{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T11:24:29Z","timestamp":1753874669608,"version":"3.41.2"},"reference-count":44,"publisher":"AIP Publishing","issue":"13","funder":[{"DOI":"10.13039\/501100012190","name":"Ministry of Science and Higher Education of the Russian Federation","doi-asserted-by":"publisher","award":["122021000038-7","FWRW-2022-0001"],"award-info":[{"award-number":["122021000038-7","FWRW-2022-0001"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2024,10,7]]},"abstract":"<jats:p>In this work, we explore the electronic properties and chemical bonding in the recently discovered mineral zaykovite, the first natural rhodium selenide Rh3Se4. We comprehensively studied the bulk electronic structure, hybridization of rhodium and selenium orbitals, and the influence of spin\u2013orbit interaction on the electronic spectrum, as well as inspected its topological properties. In addition, we investigated the surface electronic structure of zaykovite and revealed the anisotropic Rashba-type spin splitting in the surface states. In addition, using calculations of the phonon spectra and enthalpy of formation, we predicted the family of similar selenides based on other 4d and 5d transition metals such as Ir, Pd, and Pt. The structural and electronic properties of these materials are discussed.<\/jats:p>","DOI":"10.1063\/5.0232257","type":"journal-article","created":{"date-parts":[[2024,10,3]],"date-time":"2024-10-03T10:36:23Z","timestamp":1727951783000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Electronic structure of zaykovite Rh3Se4, prediction, and analysis of physical properties of related materials: Pd3Se4, Ir3Se4, and Pt3Se4"],"prefix":"10.1063","volume":"161","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1056-4478","authenticated-orcid":false,"given":"Leonid S.","family":"Taran","sequence":"first","affiliation":[{"name":"M. N. Mikheev Institute of Metal Physics, Ural Branch of Russian Academy of Sciences 1 , 620137 Yekaterinburg,","place":["Russia"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9477-3017","authenticated-orcid":false,"given":"Sergey V.","family":"Eremeev","sequence":"additional","affiliation":[{"name":"Institute of Strength Physics and Materials Science of Siberian Branch of Russian Academy of Sciences 2 , 634055 Tomsk,","place":["Russia"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2823-1754","authenticated-orcid":false,"given":"Sergey V.","family":"Streltsov","sequence":"additional","affiliation":[{"name":"M. N. Mikheev Institute of Metal Physics, Ural Branch of Russian Academy of Sciences 1 , 620137 Yekaterinburg,","place":["Russia"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"317","published-online":{"date-parts":[[2024,10,3]]},"reference":[{"key":"2024100310361496100_c1","doi-asserted-by":"publisher","first-page":"918","DOI":"10.1107\/s160057671900997x","volume":"52","year":"2019","journal-title":"J.\u00a0Appl. Crystallogr."},{"key":"2024100310361496100_c2","doi-asserted-by":"publisher","first-page":"799","DOI":"10.2138\/am-2024-nmn10949","volume":"109","year":"2024","journal-title":"Am. Mineral."},{"key":"2024100310361496100_c3","doi-asserted-by":"publisher","first-page":"118","DOI":"10.1180\/mgm.2022.122","volume":"87","year":"2023","journal-title":"Mineral. Mag."},{"key":"2024100310361496100_c4","doi-asserted-by":"publisher","first-page":"447","DOI":"10.1180\/0026461056940262","volume":"69","year":"2005","journal-title":"Mineral. 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