{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T11:21:45Z","timestamp":1753874505456,"version":"3.41.2"},"reference-count":35,"publisher":"AIP Publishing","issue":"14","funder":[{"DOI":"10.13039\/100000001","name":"US National Science Foundation","doi-asserted-by":"crossref","award":["CHE-2155232"],"award-info":[{"award-number":["CHE-2155232"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"crossref"}]},{"name":"UC Riverside Dissertation Year Fellowship"},{"name":"the University Annual Scientific Research Plan of Anhui Province","award":["2022AH010013"],"award-info":[{"award-number":["2022AH010013"]}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2023,10,14]]},"abstract":"<jats:p>Photo-predissociation of rovibrational levels of SH (A2\u03a3+, v\u2032 = 0\u20136) is studied using the high-n Rydberg atom time-of-flight technique. Spin\u2013orbit branching fractions of the S(3PJ=2,1,0) products are measured in the product translational energy distributions. The SH A2\u03a3+v\u2032 = 0 state predissociates predominantly via coupling to the 4\u03a3\u2212 repulsive state. As the vibrational level v\u2032 increases, predissociation dynamics change drastically, with all three repulsive states (4\u03a3\u2212, 2\u03a3\u2212, and 4\u03a0) involved in the dissociation. Nonadiabatic interactions and quantum interferences among these dissociation pathways affect the fine-structure state distributions of the S(3PJ=2,1,0) products.<\/jats:p>","DOI":"10.1063\/5.0176504","type":"journal-article","created":{"date-parts":[[2023,10,12]],"date-time":"2023-10-12T09:57:20Z","timestamp":1697104640000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":1,"title":["Predissociation dynamics of the A2\u03a3+ state of SH radical: Fine-structure state distributions of the S(3PJ) products"],"prefix":"10.1063","volume":"159","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-1373-0536","authenticated-orcid":false,"given":"Yuan","family":"Qin","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of California at Riverside , Riverside, California 92521, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8570-7774","authenticated-orcid":false,"given":"Xianfeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California at Riverside , Riverside, California 92521, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu","family":"Song","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California at Riverside , Riverside, California 92521, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1041-6136","authenticated-orcid":false,"given":"Ge","family":"Sun","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California at Riverside , Riverside, California 92521, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3700-151X","authenticated-orcid":false,"given":"Jingsong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California at Riverside , Riverside, California 92521, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2023,10,12]]},"reference":[{"key":"2023101209570939800_c1","doi-asserted-by":"publisher","first-page":"427","DOI":"10.1080\/00268978200101301","volume":"46","year":"1982","journal-title":"Mol. 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