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In overcrowded alkene-based molecular motors, rotary motion is accomplished through consecutive cis\u2013trans photoisomerization reactions and thermal helix inversion steps. To date, a complete understanding of the photoisomerization reactions of overcrowded alkene motors has not been achieved yet. In this work, we use quantum chemical calculations and quantum mechanics\/molecular mechanics nonadiabatic dynamics simulations to investigate the photoinduced dynamics of a push\u2013pull alkene-based molecular motor in two different solvents: cyclohexane and methanol. We show that, while in both solvents the main photorelaxation pathway of our investigated push\u2013pull motor involves two different excited-state minima, in polar methanol, the photorelaxation dynamics is much faster than in nonpolar cyclohexane because of two main effects: (i) a lowering of the energy barrier between the excited-state minima and (ii) a reduction in the energy gap with the ground state at the largely twisted dark minimum, where the excited-state decay takes place. Both effects can be attributed to solvent-polarity stabilization of the charge-transfer excited state along the photorelaxation pathway. In line with the experimental findings, our simulations also indicate that, in methanol, the accelerated photoinduced dynamics goes along with a faster fluorescence decay and a large reduction in the forward photoisomerization yield of our investigated motor.<\/jats:p>","DOI":"10.1063\/5.0269998","type":"journal-article","created":{"date-parts":[[2025,6,13]],"date-time":"2025-06-13T05:55:05Z","timestamp":1749794105000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":2,"title":["Impact of solvent polarity on the photoinduced dynamics of a push\u2013pull molecular motor"],"prefix":"10.1063","volume":"162","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4100-4679","authenticated-orcid":false,"given":"Davide","family":"Accomasso","sequence":"first","affiliation":[{"name":"Faculty of Chemistry, University of Warsaw , Pasteura 1, Warsaw,","place":["Poland"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-5634-999X","authenticated-orcid":false,"given":"Dominika","family":"Mako\u015b","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, University of Warsaw , Pasteura 1, Warsaw,","place":["Poland"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2025,6,13]]},"reference":[{"key":"2025061305545736900_c1","doi-asserted-by":"publisher","first-page":"72","DOI":"10.1002\/anie.200504313","article-title":"Synthetic molecular motors and mechanical machines","volume":"46","year":"2007","journal-title":"Angew. 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