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The results were interpreted using an analytical model for the composition-dependent structure in which the zinc ions do not act as network formers. Four-coordinated aluminum atoms were found to be in the majority for all the investigated glasses, with five-coordinated aluminum atoms as the main minority species. Mean Al\u2013O bond distances of 1.764(5) and 1.855(5) \u00c5 were obtained for the four- and five-coordinated aluminum atoms, respectively. The coordination environment of zinc was not observed to be invariant. Instead, it is dependent on whether zinc plays a predominantly network-modifying or charge-compensating role and, therefore, varies systematically with the glass composition. The Zn\u2013O coordination number and bond distance were found to be 4.36(9) and 2.00(1) \u00c5, respectively, for the network-modifying role vs 5.96(10) and 2.08(1) \u00c5, respectively, for the charge-compensating role. The more open coordination environment of the charge-compensator is related to an enhanced probability of zinc finding bridging oxygen atoms as nearest-neighbors, reflecting a change in the connectivity of the glass network comprising four-coordinated silicon and aluminum atoms as the alumina content is increased.<\/jats:p>","DOI":"10.1063\/5.0157790","type":"journal-article","created":{"date-parts":[[2023,8,8]],"date-time":"2023-08-08T06:32:29Z","timestamp":1691476349000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":13,"title":["Mapping the structural trends in zinc aluminosilicate glasses"],"prefix":"10.1063","volume":"159","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6455-3710","authenticated-orcid":false,"given":"Rita","family":"Mendes Da Silva","sequence":"first","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6501-8525","authenticated-orcid":false,"given":"Anita","family":"Zeidler","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9124-3232","authenticated-orcid":false,"given":"Hesameddin","family":"Mohammadi","sequence":"additional","affiliation":[{"name":"Department of Physics, University of Bath 1 , Bath BA2 7AY, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2247-7171","authenticated-orcid":false,"given":"Lawrence V. 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