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In many of these applications, the electrode surface is operated outside the point (potential) of zero charge, which attracts counter-ions to form the electric double layer and controls the surface properties. Here, by applying density functional theory-based finite-field molecular dynamics simulations, we have studied the effect of water adsorption energy Eads on surface acidity and the Helmholtz capacitance of BiVO4 as an example of metal oxide electrodes with weakly chemisorbed water. This allows us to establish the effect of Eads on the coordination number, the H-bond network, and the orientation of chemisorbed water by comparing an oxide series composed of BiVO4, TiO2, and SnO2. In particular, it is found that a positive correlation exists between the degree of asymmetry \u0394CH in the Helmholtz capacitance and the strength of Eads. This correlation is verified and extended further to graphene-like systems with physisorbed water, where the electric double layers (EDLs) are controlled by electronic charge rather than proton charge as in the oxide series. Therefore, this work reveals a general relationship between water adsorption energy Eads and EDLs, which is relevant to both electrochemical reactivity and the electrowetting of aqueous interfaces.<\/jats:p>","DOI":"10.1063\/5.0226111","type":"journal-article","created":{"date-parts":[[2024,9,9]],"date-time":"2024-09-09T07:07:15Z","timestamp":1725865635000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["Molecular picture of electric double layers with weakly adsorbed water"],"prefix":"10.1063","volume":"161","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-0108-224X","authenticated-orcid":false,"given":"Mei","family":"Jia","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Biomolecular Recognition and Sensing, Henan Joint International Research Laboratory of Chemo\/Biosensing and Early Diagnosis of Major Diseases, College of Chemistry and Chemical Engineering, Shangqiu Normal University 1 , Shangqiu 476000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Junyi","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, Xiamen University 2 , Xiamen 361005, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-9190-5494","authenticated-orcid":false,"given":"Qixiang","family":"Liu","sequence":"additional","affiliation":[{"name":"Laboratory Construction and Management Center, Shangqiu Normal University 3 , Shangqiu 476000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5652-6621","authenticated-orcid":false,"given":"Xiaohui","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, Xiamen University 2 , Xiamen 361005, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7167-0840","authenticated-orcid":false,"given":"Chao","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry - \u00c5ngstr\u00f6m Laboratory, Uppsala University 4 , L\u00e4gerhyddsv\u00e4gen 1, P. 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