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Predissociation lifetimes are determined by discretizing continuum states in the variational method nuclear motion calculation by restricting the calculation to a finite range of internuclear separations. Varying this range gives a series of avoided crossings between quasi-bound states associated with the A 2\u03a3+ and continuum states, from which predissociation lifetimes are extracted. 424 quasi-bound A 2\u03a3+ state rovibronic energy levels are analyzed, and 374 predissociation lifetimes are produced, offering good coverage of the predissociation region. Agreement with measured lifetimes is satisfactory, and a majority of computed results were within experimental uncertainty. A previously unreported A 2\u03a3+ state predissociation channel that goes via X 2\u03a0 is identified in the calculations. A Python package, binSLT, produced to calculate predissociation lifetimes, associated line broadening parameters, and lifetime uncertainties is made available. The PECs and other curves from this work will be used to produce a rovibronic ExoMol line list and temperature-dependent photodissociation cross sections for the hydroxyl radical.<\/jats:p>","DOI":"10.1063\/5.0198241","type":"journal-article","created":{"date-parts":[[2024,4,10]],"date-time":"2024-04-10T10:15:51Z","timestamp":1712744151000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":26,"title":["Predissociation dynamics of the hydroxyl radical (OH) based on a five-state spectroscopic model"],"prefix":"10.1063","volume":"160","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3240-8567","authenticated-orcid":false,"given":"Georgi B.","family":"Mitev","sequence":"first","affiliation":[{"name":"Department of Physics and Astronomy, University College London , Gower St., London WC1E 6BT, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4994-5238","authenticated-orcid":false,"given":"Jonathan","family":"Tennyson","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, University College London , Gower St., London WC1E 6BT, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9286-9501","authenticated-orcid":false,"given":"Sergei N.","family":"Yurchenko","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, University College London , Gower St., London WC1E 6BT, United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2024,4,10]]},"reference":[{"key":"2024041010154672900_c1","doi-asserted-by":"publisher","first-page":"129","DOI":"10.1063\/1674-0068\/cjcp2003026","volume":"33","year":"2020","journal-title":"Chin. 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