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We focus on the very rare D+ + O+ + D reaction channel in which the sequential fragmentation mechanisms were found to dominate the dynamics. Aided by theory, the state-selective formation and breakup of the transient OD+(a1\u0394, b1\u03a3+) is traced, and the most likely dissociation path\u2014OD+: a1\u0394 or b1\u03a3+ \u2192 A 3\u03a0 \u2192 X 3\u03a3\u2212 \u2192 B 3\u03a3\u2212\u2014involving a combination of spin\u2013orbit and non-adiabatic charge transfer transitions is determined. The multi-step transition probability of this complex transition sequence in the intermediate fragment ion is directly evaluated as a function of the energy of the transient OD+ above its lowest dissociation limit from the measured ratio of the D+ + O+ + D and competing D+ + D+ + O sequential fragmentation channels, which are measured simultaneously. Our coupled-channel time-dependent dynamics calculations reproduce the general trends of these multi-state relative transition rates toward the three-body fragmentation channels.<\/jats:p>","DOI":"10.1063\/5.0159300","type":"journal-article","created":{"date-parts":[[2023,9,5]],"date-time":"2023-09-05T10:35:43Z","timestamp":1693910143000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":6,"title":["Efficiency of charge transfer in changing the dissociation dynamics of OD+ transients formed after the photo-fragmentation of D2O"],"prefix":"10.1063","volume":"159","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4604-4431","authenticated-orcid":false,"given":"W.","family":"Iskandar","sequence":"first","affiliation":[{"name":"Chemical Sciences Division, Lawrence Berkeley National Laboratory 1 , Berkeley, California 94720, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8891-1359","authenticated-orcid":false,"given":"T. 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