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The setup, Mass Analytical Tool to Research Interstellar ICES, allowed us to detect newly formed species at low abundances. However, we found that with the increase in molecular complexity over the years, the detection of larger photoproducts was hindered by the dynamic range of detectors used. Here, we introduce a method to overcome this issue that we expect to be useful for similar applications in other research fields. The concept is based on a precisely controlled high-energy pulser that regulates the voltage across the deflection plates of the ToF-MS instrument to deflect the most abundant species and prevent them from reaching the detector. In this way, the detector sensitivity can be increased from an operating voltage of 2500\u00a0V up to 3000\u00a0V. The applicability is first illustrated in the simple case of an argon matrix, where 40Ar+ ions are deflected to increase the detection sensitivity for 40Ar2+ at m\/z = 20 and 40Ar2+ at m\/z = 80 by a factor 30. Similarly, it is shown that substantially larger complex organic molecules, an important species in astrochemical reaction networks, can be measured for UV irradiated methanol ice.<\/jats:p>","DOI":"10.1063\/5.0186448","type":"journal-article","created":{"date-parts":[[2024,2,29]],"date-time":"2024-02-29T13:56:06Z","timestamp":1709214966000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":1,"title":["Pulsed ion deflection to overcome detector saturation in cryogenic ice sampling"],"prefix":"10.1063","volume":"95","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-8218-5647","authenticated-orcid":false,"given":"P.","family":"Samarth","sequence":"first","affiliation":[{"name":"Laboratory for Astrophysics, Leiden Observatory, Leiden University , PO Box 9513, NL2300 RA Leiden,","place":["the Netherlands"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"Bulak","sequence":"additional","affiliation":[{"name":"Laboratory for Astrophysics, Leiden Observatory, Leiden University , PO Box 9513, NL2300 RA Leiden,","place":["the Netherlands"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"D.","family":"Paardekooper","sequence":"additional","affiliation":[{"name":"Laboratory for Astrophysics, Leiden Observatory, Leiden University , PO Box 9513, NL2300 RA Leiden,","place":["the Netherlands"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6877-5046","authenticated-orcid":false,"given":"K.-J.","family":"Chuang","sequence":"additional","affiliation":[{"name":"Laboratory for Astrophysics, Leiden Observatory, Leiden University , PO Box 9513, NL2300 RA Leiden,","place":["the Netherlands"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8322-3538","authenticated-orcid":false,"given":"H.","family":"Linnartz","sequence":"additional","affiliation":[{"name":"Laboratory for Astrophysics, Leiden Observatory, Leiden University , PO Box 9513, NL2300 RA Leiden,","place":["the Netherlands"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2024,2,29]]},"reference":[{"key":"2024123115064391600_c1","doi-asserted-by":"publisher","first-page":"30","DOI":"10.3847\/1538-4365\/ac2a48","article-title":"2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules","volume":"259","year":"2022","journal-title":"Astrophys. 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