{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T11:21:12Z","timestamp":1753874472883,"version":"3.41.2"},"reference-count":56,"publisher":"AIP Publishing","issue":"17","funder":[{"DOI":"10.13039\/501100001809","name":"The National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["22173082","21773213"],"award-info":[{"award-number":["22173082","21773213"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"The Zhejiang Provincial Natural Science Foundation of China","award":["LY22B030005"],"award-info":[{"award-number":["LY22B030005"]}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2023,5,7]]},"abstract":"<jats:p>Understanding vacuum ultraviolet photodissociation dynamics of Carbonyl sulfide (OCS) is of considerable importance in the study of atmospheric chemistry. Yet, photodissociation dynamics of the CS(X1\u03a3+) + O(3Pj=2,1,0) channels following excitation to the 21\u03a3+(\u03bd1\u2032,1,0) state has not been clearly understood so far. Here, we investigate the O(3Pj=2,1,0) elimination dissociation processes in the resonance-state selective photodissociation of OCS between 147.24 and 156.48\u00a0nm by using the time-sliced velocity-mapped ion imaging technique. The total kinetic energy release spectra are found to exhibit highly structured profiles, indicative of the formation of a broad range of vibrational states of CS(1\u03a3+). The fitted CS(1\u03a3+) vibrational state distributions differ for the three 3Pj spin\u2013orbit states, but a general trend of the inverted characteristics is observed. Additionally, the wavelength-dependent behaviors are also observed in the vibrational populations for CS(1\u03a3+, v). The CS(X1\u03a3+, v = 0) has a significantly strong population at several shorter wavelengths, and the most populated CS(X1\u03a3+, v) is gradually transferred to a higher vibrational state with the decrease in the photolysis wavelength. The measured overall \u03b2-values for the three 3Pj spin\u2013orbit channels slightly increase and then abruptly decrease as the photolysis wavelength increases, while the vibrational dependences of \u03b2-values show an irregularly decreasing trend with increasing CS(1\u03a3+) vibrational excitation at all studied photolysis wavelengths. The comparison of the experimental observations for this titled channel and the S(3Pj) channel reveals that two different intersystem crossing mechanisms may be involved in the formation of the CS(X1\u03a3+) + O(3Pj=2,1,0) photoproducts via the 21\u03a3+ state.<\/jats:p>","DOI":"10.1063\/5.0150850","type":"journal-article","created":{"date-parts":[[2023,5,4]],"date-time":"2023-05-04T10:05:38Z","timestamp":1683194738000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":2,"title":["Resonance-state selective photodissociation dynamics of OCS + <i>hv<\/i> \u2192 CS(X1\u03a3+) + O(3Pj=2,1,0) via the 21\u03a3+ state"],"prefix":"10.1063","volume":"158","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2935-2777","authenticated-orcid":false,"given":"Qian","family":"Liu","sequence":"first","affiliation":[{"name":"Hangzhou Institute of Advanced Studies, Zhejiang Normal University 1 , 1108 Gengwen Road, Hangzhou 311231, Zhejiang Province, People\u2019s Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9445-8287","authenticated-orcid":false,"given":"Zheng","family":"Li","sequence":"additional","affiliation":[{"name":"Hangzhou Institute of Advanced Studies, Zhejiang Normal University 1 , 1108 Gengwen Road, Hangzhou 311231, Zhejiang Province, People\u2019s Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1627-9793","authenticated-orcid":false,"given":"Peng","family":"Liu","sequence":"additional","affiliation":[{"name":"Hangzhou Institute of Advanced Studies, Zhejiang Normal University 1 , 1108 Gengwen Road, Hangzhou 311231, Zhejiang Province, People\u2019s Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xueming","family":"Yang","sequence":"additional","affiliation":[{"name":"Hangzhou Institute of Advanced Studies, Zhejiang Normal University 1 , 1108 Gengwen Road, Hangzhou 311231, Zhejiang Province, People\u2019s Republic of China"},{"name":"State Key Laboratory of Molecular Reaction Dynamics and Dalian Coherent Light Source, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 2 , 457 Zhongshan Road, Dalian, Liaoning 116023, People\u2019s Republic of China"},{"name":"Department of Chemistry, College of Science, Southern University of Science and Technology 3 , Shenzhen 518055, People\u2019s Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3040-1481","authenticated-orcid":false,"given":"Shengrui","family":"Yu","sequence":"additional","affiliation":[{"name":"Hangzhou Institute of Advanced Studies, Zhejiang Normal University 1 , 1108 Gengwen Road, Hangzhou 311231, Zhejiang Province, People\u2019s Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2023,5,4]]},"reference":[{"key":"2023081105031367000_c1","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1029\/gl003i002p00073","volume":"3","year":"1976","journal-title":"Geophys. 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