{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T07:07:16Z","timestamp":1792048036383,"version":"4.4.0"},"reference-count":50,"publisher":"AIP Publishing","issue":"23","funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-1955940"],"award-info":[{"award-number":["CHE-1955940"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["ACI-1449723"],"award-info":[{"award-number":["ACI-1449723"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["MRI-1828187"],"award-info":[{"award-number":["MRI-1828187"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000005","name":"U.S. Department of Defense","doi-asserted-by":"publisher","award":["HPCMP Applications Software Initiative (HASI)"],"award-info":[{"award-number":["HPCMP Applications Software Initiative (HASI)"]}],"id":[{"id":"10.13039\/100000005","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2023,6,21]]},"abstract":"<jats:p>The many-body expansion (MBE) is promising for the efficient, parallel computation of lattice energies in organic crystals. Very high accuracy should be achievable by employing coupled-cluster singles, doubles, and perturbative triples at the complete basis set limit [CCSD(T)\/CBS] for the dimers, trimers, and potentially tetramers resulting from the MBE, but such a brute-force approach seems impractical for crystals of all but the smallest molecules. Here, we investigate hybrid or multi-level approaches that employ CCSD(T)\/CBS only for the closest dimers and trimers and utilize much faster methods like M\u00f8ller\u2013Plesset perturbation theory (MP2) for more distant dimers and trimers. For trimers, MP2 is supplemented with the Axilrod\u2013Teller\u2013Muto (ATM) model of three-body dispersion. MP2(+ATM) is shown to be a very effective replacement for CCSD(T)\/CBS for all but the closest dimers and trimers. A limited investigation of tetramers using CCSD(T)\/CBS suggests that the four-body contribution is entirely negligible. The large set of CCSD(T)\/CBS dimer and trimer data should be valuable in benchmarking approximate methods for molecular crystals and allows us to see that a literature estimate of the core-valence contribution of the closest dimers to the lattice energy using just MP2 was overbinding by 0.5 kJ mol\u22121, and an estimate of the three-body contribution from the closest trimers using the T0 approximation in local CCSD(T) was underbinding by 0.7 kJ mol\u22121. Our CCSD(T)\/CBS best estimate of the 0\u00a0K lattice energy is \u221254.01 kJ mol\u22121, compared to an estimated experimental value of \u221255.3 \u00b1 2.2 kJ mol\u22121.<\/jats:p>","DOI":"10.1063\/5.0159410","type":"journal-article","created":{"date-parts":[[2023,6,15]],"date-time":"2023-06-15T11:25:00Z","timestamp":1686828300000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":15,"title":["Benchmark coupled-cluster lattice energy of crystalline benzene and assessment of multi-level approximations in the many-body expansion"],"prefix":"10.1063","volume":"158","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0683-7613","authenticated-orcid":false,"given":"Carlos H.","family":"Borca","sequence":"first","affiliation":[{"name":"Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology 1 , Atlanta, Georgia 30332, USA"},{"name":"Department of Chemical and Biological Engineering, School of Engineering and Applied Science, Princeton University 2 , 41 Olden Street, Princeton, New Jersey 08544, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0900-2849","authenticated-orcid":false,"given":"Zachary L.","family":"Glick","sequence":"additional","affiliation":[{"name":"Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology 1 , Atlanta, Georgia 30332, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2395-3229","authenticated-orcid":false,"given":"Derek P.","family":"Metcalf","sequence":"additional","affiliation":[{"name":"Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology 1 , Atlanta, Georgia 30332, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2852-5864","authenticated-orcid":false,"given":"Lori A.","family":"Burns","sequence":"additional","affiliation":[{"name":"Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology 1 , Atlanta, Georgia 30332, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5570-7666","authenticated-orcid":false,"given":"C. David","family":"Sherrill","sequence":"additional","affiliation":[{"name":"Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, Georgia Institute of Technology 1 , Atlanta, Georgia 30332, USA"},{"name":"School of Computational Science and Engineering, Georgia Institute of Technology 3 , Atlanta, Georgia 30332, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2023,6,15]]},"reference":[{"key":"2024061500005580400_c1","doi-asserted-by":"publisher","first-page":"288","DOI":"10.1021\/ct0502357","volume":"2","year":"2006","journal-title":"J. Chem. Theory Comput."},{"key":"2024061500005580400_c2","doi-asserted-by":"publisher","first-page":"4544","DOI":"10.1063\/1.1673986","volume":"53","year":"1970","journal-title":"J. Chem. 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