.1c01347","article-title":"A chirality-based quantum leap","volume":"16","year":"2022","journal-title":"ACS Nano"},{"key":"2024051500005083000_c2","doi-asserted-by":"crossref","unstructured":"A.\n            Privitera\n          , D.Faccio, D.Giuri, D.Genovese, F.Tassinari, L.Mummolo, M.Chiesa, C.Fontanesi, E.Salvadori, and A.Cornia, C.Tomasini, and R.Sessoli, \u201cChallenges in the direct detection of chirality-induced spin selectivity: Investigation of foldamer-based donor\/acceptor dyads,\u201d chemRxiv (2022).10.26434\/chemrxiv-2022-dx58w","DOI":"10.26434\/chemrxiv-2022-dx58w"},{"key":"2024051500005083000_c3","doi-asserted-by":"publisher","first-page":"2106629","DOI":"10.1002\/adma.202106629","article-title":"Theory of chirality induced spin selectivity: Progress and challenges","volume":"34","year":"2022","journal-title":"Adv. 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