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Previous scanning probe microscopy and x-ray spectroscopy studies revealed surprisingly that the TiO2 [rutile (110)] surface selectively adsorbed atmospheric carboxylic acids, which typically exist in only parts-per-billion concentrations. In this work, we used in situ sum-frequency vibrational spectroscopy to study the interaction between rutile (110) and typical VOC molecules, including formic acid, acetic acid, and formaldehyde. Spectra from all three adsorbed molecules on rutile (110) were similar to the rutile surface spectrum in the ambient atmosphere, showing a broad resonance near 2950\u00a0cm\u22121 that can be attributed to the bridging bidentate adsorption of corresponding compounds. In contrast, on a fused silica surface, a molecular monodentate adsorption configuration was observed for all the molecules, with aliphatic carbons appearing to be the dominant adventitious species.<\/jats:p>","DOI":"10.1063\/5.0231581","type":"journal-article","created":{"date-parts":[[2024,11,15]],"date-time":"2024-11-15T12:07:34Z","timestamp":1731672454000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":5,"title":["Specific and high-affinity adsorption of volatile organic compounds on titanium dioxide surface"],"prefix":"10.1063","volume":"161","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9347-8657","authenticated-orcid":false,"given":"Xinyi","family":"Liu","sequence":"first","affiliation":[{"name":"Physics Department, State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures [Ministry of Education (MOE)], Fudan University , Shanghai 200433,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Zhou","sequence":"additional","affiliation":[{"name":"Physics Department, State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures [Ministry of Education (MOE)], Fudan University , Shanghai 200433,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-4987-6081","authenticated-orcid":false,"given":"Xinyue","family":"Sheng","sequence":"additional","affiliation":[{"name":"Physics Department, State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures [Ministry of Education (MOE)], Fudan University , Shanghai 200433,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Li","sequence":"additional","affiliation":[{"name":"Physics Department, State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures [Ministry of Education (MOE)], Fudan University , Shanghai 200433,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0566-671X","authenticated-orcid":false,"given":"Wei-Tao","family":"Liu","sequence":"additional","affiliation":[{"name":"Physics Department, State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures [Ministry of Education (MOE)], Fudan University , Shanghai 200433,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2024,11,15]]},"reference":[{"issue":"6","key":"2024111512072956300_c1","doi-asserted-by":"publisher","first-page":"1113","DOI":"10.1039\/c2cy00490a","volume":"2","year":"2012","journal-title":"Catal. 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