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Incorporating logical segments into a circuit needs physical bonds between the magnetic molecules or clusters involved. In this framework, we systematically study ultrafast laser-induced spin-manipulation scenarios on a closed system of three carbon chains to which three Ni atoms are attached. After the inclusion of spin\u2013orbit coupling and an external magnetic field, different ultrafast spin dynamics scenarios involving spin-flip and long-distance spin-transfer processes are achieved by various appropriately well-tailored time-resolved laser pulses within subpicosecond timescales. We additionally study the various effects of an external magnetic field on spin-flip and spin-transfer processes. Moreover, we obtain spin-dynamics processes induced by a double laser pulse, rather than a single one. We suggest enhancing the spatial addressability of spin-flip and spin-transfer processes. The findings presented in this article will improve our knowledge of the magnetic properties of carbon-based magnetic molecular structures. They also support the relevant experimental realization of spin dynamics and their potential applications in future molecular spintronics devices.<\/jats:p>","DOI":"10.1063\/5.0158160","type":"journal-article","created":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T06:24:51Z","timestamp":1693203891000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":14,"title":["Ultrafast control of laser-induced spin-dynamics scenarios on two-dimensional Ni3@C63H54 magnetic system"],"prefix":"10.1063","volume":"159","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-6453-2663","authenticated-orcid":false,"given":"Mohamed","family":"Barhoumi","sequence":"first","affiliation":[{"name":"Department of Physics, Rheinland-Pf\u00e4lzische Technische Universit\u00e4t Kaiserslautern (RPTU) Kaiserslautern-Landau 1 , P.O. Box 3049, 67653 Kaiserslautern, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4305-858X","authenticated-orcid":false,"given":"Jing","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Theoretical Chemistry, Ulm University 2 , 89081 Ulm, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1181-3704","authenticated-orcid":false,"given":"Georgios","family":"Lefkidis","sequence":"additional","affiliation":[{"name":"Department of Physics, Rheinland-Pf\u00e4lzische Technische Universit\u00e4t Kaiserslautern (RPTU) Kaiserslautern-Landau 1 , P.O. 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