{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T21:28:57Z","timestamp":1790630937247,"version":"4.1.0"},"reference-count":121,"publisher":"AIP Publishing","issue":"8","funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-2305293"],"award-info":[{"award-number":["CHE-2305293"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2024,2,28]]},"abstract":"<jats:p>The ionization energies (IEs) of RuC, RhC, OsC, IrC, and PtC are assigned by the measurement of their two-photon ionization thresholds. Although late transition metal\u2013carbon bonds are of major importance in organometallic chemistry and catalysis, accurate and precise fundamental thermochemical data on these chemical bonds are mainly lacking in the literature. Based on their two-photon ionization thresholds, in this work, we assign IE(RuC) = 7.439(40) eV, IE(RhC) = 7.458(32) eV, IE(OsC) = 8.647(25) eV, IE(IrC) = 8.933(74) eV, and IE(PtC) = 9.397(32) eV. These experimentally derived IEs are further confirmed through quantum chemical calculations using coupled-cluster single double perturbative triple methods that are extrapolated to the complete basis set limit using a three-parameter mixed Gaussian\/exponential extrapolation scheme and corrected for spin\u2013orbit effects using a semiempirical method. The electronic structure and chemical bonding of these MC species are discussed in the context of these ionization energy measurements. The IEs of RuC, RhC, OsC, and IrC closely mirror the IEs of the corresponding transition metal atoms, suggesting that for these species, the (n + 1)s electrons of the transition metals are not significantly involved in chemical bonding.<\/jats:p>","DOI":"10.1063\/5.0194848","type":"journal-article","created":{"date-parts":[[2024,2,23]],"date-time":"2024-02-23T06:06:27Z","timestamp":1708668387000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":7,"title":["Adiabatic ionization energies of RuC, RhC, OsC, IrC, and PtC"],"prefix":"10.1063","volume":"160","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1363-1306","authenticated-orcid":false,"given":"Dakota M.","family":"Merriles","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Utah , Salt Lake City, Utah 84112, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yexalen","family":"Barrera-Casas","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Utah , Salt Lake City, Utah 84112, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3662-358X","authenticated-orcid":false,"given":"Annie S.","family":"Knapp","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Utah , Salt Lake City, Utah 84112, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2386-7315","authenticated-orcid":false,"given":"Michael D.","family":"Morse","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Utah , Salt Lake City, Utah 84112, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2024,2,23]]},"reference":[{"key":"2024022311060052500_c1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/978-94-009-1565-7","volume-title":"The Chemistry of Transition Metal Carbides and Nitrides","author":"Oyama","year":"1996"},{"key":"2024022311060052500_c2","doi-asserted-by":"publisher","first-page":"185","DOI":"10.1021\/cr0204606","volume":"105","year":"2005","journal-title":"Chem. 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